I assume that you are asking "Why is the attemperation water
spray placed between the primary superheater and the secondary
superheater?" This gives time for all the spray water to evaporate
and still be effective at de-superheating, or attemperating.
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An attemperator is a device which regulates the temperature of
somewhere, such as a boiler, by passing hot or cold water through a
coil of spring.
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Some major fields of study under engineering are as follows.