Yes ants can walk backwards but most of them do not.
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Many birds can walk backwards. Parrots, ostriches, doves and
pigeons are just some birds which are able to walk backwards.
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There some insects that walk backwards which is part of their
unique features. The doodle bug is one of the various types of
insects that walk backwards.
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In the chat box, type in /moonwalk your character will walk
backwards instead of foward, but you must log out to undo it.