cellophane

Printed cellophane bag with chocolate hearts and a transparent cellophane packaging with gingerbread

Cellophane is a thin, transparent sheet made of regenerated cellulose. Its low permeability to air, oils and greases, and bacteria makes it useful for food packaging. Cellophane is in many countries a registered trade mark of Innovia Films Ltd, Cumbria, UK.

Production

Cellulose is treated with alkali and carbon disulfide to yield viscose.

Cellulose fibers from wood, cotton, hemp, or other sources are dissolved in alkali and carbon disulfide to make a solution called viscose, which is then extruded through a slit into a bath of dilute sulfuric acid and sodium sulfate to reconvert the viscose into cellulose. The film is then passed through several more baths, one to remove sulfur, one to bleach the film, and one to add glycerin to prevent the film from becoming brittle.

A similar process, using a hole (a spinneret) instead of a slit, is used to make a fibre called rayon. Chemically, cellophane, rayon and cellulose are polymers of glucose and contain the chemical elements carbon, hydrogen, and oxygen.

History

Cellophane was invented by Swiss chemist Jacques E. Brandenberger while employed by Blanchisserie et Teinturerie de Thaon. In 1900, inspired by seeing a wine spill on a restaurant's tablecloth, he decided to create a cloth that could repel liquids rather than absorb them. His first step was to spray a waterproof coating on to fabric, and he opted to try viscose. The resultant coated fabric was far too stiff, but the clear film easily separated from the backing cloth, and he abandoned his original idea as the possibilities of the new material became apparent.

It took ten years for Brandenberger to perfect his film, his chief improvement over earlier work with such films being to add glycerin to soften the material. By 1912 he had constructed a machine to manufacture the film, which he had named Cellophane, from the words cellulose and diaphane ("transparent"). Cellophane was patented that year.^[1] The following year, the company Comptoir des Textiles Artificiels (CTA) bought the Thaon firm's interest in Cellophane and established Brandenberger in a new company, La Cellophane SA.^[2]

Whitman's candy company initiated use of cellophane for candy wrapping in the United States in 1912 for their Whitman's Sampler. They remained the largest user of imported cellophane from France until nearly 1924, when DuPont built the first cellophane manufacturing plant in the US. Cellophane saw limited sales in the US at first since while it was waterproof, it was not moisture proof—it held water but was permeable to water vapor. This meant that it was unsuited to packaging products that required moisture proofing. Du Pont hired the chemist William Hale Charch, who spent three years developing a nitrocellulose lacquer that, when applied to Cellophane, made it moisture proof.^[3] Following the introduction of moisture-proof Cellophane in 1927, the material's sales tripled between 1928 and 1930, and in 1938, Cellophane accounted for 10% of Du Pont's sales and 25% of its profits.^[2]

The British textile company Courtaulds' viscose technology had allowed it to diversify in 1930 into viscose film, which it named "Viscacelle". However, competition with Cellophane was an obstacle to its sales, and in 1935 it founded British Cellophane in conjunction with the Cellophane Company and its French parent company CTA.^[4] A major production facility was constructed at Bridgwater, Somerset, England, from 1935-1937, employing 3,000 workers.

Present day

Cellulose film has been manufactured continuously since the mid-1930s and is still used today. As well as packaging a variety of food items, there are also industrial applications, such as a base for such self-adhesive tapes as Sellotape and Scotch Tape, a semi-permeable membrane in a certain type of battery, as dialysis tubing (Visking tubing) and as a release agent in the manufacture of fibreglass and rubber products. The word "cellophane" has become genericized in the US, and is often used informally to refer to a wide variety of plastic film products, even those not made of cellulose.^[5] However, in the UK, Europe and in many other countries it is still a registered trademark and the property of Innovia Films Ltd.^[6]

Cellophane sales have dwindled since the 1960s due to use of alternative packaging options, and the fact that viscose is becoming less common because of the polluting effects of carbon disulfide and other by-products of the process. However, the fact that cellophane is 100% biodegradable has increased its popularity as a food wrapping. Cellophane is the most popular material for manufacturing cigar packaging; its permeability to moisture makes cellophane the perfect product for this application as cigars must be allowed to "breathe" while in storage.^[7][8]

See also

• Bioplastics
• Genericized trademark
• British Cellophane
• Jacques E. Brandenberger

Notes

External links

• Cellophane Invention