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cordierite

 
Dictionary: cor·di·er·ite   (kôr'dē-ə-rīt') pronunciation
n.
A dichroic violet-blue to gray mineral silicate of magnesium, aluminum, and sometimes iron. Also called dichroite.

[French, after Pierre L. Cordier (1777-1861), French geologist.]


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Sci-Tech Encyclopedia: Cordierite
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An orthorhombic magnesium aluminosilicate mineral of composition Mg2[Al4Si5O18]. The crystal structure is related to beryl. Limited amounts of Fe2+ may substitute for Mg2+, and Fe3+ for Al3+. The hardness is 7 (Mohs scale); specific gravity 2.6; luster vitreous; cleavage poor; and color greenish-blue, lilac blue, or dark blue, often strongly pleochroic colorless to deep blue. Transparent pleochroic crystals are used as gem material. The disordered cordierite structure, Mg2[(Al,Si)9O18], is called indialite and is hexagonal, isotypic with beryl. Osumilite, KMg2Al3[(Al,Si)12O30] · H2O, is also related but has a structure built of double six-membered rings of tetrahedrons. Cordierite, indialite, and osumilite are difficult to distinguish. Pale colored varieties are often misidentified as quartz, since these minerals have many physical properties in common. See also Beryl; Silicate minerals.

Cordierite possesses unusually low thermal expansion, and synthetic material has been applied to thermal-shock-resistant materials, such as insulators for spark plugs and low-expansion concrete.

Cordierite frequently occurs associated with thermally metamorphosed rocks derived from argillaceous sediments. It may occur in aluminous schists, gneisses, and granulites; though usually appearing in minor amounts, cordierite occurs at many localities throughout the world.


Rock & Mineral Guide: cordierite
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(Mg,Fe)
Orthorhombic -- Rhombic bipyramidal

Environment

Usually a mineral of metamorphic rocks, considered indicators of intense heat and pressure.

Crystal description

Crystals rare, and embedded, often more or less altered to a mica or chlorite. Usually in grains or masses embedded in rock without crystal outlines.

Physical properties

Gray and blue in the same grain. Luster glassy; hardness 7-7Ɖ; specific gravity 2.6-2.7; fracture subconchoidal; cleavage poor pinacoidal (side pinacoid best). Brittle; gemmy to translucent; strong transformation of hue in different crystal directions, changing from violet-blue to grayish as it is turned (the inspiration for one of its alternate names, "dichroite").

Composition

Magnesium, aluminum silicate; plus iron, calcium, and hydroxyl (OH): 10.2% MgO, 33.6% Al 2 O 3 , 49.4% SiO 2 , perhaps 5.3% FeO, and 15% H 2 O.

Tests

No blowpipe test is necessary. The color change from blue to gray, which will be seen through most flakes, is sufficiently distinctive. In case of doubt, look through chip at light reflecting from a polished table top or glass sheet and turn it to see the two colors.

Distinguishing characteristics

Color and dichroism (directional change in color) are very characteristic; there is no other very common violet-blue schist mineral with this appearance.

Occurrence

The largest (altered) crystals have been found in Bodenmais, Germany. Good embedded glassy masses are found at Orijärvi, Finland; Kragerø, Norway; and Mt. Tsilaizina, Madagascar. Gemmy waterworn pebbles are found in the Sri Lanka (Ceylon) gem gravels and in India. Recently found in Yellowknife, Northwest Territories.

In the U.S. it is found near Haddam, Connecticut, on the w. side of the Connecticut River.

Also known as iolite for its violet color and as dichroite because of the remarkable directional color change. It has been used as a jewelry stone but is lacking in brilliance, since it is rarely really clear and usually too dark. Valued as a geological thermometer and used as a guide to the grade of metamorphism. It has been suggested that this mineral was used in the Norsemen's Atlantic navigation to locate the sun's position in cloudy weather (the strongest polarization of sky light, and the bluest hue in the iolite, is at 90° from the sun).



WordNet: cordierite
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Note: click on a word meaning below to see its connections and related words.

The noun has one meaning:

Meaning #1: a blue mineral of magnesium and iron and aluminum and silicon and oxygen; often used as a gemstone


Wikipedia: Cordierite
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Cordierite

Left: rough specimen showing dichroism; right: cut stone
General
Category Mineral
Chemical formula (Mg,Fe)2Al4Si5O18
Identification
Color Blue, violet, yellow-brown; transparent to translucent
Crystal habit Pseudo-hexagonal prismatic twins, as imbedded grains, and massive
Crystal system Orthorhombic; 2/m 2/m 2/m
Cleavage {010} poor
Fracture Conchoidal, uneven
Mohs scale hardness 7 - 7.5
Luster Greasy or vitreous
Streak White
Specific gravity 2.57 - 2.66
Optical properties Usually optically (-), sometimes (+); 2V = 0-90°
Refractive index α=1.522 - 1.558 β=1.524 - 1.574 γ=1.527 - 1.578 Indices increase with Fe content.
Pleochroism Strong, dichroic: brown-yellow, light and dark blue
Fusibility on thin edges
Diagnostic features Resembles quartz can be distinguished by pleochroism. Can be distinguished from corundum by its lower hardness
Other characteristics Dana class: 61.2.1.1
Crystal structure of Cordierite

Cordierite (mineralogy) or iolite (gemology) is a magnesium iron aluminium cyclosilicate. Iron is almost always present and a solid solution exists between Mg-rich cordierite and Fe-rich sekaninaite with a series formula: (Mg,Fe)2Al3(Si5AlO18) to (Fe,Mg)2Al3(Si5AlO18)[1]. A high temperature polymorph exists, indialite, which is isostructural with beryl and has a random distribution of Al in the (Si,Al)6O18 rings.[2]

Cordierite is named after the French geologist Louis Cordier (1777–1861).

Contents

Occurrence

Cordierite typically occurs in contact or regional metamorphism of argillaceous rocks. It is especially common in hornfels produced by contact metamorphism of pelitic rocks. Two common metamorphic mineral assemblages include sillimanite-cordierite-spinel and cordierite-spinel-plagioclase-orthopyroxene. Other associated minerals include garnet (cordierite-garnet-sillimanite gneisses) and anthophyllite.[3][4] Cordierite also occurs in some granites, pegmatites, and norites in gabbroic magmas. Alteration products include mica, chlorite, and talc. Cordierite occurs in the granite contact zone at Geevor Tin Mine in Cornwall.

Cordierite from Madagascar

Commercial use

Catalytic converters are commonly made from ceramics containing a large proportion of cordierite. The manufacturing process deliberately aligns the cordierite crystals to make use of the very low thermal expansion seen for one axis. This prevents thermal shock cracking from taking place when the catalytic converter is used.[5]

Gem variety

As the transparent variety iolite, it is often used as a gemstone. The name "iolite" comes from the Greek word for violet. Another old name is dichroite, a Greek word meaning "two-colored rock", a reference to cordierite's strong pleochroism. It has also been called "water-sapphire" and "Vikings' Compass", because of its ability to determine the direction of the sun on overcast days. This works by determining the direction of polarization of the sky overhead. Light scattered by air molecules is polarized, and the direction of the polarization is at right angles to a line to the sun, even when the sun's disk itself is obscured by dense fog or lies just below the horizon. [6] Gem quality iolite varies in color from sapphire blue to blue violet to yellowish gray to light blue as the light angle changes.

Iolite is sometimes used as an inexpensive substitute for sapphire. It has a low price tag because it is much softer than sapphires[7] and is abundantly found in Sri Lanka, India, Burma, Australia's Northern Territory, Namibia, Brazil, Tanzania, Madagascar, Connecticut, and the Yellowknife area of the Northwest Territories of Canada.

See also

References

  1. ^ http://www.mindat.org/min-1128.html Mindat.org
  2. ^ Webmineral
  3. ^ Hurlbut, Cornelius S.; Klein, Cornelis, 1985, Manual of Mineralogy, 20th ed., John Wiley and Sons, New York, p. 395-396, ISBN 0-471-80580-7
  4. ^ Klein, Cornelius., 2002, The Manual of Mineral Science, 22nd ed., John Wiley & Sons, Inc. ISBN 0-471-25177-1
  5. ^ Cybulski, A: "Structural Catyalysts and Reactors - Second Edition"., p. 35, 2005, CRC Press.
  6. ^ (Geophysical Institute, University of Alaska Fairbanks) Oscar Noel and Sue Ann Bowling, "Polar Navigation and the Sky Compass", 1988.
  7. ^ Iolite as a gemstone

External links


 
 

 

Copyrights:

Dictionary. The American Heritage® Dictionary of the English Language, Fourth Edition Copyright © 2007, 2000 by Houghton Mifflin Company. Updated in 2009. Published by Houghton Mifflin Company. All rights reserved.  Read more
Sci-Tech Encyclopedia. McGraw-Hill Encyclopedia of Science and Technology. Copyright © 2005 by The McGraw-Hill Companies, Inc. All rights reserved.  Read more
Rock & Mineral Guide. Peterson Field Guide to Rocks and Minerals, by Frederick H. Pough. Copyright © 1998 by Houghton Mifflin Company. Published by Houghton Mifflin Company. All rights reserved.  Read more
WordNet. WordNet 1.7.1 Copyright © 2001 by Princeton University. All rights reserved.  Read more
Wikipedia. This article is licensed under the Creative Commons Attribution/Share-Alike License. It uses material from the Wikipedia article "Cordierite" Read more

 

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