Something that does not give results that you would expect.
Pumice is a rock that is created by volcanoes. It is very porous and filled with air pockets, so it floats in water.
Now...rocks normally sink in water. The fact that this rock floats is <counter intuitive> to the normal idea that rocks sink.
A red sky at sunrise or sunset is counter intuitive to the idea that the sky is blue.
"Charley is a gentle giant, which is counter intuitive because he looks like a serial killer!"