Heavy water occurs naturally in all water in a proportion of about one part in twenty million. In order to get a certain amount of heavcy water you have to isolate the heavy molecules out of a large quantity of water. The Germans used fresh water because there would have been no point in having to desalinize before they could even begin isolating the heavy water from the regular water. Heavy water is heavy because one of the hydrogen atoms in the water molecule has a neutron in its nucleus along with the proton.