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effusion

 
(ĭ-fyū'zhən) pronunciation
n.
    1. The act or an instance of effusing.
    2. Liquid or other matter poured forth.
  1. An unrestrained outpouring of feeling, as in speech or writing: "the devout effusions of sacred eloquence" (Edmund Burke).
  2. Pathology.
    1. The seeping of serous, purulent, or bloody fluid into a body cavity or tissue.
    2. The effused fluid.

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The flow of a gas through a small aperture. The relative rates at which gases effuse, under the same conditions, is approximately inversely proportional to the square roots of their densities.




n

Definition: outpouring
Antonyms: restraint

A form of oedema in which there is an accumulation of fluid in a potential space, such as a joint capsule.

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effusion

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pronunciation

IN BRIEF: Free expression of words or feelings; an outpouring.

pronunciation Frank was touched by the effusion of good wishes from his colleagues at his retirement party.

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1. escape of a fluid into a part; exudation or transudation. See also specific anatomic sites.
2. an exudate or transudate.

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For a list of words related to effusion, see:

In physics, effusion is the process in which individual molecules flow through a hole without collisions between molecules. This occurs if the diameter of the hole is considerably smaller than the mean free path of the molecules.[1] According to Graham's law, the rate at which gases effuse (i.e., how many molecules pass through the hole per second) is dependent on their molecular weight; gases with a lower molecular weight effuse more quickly than gases with a higher molecular weight. For two gases at the same temperature (and having the same specific heat), and thus having the same kinetic energy, the root mean square molecular speed, vrms, of each gas can be found using the equation

32kBT = 12mv2
rms

where kB is the Boltzmann constant. Thus, lighter molecules have a higher speed. This results in more molecules passing through the hole per unit time. This is why a balloon filled with low molecular weight hydrogen deflates faster than an equivalent balloon full of higher molecular weight oxygen.

Contents

Application to Chemistry

[2] Thomas Graham (1805-1869), a Scottish chemist, found experimentally that the rate of effusion of a gas is inversely proportional to the square root of the mass of its particles. In other words, the relative rates of effusion of two gases at the same temperature and pressure are given by the inverse ratio of the square roots of the masses of the gas particles.


In chemistry, the equation is given by

{\mbox{Rate of effusion of gas}_1 \over \mbox{Rate of effusion of gas}_2}=\sqrt{M_2 \over M_1}

where M1 and M2 represent the molar masses of the gases. This equation is known as Graham's Law of Effusion.

The effusion rate for a gas depends directly on the average velocity of its particles. Thus, the faster the gas particles are moving, the more likely they are to pass through the effusion orifice. A figure of Graham's law of effusion linked below shows the rate of effusion (the rate at which the gas is transferred across the barrier through the pin hole) is inversely proportional to the square root of the mass of the gas molecules. See: [[File:Effusion of a gas into an evacuated chamber]]

See also

References

  1. ^ K.J. Laidler and J.H. Meiser, Physical Chemistry, Benjamin/Cummings 1982, p.18
  2. ^ Zumdahl, Steven S. (2008). Chemical Principles. Boston: Houghton Mifflin Harcourt Publishing Company. pp. 164. ISBN 9780547196268. 

External links


Translations:

Effusion

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Dansk (Danish)
n. - ordflom, udstrømning, blodudtrædning, væsleudtrædning, effusion

Nederlands (Dutch)
spraakwaterval, het uitstromen, uitvloeisel

Français (French)
n. - écoulement (d'un liquide), effusion (de sang), (fig) effusion, épanchement

Deutsch (German)
n. - Erguß, Ausströmen

Ελληνική (Greek)
n. - διάχυση, (μτφ.) (ποιητική) έξαρση

Italiano (Italian)
effusione

Português (Portuguese)
n. - efusão (f)

Русский (Russian)
излияние, кровоизлияние, поток (слов, эмоций)

Español (Spanish)
n. - efusión

Svenska (Swedish)
n. - utgjutning

中文(简体)(Chinese (Simplified))
泻出, 吐露, 流出, 强烈的情感流露

中文(繁體)(Chinese (Traditional))
n. - 瀉出, 吐露, 流出, 強烈的情感流露

한국어 (Korean)
n. - 유출, 유출물, 토로

日本語 (Japanese)
n. - 流出, ほとばしり, 発露, 流露, 表現

العربيه (Arabic)
‏(الاسم) اراقه, تدفق‏

עברית (Hebrew)
n. - ‮השתפכות, נזילה‬


 
 

 

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