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Energy content of biofuel

 
Wikipedia: Energy content of biofuel
 

Contents

A Table of Energy Content and CO2 Output of Common Fuels

Energy is the ability to do work. Per kilogram of mass, different substances can do different amounts of work.[1] In other words they have different energy contents. Of course to do work we usually use a machine of some type. These machines vary in efficiency, or useful work done, and none are 100% efficient. Thus the amount of useful work actually performed by these substances will never totally match these results. However this table gives us a relative measure of the amounts of these substances which could be equivalent in producing the required result (moving a car, heating a home, etc.).

In the example of the first two entries, Bagasse (Cane Stalks) has 9.6 MJ/kg (Mega Joules per kilogram) and Chaff (Seed Casings) has an energy content of 14.6 MJ/kg. In other words 1 kg of Chaff as a fuel would have 14.6-9.6, or 5 MJ more energy per kilogram energy content and potential work output than Bagasse.

The next column in the table (3) is the energy content per liter of volume, which is useful for liquid fuels.

The next column (4) contains the ratio of CO2 mass produced to the mass of the fuel. For example Bagasse has a ratio of 1.3 which means 1.3 kg of CO2 will be produced for every 1 kg of Bagasse used as fuel.

The last column (5), Energy in MJ per kg CO2 produced (MJ/kg) lists the energy produced per Kg of CO2 produced. This is a measure of the potential environmental impact of the use of the substance as a fuel with respect to the release of CO2. The more CO2 released the worse it is for the environment. Thus a higher number in this column is better for the environment because we get more energy per kg of CO2 produced. For example gasoline produces 13.64-14.64 MJ per kg of CO2 but methane produces 20.05-20.30 MJ of energy, or nearly 50% more energy for the same CO2 production.

Fuel Type Specific Energy Density
(MJ/kg)
Volumetric Energy Density
(MJ/L)
CO2 Gas made from Fuel Used
(kg/kg)
Energy per CO2
(MJ/kg)
Solid Fuels
Bagasse (Cane Stalks) 9.6           ~+40%(C6H10O5)n+15%(C26H42O21)n+15%(C9H10O2)n1.30  7.41 
Chaff (Seed Casings) 14.6           [Please insert average composition here] 
Animal Dung/Manure [1] 10-[2] 15              [Please insert average composition here] 
Dried plants (C6H10O5)n 10 – 16            1.6 - 16.64       IF50%(C6H10O5)n+25%(C26H42O21)n+25%(C10H12O3)n1.84  5.44-8.70 
Wood fuel (C6H10O5)n 16 – 21            [3] 2.56 - 21.84       IF45%(C6H10O5)n+25%(C26H42O21)n+30%(C10H12O3)n1.88  8.51-11.17 
Charcoal 30              85-98% Carbon+VOC+Ash 3.63  8.27 
Liquid Fuels
Pyrolysis oil 17.5         21.35       (Assumption Of Fuel: Carbon Content = 23% w/w) 0.84  20.77 
Methanol (CH3-OH) 19.9 – 22.7         15.9         1.37  14.49-16.53 
Ethanol (CH3-CH2-OH) 23.4 – 26.8         18.4 - 21.2         1.91  12.25-14.03 
EcaleneTM 28.4         22.7         75%C2H6O+9%C3H8O+7%C4H10O+5%C5H12O+4%Hx 2.03  14.02 
Butanol(CH3-(CH2)3-OH) 36            29.2         2.37  15.16 
Fat 37.656     31.68       [Please insert average composition here] 
Biodiesel 37.8         33.3 – 35.7         ~2.85  ~13.26 
Sunflower oil (C18H32O2) [4] 39.49       33.18       (12%(C16H32O2)+16%(C18H34O2)+71%(LA)+1%(ALA))2.81  14.04 
Castor oil (C18H34O3) [5] 39.5         33.21       (1%PA+1%SA+89.5%ROA+3%OA+4.2%LA+0.3%ALA)2.67  14.80 
Olive oil (C18H34O2) 39.25 - 39.82       33 - 33.48       (15%(C16H32O2)+75%(C18H34O2)+9%(LA)+1%(ALA))2.80  14.03 
Gaseous Fuels
Methane (CH4) 55 – 55.7         (Liquified) 23.0 – 23.3         (Methane leak exerts 23 × greenhouse effect of CO2) 2.74  20.05-20.30 
Hydrogen (H2) 120 – 142            (Liquified) 8.5 – 10.1         (Hydrogen leak slightly catalyzes ozone depletion) 0.0    
Fossil Fuels (comparison)
Coal 29.3 – 33.5         39.85 - 74.43       (Not Counting:CO,NOx,Sulfates & Particulates) ~3.59  ~8.16-9.33 
Crude Oil 41.868     28 – 31.4         (Not Counting:CO,NOx,Sulfates & Particulates) ~3.4   ~12.31 
Gasoline 45 – 48.3         32 – 34.8         (Not Counting:CO,NOx,Sulfates & Particulates) ~3.30  ~13.64-14.64 
Diesel 48.1         40.3         (Not Counting:CO,NOx,Sulfates & Particulates) ~3.4   ~14.15 
Natural Gas 38 – 50            (Liquified) 25.5 – 28.7         (Ethane,Propane & Butane N/C:CO,NOx & Sulfates) ~3.00  ~12.67-16.67 
Ethane (CH3-CH3) 51.9         (Liquified) ~24.0         2.93  17.71 
Uranium-235 (235U) 77,000,000            (Pure)1,470,700,000            [Greater for lower ore conc.(Mining,Refining,Moving)] 0.0   (NETT) >12.67 
Nuclear fusion (2H-3H) 300,000,000            (Liquified)53,414,377.6         (Sea-Bed Hydrogen-Isotope Mining-Method Dependent) 0.0    
Fuel Cell Energy Storage (comparison)
Direct-Methanol 4.5466   [6] 3.6         ~1.37  ~3.31 
Proton-Exchange (R&D) up to 5.68       up to 4.5         (IFF Fuel is recycled) 0.0    
Sodium Hydride (R&D) up to 11.13       up to 10.24       (Bladder for Sodium Oxide Recycling) 0.0    
Battery Energy Storage (comparison)
Lead-acid battery 0.108     ~0.1         (200-600 Deep-Cycle Tolerance) 0.0    
Nickel-iron battery [7]0.0487 - 0.1127    0.0658 - 0.1772    (<40y Life)(2k-3k Cycle Tolerance IF no Memory effect) 0.0    
Nickel-cadmium battery 0.162 - 0.288     ~0.24       (1k-1.5k Cycle Tolerance IF no Memory effect) 0.0    
Nickel metal hydride 0.22 - 0.324     0.36       (300-500 Cycle Tolerance IF no Memory effect) 0.0    
Super iron battery 0.33       [8] (1.5 * NiMH) 0.54       [9] (~300 Deep-Cycle Tolerance) 0.0    
Zinc-air battery 0.396 - 0.72       [10] 0.5924 - 0.8442    (Recyclable by Smelting & Remixing, not Recharging) 0.0    
Lithium ion battery 0.54 - 0.72       0.9 - 1.9         (3-5 y Life) (500-1k Deep-Cycle Tolerance) 0.0    
Lithium-Ion-Polymer 0.65 - 0.87       (1.2 * Li-Ion)1.08 - 2.28       (3-5 y Life) (300-500 Deep-Cycle Tolerance) 0.0    
DURACELL Zinc-Air 1.0584 - 1.5912    5.148 - 6.3216    (1-3 y Shelf-life) (Recyclable not Rechargeable) 0.0    
Aluminium battery 1.8 - 4.788     7.56       (10-30 y Life) (3k+ Deep-Cycle Tolerance) 0.0    
PolyPlusBC Li-Aircell 3.6 - 32.4         3.6 - 17.64       (May be Rechargeable)(Might leak sulfates) 0.0    

Notes

Yields of common crops associated with biofuels production

Crop Oil
(kg/ha)
Oil
(L/ha)
Oil
(lbs/acre)
Oil
(US gal/acre)
Oil per seeds
(kg/100 kg)
Melting Range (°C) Iodine
number
Cetane
number
Oil /
Fat
Methyl
Ester
Ethyl
Ester
Groundnut (Kernel)42
Copra 62
Tallow 35 - 42 16 12 40 - 60 75
Lard 32 - 36 14 10 60 - 70 65
Corn (maize) 145 172 129 18 -5 -10 -12 115 - 124 53
Cashew nut 148 176 132 19
Oats 183 217 163 23
Lupine 195 232 175 25
Kenaf 230 273 205 29
Calendula 256 305 229 33
Cotton 273 325 244 35 (Seed)13 -1 - 0 -5 -8 100 - 115 55
Hemp 305 363 272 39
Soybean 375 446 335 48 14 -16 - -12 -10 -12 125 - 140 53
Coffee 386 459 345 49
Linseed (flax) 402 478 359 51 -24 178
Hazelnuts 405 482 362 51
Euphorbia 440 524 393 56
Pumpkin seed 449 534 401 57
Coriander 450 536 402 57
Mustard seed 481 572 430 61 35
Camelina 490 583 438 62
Sesame 585 696 522 74 50
Safflower 655 779 585 83
Rice 696 828 622 88
Tung oil tree 790 940 705 100 -2.5 168
Sunflowers 800 952 714 102 32 -18 - -17 -12 -14 125 - 135 52
Cocoa (cacao) 863 1,026 771 110
Peanuts 890 1,059 795 113 3 93
Opium poppy 978 1,163 873 124
Rapeseed 1,000 1,190 893 127 37 -10 - 5 -10 - 0 -12 - -2 97 - 115 55 - 58
Olives 1,019 1,212 910 129 -12 - -6 -6 -8 77 - 94 60
Castor beans 1,188 1,413 1,061 151 (Seed)50 -18 85
Pecan nuts 1,505 1,791 1,344 191
Jojoba 1,528 1,818 1,365 194
Jatropha 1,590 1,892 1,420 202
Macadamia nuts 1,887 2,246 1,685 240
Brazil nuts 2,010 2,392 1,795 255
Avocado 2,217 2,638 1,980 282
Coconut 2,260 2,689 2,018 287 20 - 25 -9 -6 8 - 10 70
Chinese Tallow 4,700 500
Oil palm 5,000 5,950 4,465 635 20-(Kernal)36 20 - 40 -8 - 21 -8 - 18 12 - 95 65 - 85
Algae 95,000 10,000
Crop Oil
(kg/ha)
Oil
(L/ha)
Oil
(lbs/acre)
Oil
(US gal/acre)
Oil per seeds
(kg/100 kg)
Melting Range (°C) Iodine
number
Cetane
number
Oil /
Fat
Methyl
Ester
Ethyl
Ester

Oil per seeds = Typical oil extraction from 100 kg. of oil seeds
- Note: Chinese Tallow (Sapium sebiferum, or Tradica Sebifera) is also known as the "Popcorn Tree".
Source: Used with permission from the The Global Petroleum Club

See also

References




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Wikipedia. This article is licensed under the GNU Free Documentation License. It uses material from the Wikipedia article "Energy content of biofuel" Read more