The song was "One Step Closer". It was featured in the ER episode "On the Beach."
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Somewhere over the rainbow!
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The correct name of the television series is Rescue Me. The
first episode of season 4 aired on June 13, 2007. Rescue Me, season
4, was released on DVD on June 3, 2008.
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It's called Wolf Like Me and the artist is TV on the Radio.
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The episode title was "Loss of Innocence" but I can't find the
song.