Yes you have to unlock them. The samurai is on the Azure
Rainforest somewhere and the hexcaster is on the Sandy Barrens
level somewhere.
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To get past the White and Violet crystals, you need the
appropriate keys.
The White key can be found on B7F
The Violet key can be found on B13F.
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You need to mine some Andradite from any of the Mining gather
points on the first stratum. It is a rare find, so you may have to
revisit the gather points on different days, before you find
one.