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fermium

 
Dictionary: fer·mi·um   (fûr'mē-əm, fĕr'-) pronunciation
 
n. (Symbol Fm)

A synthetic transuranic metallic element (atomic number 100) having 10 isotopes with mass numbers ranging from 248 to 257 and corresponding half-lives ranging from 0.6 minutes to approximately 100 days.

[After Enrico FERMI.]


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A chemical element, Fm, atomic number 100, the eleventh element in the actinide series. Fermium does not occur in nature; its discovery and production have been accomplished by artificial nuclear transmutation of lighter elements. Radioactive isotopes of mass number 244–259 have been discovered. The total weight of fermium which has been synthesized is much less than one-millionth of a gram. See also Actinide elements; Periodic table.

Spontaneous fission is the major mode of decay for 244Fm, 256Fm, and 258Fm. The longest-lived isotope is 257Fm, which has a half-life of about 100 days. Fermium-258 decays by spontaneous fission with a half-life of 0.38 millisecond. This suggests the existence of an abnormality at this point in the nuclear periodic table. See also Nuclear chemistry; Transuranium elements.


 
fermium (fûr'mēəm) [for Enrico Fermi], artificially produced radioactive chemical element; symbol Fm; at. no. 100; mass no. of most stable isotope 257; m.p. 1,527°C; b.p. and sp. gr. unknown; valence +2, +3. Fermium is a member of Group 3 of the periodic table. The physical properties of fermium are largely unknown; its chemical properties are believed to be similar to those of the other members of the actinide series. The eighth transuranium element to be discovered, fermium was first identified (1952) as fermium-255 (half-life about 20 hours) by Albert Ghiorso and his coworkers, who discovered it in residue from the first thermonuclear test explosion in the South Pacific. Twenty isotopes, all of which are radioactive, are known; the most stable is fermium-257, with a half-life of about 100 days. Isotopes of fermium have been produced by neutron bombardment of plutonium.


 

A chemical element, atomic number 100, atomic weight 253, symbol Fm.

 
Wikipedia: Fermium
Top
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Er

Fm

(Upn)
General
Name, Symbol, Number fermium, Fm, 100
Element category actinides
Group, Period, Block n/a, 7, f
Appearance unknown, probably silvery
white or metallic gray
Standard atomic weight (257)  g·mol−1
Electron configuration [Rn] 5f12 7s2
Electrons per shell 2, 8, 18, 32, 30, 8, 2
Physical properties
Phase solid
Melting point 1800 K
(1527 °C, 2781 °F)
Atomic properties
Oxidation states 2, 3
Electronegativity 1.3 (Pauling scale)
Ionization energies 1st: 627 kJ/mol
Miscellaneous
CAS registry number 7440-72-4
Most-stable isotopes
Main article: Isotopes of fermium
iso NA half-life DM DE (MeV) DP
252Fm syn 25.39 h SF - -
α 7.153 248Cf
253Fm syn 3 d ε 0.333 253Es
α 7.197 249Cf
255Fm syn 20.07 h SF - -
α 7.241 251Cf
257Fm syn 100.5 d α 6.864 253Cf
SF - -
References

Fermium (pronounced /ˈfɜrmiəm/) is a synthetic element with the symbol Fm and atomic number 100. A highly radioactive metallic transuranic element of the actinide series, fermium is made by bombarding plutonium with neutrons and is named after nuclear physicist Enrico Fermi. Fermium is the eighth transuranic element.

Contents

Characteristics

Electron shell diagram of fermium

Only small amounts of fermium have ever been produced or isolated. Thus relatively little is known about its chemical properties. Only the (III) oxidation state of the element appears to exist in aqueous solution. 254Fm and heavier isotopes can be synthesized by intense neutron bombardment of lighter elements (especially uranium and plutonium). During this, successive neutron captures mixed with beta decays build the fermium isotope. The intense neutron bombardment conditions needed to create fermium exist in thermonuclear explosions and can be replicated in the laboratory (such as in the High Flux Isotope Reactor at Oak Ridge National Laboratory). The synthesis of element 102 (nobelium) was confirmed when 250Fm was chemically identified.

Uses

There are no known uses of fermium outside of basic research.

History

Fermium (after Enrico Fermi) was first discovered by a team led by Albert Ghiorso in 1952. The team found 255Fm in the debris of the first hydrogen bomb explosion (see Operation Ivy). That isotope was created when 238U combined with 17 neutrons in the intense temperature and pressure of the explosion (eight beta decays also occurred to create the element). The work was overseen by the University of California Radiation Laboratory, Argonne National Laboratory, and Los Alamos Scientific Laboratory. All these findings were kept secret until 1955 due to Cold War tensions.[1] Samples of sea coral impacted from the first thermonuclear explosion of November 1952 were used.[2]

In late 1953 and early 1954 a team from the Nobel Institute of Physics in Stockholm bombarded a 238U target with 16O ions, producing an alpha-emitter with an atomic weight of ~250 and with 100 protons (in other words, element 250100).[3] The Nobel team did not claim discovery until 1954. The isotope they produced was later positively identified as 250Fm.

Isotopes

17 radioisotopes of fermium have been characterized, with the most stable being 257Fm with a half-life of 100.5 days, 253Fm with a half-life of 3 days, 252Fm with a half-life of 25.39 hours, and 255Fm with a half-life of 20.07 hours. All of the remaining radioactive isotopes have half-lives that are less than 5.4 hours, and the majority of these have half-lives that are less than 3 minutes. This element also has 1 meta state, 250mFm (t½ 1.8 seconds). The isotopes of fermium range in atomic weight from 242.073 u (242Fm) to 259.101 u (259Fm).

References

  1. ^ Ghiorso, A.; Thompson, S. G.; Higgins, G. H. ; Seaborg, G. T.; Studier, M. H.; Fields, P. R.; Fried, S. M.; Diamond, H.; Mech, J. F.; Pyle, G. L.; Huizenga, J. R.; Hirsch, A.; Manning, W. M.; Browne, C. I.; Smith, H. L.; Spence, R. W. (1955). "New Elements Einsteinium and Fermium, Atomic Numbers 99 and 100". Physical Review 99: 1048–1049. doi:10.1103/PhysRev.99.1048. http://prola.aps.org/abstract/PR/v99/i3/p1048_1. 
  2. ^ Albert Ghiorso (2003). "Einsteinium and Fermium". Chemical and Engineering News. http://pubs.acs.org/cen/80th/einsteiniumfermium.html. 
  3. ^ Atterling, Hugo; Forsling, Wilhelm; Holm, Lennart W.; Melander, Lars; Åström, Björn (1954). "Element 100 Produced by Means of Cyclotron-Accelerated Oxygen Ions". Physical Review 95: 585–586. doi:10.1103/PhysRev.95.585.2. 

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