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fire extinguisher

 
Dictionary: fire extinguisher

n.
A portable apparatus containing chemicals that can be discharged in a rapid stream to extinguish a small fire.


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How Products are Made: How is a fire extinguisher made?
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Background

The hand-held fire extinguisher is simply a pressure vessel from which is expelled a material (or agent) to put out a fire. The agent acts upon the chemistry of the fire by removing one or more of the three elements necessary to maintain fire—commonly referred to as the fire triangle. The three sides of the fire triangle are fuel, heat, and oxygen. The agent acts to remove the heat by cooling the fuel or to produce a barrier between the fuel and the oxygen supply in the surrounding air. Once the fire triangle is broken, the fire goes out. Most agents have a lasting effect upon the fuel to reduce the possibility of rekindling. Generally, the agents applied are water, chemical foam, dry powder, halon, or carbon dioxide (CO2). Unfortunately, no one agent is effective in fighting all types (classes) of fires. The type and environment of the combustible material determines the type of extinguisher to be kept nearby.

History

Fire extinguishers, in one form or another, have probably postdated fire by only a short time. The more practical and unitized extinguisher now commonplace began as a pressurized vessel that spewed forth water, and later, a combination of liquid elements. The older extinguishers comprised cylinders containing a solution of baking soda (sodium bicarbonate) and water. Inside, a vessel of sulfuric acid was positioned at the top of the body. This design had to be turned upside down to be activated, so that the acid spilled into the sodium bicarbonate solution and reacted chemically to form enough carbon dioxide to pressurize the body cylinder and drive out the water through a delivery pipe. This volatile device was improved by placing the acid in a glass bottle, designed to be broken by a plunger set on the top of the cylinder body or by a hammer striking a ring contraption on the side to release the acid. Cumbersome and sometimes ineffective, this design also required improvement.

Design

Aside from using different agents, manufacturers of extinguishers generally use some type of pressurized vessel to store and discharge the extinguishing agent. The means by which each agent is discharged varies. Water fire extinguishers are pressurized with air to approximately 150 pounds per square inch (psi)—five times a car tire pressure—from a compressor. A squeeze-grip handle operates a spring-loaded valve threaded into the pressure cylinder. Inside, a pipe or "dip tube" extends to the bottom of the tank so that in the upright position, the opening of the tube is submerged. The water is released as a steady stream through a hose or nozzle, pushed out by the stored pressure above it.

Water extinguishers of the "gas cartridge" type operate in much the same manner, but the pressure source is a small cartridge of carbon dioxide gas (CO2) at 2,000 psi, rather than air. To operate a gas cartridge unit, the end of the extinguisher is struck against the floor, causing a pointed spike to pierce the cartridge, releasing the gas into the pressure vessel. The released CO2 expands several hundred times its original volume, filling the gas space above the water. This pressurizes the cylinder and forces the water up through a dip-pipe and out through a hose or nozzle to be directed upon the fire. This design proved to be less prone to leakdown (loss of pressure over time) than simply pressurizing the entire cylinder.

In foam extinguishers, the chemical agent is generally held under stored pressure. In dry powder extinguishers, the chemicals can either be put under stored pressure, or a gas cartridge expeller can be used; the stored-pressure type is more widely used. In carbon dioxide extinguishers, the CO2 is retained in liquid form under 800 to 900 psi and is "self-expelling," meaning that no other element is needed to force the CO2 out of the extinguisher. In halon units, the chemical is also retained in liquid form under pressure, but a gas booster (usually nitrogen) is generally added to the vessel.

Raw Materials

Fire extinguishers can be divided into four classifications: Class A, Class B, Class C, and Class D. Each class corresponds to the type of fire the extinguisher is designed for, and, thus, the type of extinguishing agents used. Class A extinguishers are designed to fight wood and paper fires; Class B units fight contained flammable liquid fires; Class C extinguishers are designed to fight live electrical fires; and Class D units fight burning metal fires.

Water has proven effective in extinguishers used against wood or paper fires (Class A). Water, however, is an electrical conductor. Naturally, for this reason, it is not safe as an agent to fight electrical fires where live circuits are present (Class C). In addition, Class A extinguishers should not to be used in the event of flammable liquid fires (Class B), especially in tanks or vessels. Water can cause an explosion due to flammable liquids floating on the water and continuing to burn. Also, the forceful water stream can further splatter the burning liquid to other combustibles. One disadvantage of water extinguishers is that the water often freezes inside the extinguisher at lower temperatures. For these reasons, foam, dry chemical, CO2, and halon types were developed.

Foam, although water based, is effective against fires involving contained flammable liquids (Class B). A two-gallon (7.5 liters) extinguisher will produce about 16 gallons (60 liters) of thick, clinging foam that cools and smothers the fire. The agent itself is a proprietary compound developed by the various manufacturers and contains a small amount of propylene glycol to prevent freezing. It is contained as a mixture in a pressurized cylinder similar to the water type. Most aircraft carry this type of extinguisher. Foam can also be used on Class A fires.

The dry powder agent was developed to reduce the electrical hazard of water, and thus is effective against Class C fires. (It can also be used against Class B fires.) The powder is finely divided sodium bicarbonate that is extremely free-flowing. This extinguisher, also equipped with a dip-tube and containing a pressurizing gas, can be either cartridge-operated or of the stored pressure type as discussed above. Many specialized dry chemical extinguishers are also suitable for burning metal fires, or Class D.

Carbon dioxide (CO2) extinguishers, effective against many flammable liquid and electrical fires (Class B and C), use CO2 as both the agent and the pressurizing gas. The liquified carbon dioxide, at a pressure that may exceed 800 psi depending on size and use, is expelled through a flared horn. Activating the squeeze-grip handle releases the CO2 into the air, where it immediately forms a white, fluffy "snow." The snow, along with the gas, substantially reduces the amount of oxygen in a small area around the fire. This suffocates the fire, while the snow clings to the fuel, cooling it below the combustion point. The greatest advantage to the CO2 extinguisher is the lack of permanent residue. The electrical apparatus that was on fire is then more likely to be able to be repaired. Unlike CO2 "snow," water, foam, and dry chemicals can ruin otherwise undamaged components.

As extinguishing agents, halons are up to ten times more effective in putting out fires than other chemicals. Most halons are non-toxic and extremely fast and effective. Chemically inert, they are harmless to delicate equipment, including computer circuits, and leave no residue. The advantage of the halon over the CO2 extinguisher is that it is generally smaller and lighter. Halon is a liquid when under pressure, so it uses a dip-tube along with nitrogen as the pressurizing gas.

Halon, at least in fire extinguishers, may soon become a footnote to history. In 1992, 87 nations around the world agreed to halt the manufacture of halon fire extinguishers by January 1, 1994. This will eliminate a potential threat to the earth's protective ozone layer, which halon molecules—highly resistant to decomposition—interact with and destroy.

Most of the other elements of a fire extinguisher are made of metal. The pressure vessel is generally made of an aluminum alloy, while the valve can either be steel or plastic. Other components, such as the actuating handle, safety pins, and mounting bracket, are typically made of steel.

The Manufacturing
Process

Manufacture of the tank-type or cylinder fire extinguisher requires several manufacturing operations to form the pressure vessel, load the chemical agent, machine the valve, and add the hardware, hose, or nozzle.

Creating the pressure vessel

  • Pressure vessels are formed from puck-shaped (disc) blocks of special aluminum alloy. The puck is first impact extruded on a large press under great pressure. In impact extrusion, the aluminum block is put into a die and rammed at very high velocity with a metal tool. This tremendous energy liquifies the aluminum and causes it to flow into a cavity around the tool. The aluminum thus takes the form of an open-ended cylinder with considerably more volume than the original puck.

Necking and spinning

  • The necking process puts a dome on the open end of the cylinder by constricting the open end with another operation called spinning. Spinning gently rolls the metal together, increasing the wall thickness and reducing the diameter. After spinning, the threads are added.
  • The vessel is hydrostatically tested, cleaned, and coated with a powdered paint. The vessel is then baked in an oven where the paint is cured.

Adding the extinguishing agent

  • Next, the extinguishing agent is added. If the vessel is a "stored-pressure" type, the vessel is then pressurized accordingly. If a gas-cartridge is necessary to help expel the extinguishing agent, it is also inserted at this time.
  • After the extinguishing element is added, the vessel is sealed and the valve is added. The valve consists of a machined body made of metal bar stock on a lathe, or a plastic injected molded part on the economy versions. It must be leak free, and it must have provisions for threading into the cylinder.

Final assembly

  • The final manufacturing operation is the assembly of the actuating handle, safety pins, and the mounting bracket. These parts are usually cold formed—formed at low temperatures—steel or sheet metal forms, purchased by the manufacturer from an outside vendor. Identification decals are also placed on the cylinder to identify the proper fire class rating as well as the suitability for recharging. Many of the economy versions are for one time use only and cannot be refilled.

Quality Control

All fire extinguishers in the United States fall under the jurisdiction of the National Fire Protection Association (NFPA), Under-writer's Laboratories, The Coast Guard, and other organizations such as the New York Fire Department. Manufacturers must register their design and submit samples for evaluation before marketing an approved fire extinguisher.

One of the most crucial checkpoints during the manufacturing process occurs after the extinguishing agent is added and the vessel sealed. It is extremely important that the cylinder not leak down the pressurizing gas, because that would render the extinguisher useless. To check for leaks, a boot is placed over the cylinder to serve as an accumulator. A trace gas is released inside, and within two minutes any unacceptable rate of leakage can be recorded by sophisticated pressure and gas-detecting equipment. All extinguishers are leak tested.

The Future

With the gradual elimination of halon, a new, non-damaging agent will most likely replace the hazardous chemical within the next few years. In addition, new applications of the old designs are being seen; most prevalent are automatic heat and fire sensors that discharge the extinguisher without the need for an operator.

Where To Learn More

Books

Fire Prevention Handbook. Butterworths, London, 1986.

Mahoney, Gene. Introduction to Fire Apparatus & Equipment. 2nd ed., Fire Engineering Books & Videos, 1986.

Pamphlets

Portable Fire Extinguishing Equipment in Family Dwellings & Living Units. National Fire Protection Association, 1992.

[Article by: Douglas E. Betts and; Peter Toeg]


Sci-Tech Encyclopedia: Fire extinguisher
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Fire may be extinguished by the following methods: (1) cooling the burning materials; (2) blanketing the fire with inert gas that chokes it for lack of oxygen; (3) introducing materials that inhibit combustion; and (4) covering the burning matter with a blanket or a layer of solid particles that prevent access of air. Fire extinguishers operate on one or a combination of these principles.

Water is the most effective cooling agent used in fire extinguishing. The generation of steam also drives away the air and forms a blanket, but being less dense than air, it is rapidly displaced. Wetting agents and foaming agents increase the effectiveness of water. In the small, first-aid, water fire extinguishers, a propellant must be provided. Usually this is carbon dioxide, which is either generated when needed or stored in a cartridge. Water should not be used on oil fires or on electrical fires.

Automatic water sprinkler systems are a common form of fire protection in industrial plants and large buildings. The installation of these systems is the greatest single factor to be credited for the sharply reduced incidence of disastrous fires in recent years. See also Automatic sprinkler system.

Carbon dioxide is a safe and effective extinguisher for all confined fires. It acts as an inert blanket, and because it is heavier than air, it will exclude oxygen very efficiently from a fire on the floor of a building or in a vat or similar vessel. It is not effective in an elevated location or outdoors where the wind can blow the gas away.

A dry powder, consisting principally of sodium bicarbonate, may also be used as a fire extinguisher. The powder must have the correct particle size and contain materials that prevent it from caking. The action of the powder is threefold: to generate carbon dioxide; to cool the burning material; and to provide a shielding to prevent access of air. Dry chemical is useful for small fires, and especially electrical fires.

Carbon tetrachloride, CCl4, has had a long history as a fire-extinguishing agent. As it is customarily used, in small quantities, the principal action is to supply a heavy blanket of vapor over the fire. In addition, carbon tetrachloride, in common with all the halogenated compounds, has a definite chemical inhibiting effect on combustion. Other halogenated hydrocarbons that have been used are chlorobromomethane, and several of the fluorinated hydrocarbons known as freons. The principal difficulty, however, with all the halogenated hydrocarbons, and with CCl4, in particular, is toxicity.

Other extinguishing methods should be mentioned that require no special equipment. For a household fire, especially involving clothing on a person, a blanket or a rug provides an effective means to smother the fire. Small fires around a kitchen stove may be snuffed out with salt or, better still, with bicarbonate of soda. A bucket of sand, strategically located, is also useful against domestic fire hazards.


Insurance Dictionary: Fire Extinguisher
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Instrument that uses noncombustible substances such as carbon dioxide to deprive a fire of oxygen, thereby extinguishing it.

Architecture: fire extinguisher
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A portable device, for immediate and temporary use in putting out a fire: class A: used on fires involving ordinary combustible materials (such as wood, cloth, paper, rubber, and many plastics), which require the cooling effects of water or certain dry chemical coatings to retard combustion; class B: used on fires involving liquids, gases, greases, etc., extinguished most readily by excluding air or inhibiting the release of combustible vapors; class C: used on fires in “live” electrical equipment; class D: used on fires involving certain combustible metals, such as magnesium, sodium, etc., requiring a heat-absorbing extinguishing medium not reactive with the burning metals.


Wikipedia: Fire extinguisher
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A stored-pressure fire extinguisher

A fire extinguisher is an active fire protection device used to extinguish or control small fires, often in emergency situations. It is not intended for use on an out-of-control fire, such as one which has reached the ceiling, endangers the user (i.e. no escape route, smoke, explosion hazard, etc.), or otherwise requires the expertise of a fire department. Typically, a fire extinguisher consists of a hand-held cylindrical pressure vessel containing an agent which can be discharged to extinguish a fire.

There are two main types of fire extinguishers: stored pressure and cartridge-operated. In stored pressure units, the expellant is stored in the same chamber as the firefighting agent itself. Depending on the agent used, different propellants are used. With dry chemical extinguishers, nitrogen is typically used; water and foam extinguishers typically use air. Stored pressure fire extinguishers are the most common type. Cartridge-operated extinguishers contain the expellant gas in a separate cartridge that is punctured prior to discharge, exposing the propellant to the extinguishing agent. This type is not as common, used primarily in areas such as industrial facilities, where they receive higher-than-average use. They have the advantage of simple and prompt recharge, allowing an operator to discharge the extinguisher, recharge it, and return to the fire in a reasonable amount of time. Unlike stored pressure types, these extinguishers utilize compressed carbon dioxide instead of nitrogen, although nitrogen cartridges are used on low temperature (-60 rated) models. Cartridge operated extinguishers are available in dry chemical and dry powder types in the US and in water, wetting agent, foam, and dry powder (ABC, BC, or D) types in the rest of the world.

A cartridge-operated fire extinguisher

Fire extinguishers are further divided into handheld and cart-mounted, also called wheeled extinguishers. Handheld extinguishers weigh from 0.5 to 14 kilograms (1 to 30 pounds), and are hence, easily portable by hand. Cart-mounted units typically weigh 23+ kilograms (50+ pounds). These wheeled models are most commonly found at construction sites, airport runways, heliports, as well as docks and marinas.

Contents

History

A 1905 illustration marketing extinguishers.

The first fire extinguisher of which there is any record was patented in England in 1723 by Ambrose Godfrey, a celebrated chemist. It consisted of a cask of fire-extinguishing liquid containing a pewter chamber of gunpowder. This was connected with a system of fuses which were ignited, exploding the gunpowder and scattering the solution. This device was probably used to a limited extent, as Bradley's Weekly Messenger for November 7, 1729, refers to its efficiency in stopping a fire in London.

The modern fire extinguisher was invented by British Captain George William Manby in 1818; it consisted of a copper vessel of 3 gallons (13.6 litres) of pearl ash (potassium carbonate) solution contained within compressed air.


A classic copper building type soda-acid extinguisher

The soda-acid extinguisher was first patented in 1866 by Francois Carlier of France, which mixed a solution of water and sodium bicarbonate with tartaric acid, producing the propellant CO2 gas. A soda-acid extinguisher was patented in the U.S. in 1881 by Almon M. Granger. His extinguisher used the reaction between sodium bicarbonate solution and sulfuric acid to expel pressurized water onto a fire.[1] A vial was suspended in the cylinder containing concentrated sulfuric acid. Depending on the type of extinguisher, the vial of acid could be broken in one of two ways. One used a plunger to break the acid vial, whilst the second released a lead stopple that held the vial closed. Once the acid was mixed with the bicarbonate solution, carbon dioxide gas was expelled and thereby pressurize the water. The pressurized water was forced from the canister through a nozzle or short length of hose.

The cartridge-operated extinguisher was invented by Read & Campbell of England in 1881, which used water or water-based solutions. They later invented a carbon tetrachloride model called the "Petrolex" which was marketed toward automotive use.[2]

A chemical foam extinguisher with contents.

The chemical foam extinguisher was invented around 1905 by Alexander Laurant of Russia, who first used it to extinguish a pan of burning naphtha. It works and looks similar to the soda-acid type, but the inner parts are different. The main tank contains a solution of water, foam compound (usually made from licorice root) and sodium bicarbonate. A cylindrical metal or plastic chamber holds about a quart and a half of 13% aluminium sulfate and is capped with a lead cap. When the unit is turned over, the chemicals mix, producing CO2 gas. The licorice causes some of the CO2 bubbles to become trapped in the liquid and is discharged on the fire as a thick whitish-brown foam.

A brass carbon tetrachloride extinguisher from Pyrene

Around 1912 Pyrene[who?] invented the carbon tetrachloride (CTC) extinguisher, which expelled the liquid from a brass or chrome container by a handpump; it was usually of 1 imperial quart (1.1 L) or 1 imperial pint (0.6 L) capacity but was also available in up to 2 imperial gallon (9 L) size. A further variety consisted of a glass bottle "bomb" filled with the liquid that was intended to be hurled at the base of a fire. The CTC vaporized and extinguished the flames by creating a dense, oxygen-excluding blanket of fumes, and to a lesser extent, inhibiting the chemical reaction. The extinguisher was suitable for liquid and electrical fires, and was popular in motor vehicles for the next 60 years. In the 1940s, Germany invented the liquid chlorobromomethane (CBM) for use in aircraft. It was more effective and slightly less toxic than carbon tetrachloride and was used until 1969. Methyl Bromide was discovered as an extinguishing agent in the 1920s and was used extensively in Europe. It is a low-pressure gas that works by inhibiting the chain reaction of the fire and is the most toxic of the vaporizing liquids, used until the 1960s. The vapor and combustion by-products of all vaporizing liquids were highly toxic, and could cause death in confined spaces.

A glass "grenade" style extinguisher, to be thrown into a fire.

The carbon dioxide (CO2) extinguisher was invented (at least in the US) by the Walter Kidde Company in 1924 in response to Bell Telephone's request for an electrically non-conductive chemical for extinguishing the previously difficult to extinguish fires in telephone switchboards. It consisted of a tall metal cylinder containing 7.5 lbs. of CO2 with a wheel valve and a woven brass, cotton covered hose, with a composite funnel-like horn as a nozzle. CO2 is still popular today as it is an ozone-friendly clean agent and is useful for an extinguishing a person who is on fire, hence its widespread use in film and television.

An early dry chemical extinguisher, the first ones had copper cylinders, this one is steel.

In 1928, DuGas (later bought by ANSUL) came out with a cartridge-operated dry chemical extinguisher, which used sodium bicarbonate specially treated with chemicals to render it free-flowing and moisture-resistant. It consisted of a copper cylinder with an internal CO2cartridge. The operator turned a wheel valve on top to puncture the cartridge and squeezed a lever on the valve at the end of the hose to discharge the chemical. This was the first agent available for large scale three-dimensional liquid and pressurized gas fires, and was but remained largely a specialty type until the 1950s, when small dry chemical units were marketed for home use. ABC dry chemical came over from Europe in the 1950s, with Super-K being invented in the early 60s and Purple-K being developed by the US Navy in the late 1960s.

Halon 1211 came over to the US from Europe in the 1970s, where it had been used since the late 40s or early 50s. Halon 1301 had been developed by DuPont and the US Army in 1954. Both work by inhibiting the chain reaction of the fire, and in the case of Halon 1211, cooling class A fuels as well. Halon is still in use today, but is falling out of favor for many uses due to its environmental impact. Europe and Australia have severely restricted its use, but it is still widely available in North America, the Middle East, and Asia.

Classification

Internationally there are several accepted classification methods for hand-held fire extinguishers. Each classification is useful in fighting fires with a particular group of fuel.

Australia

Type Pre-1997   Current Suitable for use on Fire Classes (brackets denote sometimes applicable)
Water Solid red Solid red A        
Foam Solid blue Red with a blue band A B      
Dry chemical (powder) Red with a white band Red with a white band A B C E  
Carbon dioxide Red with a black band Red with a black band (A) B C E F
Vaporising liquid (not halon) Red with a yellow band Red with a yellow band A B C E  
Halon Solid green No longer produced A B E  
Wet chemical Solid oatmeal Red with an oatmeal band A F

In Australia, yellow (Halon) fire extinguishers are illegal to own or use on a fire, unless an essential use exemption has been granted.[3]

United Kingdom

Typical United Kingdom CO2 and water fire extinguishers

According to the standard BS EN 3, fire extinguishers in the United Kingdom as all throughout Europe are red RAL 3000, and a band or circle of a second color covering between 5-10% of the surface area of the extinguisher indicates the contents. Before 1997, the entire body of the fire extinguisher was color coded according to the type of extinguishing agent.

The UK recognizes Six fire classes:

  • Class A fires involve organic solids such as paper and wood.
  • Class B fires involve flammable liquids and liquifiable solids.
  • Class C fires involve flammable gases.
  • Class D fires involve metals.
  • Class E Electrical equipment.
  • Class F fires involve cooking fat and oil.

Fire extinguishing performance per fire class is displayed using numbers and letters such as 13A, 55B.

EN3 does not recognize a separate electrical class - however there is an additional feature requiring special testing (35 kV dielectric test per EN 3-7:2004). A powder or CO2 extinguisher will bear an electrical pictogram as standard signifying that it can be used on live electrical fires (given the symbol E in the table). If a water-based extinguisher has passed the 35 kV test it will also bear the same electrical pictogram - however, any water-based extinguisher is only recommended for inadvertent use on electrical fires.

Type Old Code   BS EN 3 Colour Code Suitable for use on Fire Classes (brackets denote sometimes applicable) [4]
Water Signal Red Signal Red A          
Foam Cream Red with a Cream panel above the operating instructions A B        
Dry powder Blue Red with a Blue panel above the operating instructions (A) B C   E  
Carbon dioxide CO2 Black Red with a Black panel above the operating instructions   B     E  
Wet chemical N/A Red with a Canary Yellow panel above the operating instructions A (B)       F
Class D powder Blue Red with a Blue panel above the operating instructions       D    
Halon gas Green Now prohibited except under certain situations.[4]            

In the UK the use of Halon gas is now prohibited except under certain situations such as on aircraft and in the military.[4]

United States

There is no official standard in the United States for the color of fire extinguishers, though they are typically red, except for Class D extinguishers, which are usually yellow, and water, which are usually silver, or white if water mist. Extinguishers are marked with pictograms depicting the types of fires that the extinguisher is approved to fight. In the past, extinguishers were marked with colored geometric symbols, and some extinguishers still use both symbols. The types of fires and additional standards are described in NFPA 10: Standard for Portable Fire Extinguishers, 2007 edition.

Fire Class Geometric Symbol   Pictogram Intended Use
A Green Triangle Garbage can and wood pile burning Ordinary solid combustibles
B Red Square Fuel container and burning puddle Flammable liquids and gases
C Blue Circle Electric plug and burning outlet Energized electrical equipment
D Yellow Pentagram (Star) Burning Gear and Bearing Combustible metals
K Black Hexagon Pan burning Cooking oils and fats

The Underwriters Laboratories rate fire extinguishing capacity in accordance with UL/ANSI 711: Rating and Fire Testing of Fire Extinguishers. The ratings are described using numbers preceding the class letter, such as 1-A:10-B:C. The number preceding the A multiplied by 1.25 gives the equivalent extinguishing capability in gallons of water. The number preceding the B indicates the size of fire in square feet that an ordinary user should be able to extinguish. There is no additional rating for class C, as it only indicates that the extinguishing agent will not conduct electricity, and an extinguisher will never have a rating of just C.

Installation

A fire extinguisher fitted to the passenger seat of a car.

Fire extinguishers are typically fitted in buildings at an easily-accessible location, such as against a wall in a high-traffic area. They are also often fitted to motor vehicles, watercraft, and aircraft - this is required by law in many jurisdictions, for identified classes of vehicles. Under NFPA 10 all commercial vehicles must carry at least one fire extinguisher (size/UL rating depending on type of vehicle and cargo (i.e.. fuel tankers typically must have a 9.1 kg (20 lb). when most others can carry a 2.3 kg (5 lb).) The revised NFPA 10 created criteria on the placement of "Fast Flow Extinguishers" in locations such as those storing and transporting pressurized flammable liquids and pressurized flammable gas or areas with possibility of three dimensional class B hazards are required to have "fast flow" extinguishers as required by NFPA 5.5.1.1. Varying classes of competition vehicles require fire extinguishing systems, the simplest requirements being a 1A:10BC hand-held portable extinguisher mounted to the interior of the vehicle.

Types of extinguishing agents

Dry chemical

Powder based agent that extinguishes by separating the four parts of the fire tetrahedron. It prevents the chemical reaction between heat, fuel and oxygen and halts the production of fire sustaining "free-radicals", thus extinguishing the fire.

  • Ammonium phosphate, also known as "tri-class", "multipurpose" or "ABC" dry chemical, used on class A, B, and C fires. It receives its class A rating from the agent's ability to melt and flow at 177 °C (350 °F) to smother the fire. More corrosive than other dry chemical agents. Pale yellow in color.
  • Sodium bicarbonate, "regular" or "ordinary" used on class B and C fires, was the first of the dry chemical agents developed. It interrupts the fire's chemical reaction, and was very common in commercial kitchens before the advent of wet chemical agents, but now is falling out of favor, as it is much less effective than wet chemical agents for class K fires, less effective than Purple-K for class B fires, and is ineffective on class A fires. White or blue in color.
  • Potassium bicarbonate (aka Purple-K), used on class B and C fires. About two times as effective on class B fires as sodium bicarbonate, it is the preferred dry chemical agent of the oil and gas industry. The only dry chemical agent certified for use in ARFF by the NFPA. Violet in color.
  • Potassium bicarbonate & Urea Complex (aka Monnex), used on Class B and C fires. More effective than all other powders due to its ability to decrepitate (where the powder breaks up into smaller particles) in the flame zone creating a larger surface area for free radical inhibition.
  • Potassium Chloride, or Super-K dry chemical was developed in an effort to create a high efficiency, protein-foam compatible dry chemical. Developed in the 60s, prior to Purple-K, it was never as popular as other agents since being a salt, it was quite corrosive. For B and C fires, white in color.
  • Foam-Compatible, which is a sodium bicarbonate (BC) based dry chemical, was developed for use with protein foams for fighting class B fires. Most dry chemicals contain metal stearates to waterproof them, but these will tend to destroy the foam blanket created by protein (animal) based foams. Foam compatible type uses silicone as a waterproofing agent, which does not harm foam. Effectiveness is identical to regular dry chemical, and it is light green in color (some ANSUL brand formulations are blue). This agent is generally no longer used since most modern dry chemicals are considered compatible with synthetic foams such as AFFF.
  • MET-L-KYL is a specialty variation of sodium bicarbonate for fighting pyrophoric liquid fires (ignite on contact with air). In addition to sodium bicarbonate, it also contains silica gel particles. The sodium bicarbonate interrupts the chain reaction of the fuel and the silica soaks up any unburned fuel, preventing contact with air. It is effective on other class B fuels as well. Blue/Red in color.

Foams

A 2-1/2 gallon AFFF foam fire extinguisher

Applied to fuel fires as either an aspirated (mixed & expanded with air in a branch pipe) or non aspirated form to form a frothy blanket or seal over the fuel, preventing oxygen reaching it. Unlike powder, foam can be used to progressively extinguish fires without flashback.

  • AFFF (aqueous film forming foam), used on A and B fires and for vapor suppression. The most common type in portable foam extinguishers. It contains fluoro tensides [5] which can be accumulated in human body. The long-term effects of this on the human body and environment are unclear at this time.
  • AR-AFFF (Alcohol-resistant aqueous film forming foams), used on fuel fires containing alcohol. Forms a membrane between the fuel and the foam preventing the alcohol from breaking down the foam blanket.
  • FFFP (film forming fluoroprotein) contains naturally occurring proteins from animal by-products and synthetic film-forming agents to create a foam blanket that is more heat resistant than the strictly synthetic AFFF foams. FFFP works well on alcohol-based liquids and is used widely in motorsports.
  • CAFS (compressed air foam system) Any APW style extinguisher that is charged with a foam solution and pressurized with compressed air. Generally used to extend a water supply in wildland operations. Used on class A fires and with very dry foam on class B for vapor suppression.
  • Arctic Fire is a liquid fire extinguishing agent that emulsifies and cools heated materials more quickly than water or ordinary foam. It is used extensively in the steel industry. Effective on classes A, B, and D.
  • FireAde, a foaming agent that emulsifies burning liquids and renders them non-flammable. It is able to cool heated material and surfaces similar to CAFS. Used on A and B (said to be effective on some class D hazards, although not recommended due to the fact that fireade still contains amounts of water which will react with some metal fires).


An American water extinguisher

Water

Cools burning material.

  • APW (Air pressurized water) cools burning material by absorbing heat from burning material. Effective on Class A fires, it has the advantage of being inexpensive, harmless, and relatively easy to clean up. In the United States, APW units contain 2.5 gallons (9 litres) of water in a tall, stainless steel cylinder. In Europe, they are typically mild steel lined with polyethylene, painted red, containing 6-9 litres (1.75-2.5 gallons) of water.
  • Water Mist uses a fine misting nozzle to break up a stream of deionized water to the point of not conducting electricity back to the operator. Class A and C rated. It is used widely in hospitals for the reason that, unlike other clean-agent suppressants, it is harmless and non-contaminant. These extinguishers come in 1.75 and 2.5 gallon units, painted white in the United States and red in Europe.

Wet chemical and water additives

  • Wet Chemical (potassium acetate, carbonate, or citrate) extinguishes the fire by forming a soapy foam blanket over the burning oil (saponification) and by cooling the oil below its ignition temperature. Generally class A and K (F in Europe) only, although newer models are outfitted with misting nozzles as those used on water mist units to give these extinguishers class B and C firefighting capability.
  • Wetting Agents Detergent based additives used to break the surface tension of water and improve penetration of Class A fires.
  • Antifreeze Chemicals added to water to lower its freezing point to about -40 degrees Fahrenheit. Has no appreciable effect on extinguishing performance.

Clean agents and carbon dioxide

A 5lb. CO2 fire extinguisher

Agent displaces oxygen (CO2 or inert gases), removes heat from the combustion zone (Halotron, FE-36) or inhibits chemical chain reaction (Halons). They are labelled clean agents because they do not leave any residue after discharge which is ideal for sensitive electronics and documents.

  • Halon (including Halon 1211 and Halon 1301), a gaseous agent that inhibits the chemical reaction of the fire. Classes B:C for lower weight fire extinguishers (2.3 kg ; under 9 lbs) and A:B:C for heavier weights (4.1-7.7 kg ; 9-17 lbs). Banned from new production, except for military use, as of January 1, 1994 as its properties contribute to ozone depletion and long atmospheric lifetime, usually 400 years. Halon was completely banned in Europe resulting in stockpiles being sent to the United States for reuse. Although production has been banned, the reuse is still permitted. Halon 1301 and 1211 are being replaced with new halocarbon agents which have no ozone depletion properties and low atmospheric lifetimes, but are less effective. Currently Halotron I, Halotron II, FE-36 Cleanguard and FM-200 are meant to be replacements with significantly reduced ozone depletion potential.
  • CO2, a clean gaseous agent which displaces oxygen. Highest rating for 7.7 kg (20 pound) portable CO2 extinguishers is 10B:C. Not intended for Class A fires, as the high-pressure cloud of gas can scatter burning materials. CO2 is not suitable for use on fires containing their own oxygen source, metals or cooking media. Although it can be rather successful on a person on fire, its use should be avoided where possible as it can cause chemical burns and is dangerous to use as it may displace the oxygen needed for breathing, causing suffocation.
  • Mixtures of inert gases, including Inergen and Argonite.

Class D

A class D fire extinguisher for various metals

There are several Class D fire extinguisher agents available, some will handle multiple types of metals, others will not.

  • Copper based (Copper Powder Navy125S) -developed by the U.S. Navy in the 70s for hard-to-control lithium and lithium-alloy fires. Powder smothers and acts as a heat sink to dissipate heat, but also forms a copper-lithium alloy on the surface which is non-combustible and cuts off the oxygen supply. Will cling to a vertical surface-lithium only.
  • Graphite based (G-Plus, G-1, Lith-X, Pyromet or METAL.FIRE.XTNGSHR) -contains dry graphite that smothers burning metals. First type developed, designed for magnesium, works on other metals as well. Unlike sodium chloride powder extinguishers, the graphite powder fire extinguishers can be used on very hot burning metal fires such as lithium, but unlike copper powder extinguishers will not stick to and extinguish flowing or vertical lithium fires. Like copper extinguishers, the graphite powder acts as a heat sink as well as smothering the metal fire.
  • Sodium carbonate based (Na-X)-used where stainless steel piping and equipment could be damaged by sodium chloride based agents to control sodium, potassium, and sodium-potassium alloy fires. Limited use on other metals. Smothers and forms a crust.

Water-based chemicals should never be used on metal fires due to the possibility of a violent reaction.

Most Class D extinguishers will have a special low velocity nozzle or discharge wand to gently apply the agent in large volumes to avoid disrupting any finely divided burning materials. Agents are also available in bulk and can be applied with a scoop or shovel.

Fire Extinguishing Ball

Several modern ball or "grenade" style extinguishers are on the market. They are manually operated by rolling or throwing into a fire. The modern version of the ball will self destruct once in contact with flame, dispersing a cloud of ABC dry chemical powder over the fire which extinguishes the flame. The coverage area is about 5 square meters. One benefit of this type is that it may be used for passive suppression. The ball can be placed in a fire prone area and will deploy automatically if a fire develops, being triggered by heat. Most modern extinguishers of this type are designed to make a loud noise upon deployment.[6]

This technology is not new, however. In the 1800s, glass fire grenades filled with suppressant liquids were popular. These glass fire grenade bottles are sought by collectors. [7] Some later brands, such as Red Comet, were designed for passive operation, and included a special holder with a spring loaded trigger that would break the glass ball when a fusible link melted. As was typical of this era, some glass extinguishers contained the toxic carbon tetrachloride.

Maintenance

An empty fire extinguisher which was not replaced for years.

Most countries in the world require regular fire extinguisher maintenance by a competent person to operate safely and effectively, as part of fire safety legislation. Lack of maintenance can lead to an extinguisher not discharging when required, or rupturing when pressurized. Deaths have occurred, even in recent times, from corroded extinguishers exploding.

There is no all-encompassing fire code in the United States. Generally, most municipalities (by adoption of the International Fire Code) require inspections every 30 days to ensure the unit is pressurized and unobstructed (done by an employee of the facility) and an annual inspection by a qualified technician. Hydrostatic pressure testing for all types of extinguishers is also required, generally every five years for water and CO2 models up to every 12 years for dry chemical models.

Recently the National Fire Protection Association and ICC voted to allow for the elimination of the 30 day inspection requirement so long as the fire extinguisher is monitored electronically. According to NFPA, the system must provide record keeping in the form of an electronic event log at the control panel. The system must also constantly monitor an extinguisher’s physical presence, internal pressure and whether an obstruction exists that could prevent ready access. In the event that any of the above conditions are found, the system must send an alert to officials so they can immediately rectify the situation. Electronic monitoring can be wired or wireless.

In the UK, three types of maintenance are required:

  • Basic Service: All types of extinguisher require a basic inspection annually to check weight, correct pressure (using a special tool, not just looking at the gauge) and for signs of damage or corrosion, cartridge extinguishers are opened up for internal inspection & check weighing of the cartridge, labels are checked for legibility, where possible dip tubes, hoses and mechanisms checked for clear free operation.
  • Extended Service: Water, Wet Chemical, Foam & Powder extinguishers require every five years a more detailed examination including a test discharge of the extinguisher and recharging- on stored pressure extinguishers this is the only opportunity to internally inspect for damage/corrosion. By recharging fresh agent is used as they all have a shelf life, even water goes foul inside an extinguisher; Note: extinguishers should be percentage tested according to total number of units in any given area. Some extinguishers contain pressure in excess of 1.38 MPa (200psi) and this internal pressure over periods of time affects each brand & make differently depending on their placement & location.
  • Overhaul: CO2 extinguishers, due to their high operating pressure, are subject to pressure vessel safety legislation and must be hydraulic pressure tested, inspected internally & externally and date stamped every 10 years. As it cannot be pressure tested a new valve is also fitted. If replacing any part of the extinguisher (valve, horn, etc) with a part from another manufacturer then the extinguisher will lose its fire rating. This may invalidate insurance, as would incorrect or inadequate servicing if it were to be found.

In the United States there are 3 types of service as well:

  • Maintenance Inspection: All types, annually (with the exception of water types which require a yearly recharge), consists of a physical maintenance and visual inspection. The extinguisher is checked to make sure it has good pressure (gauge in green or proper cartridge weight), has the correct volume of agent (tech weighs it), is within the required hydrotest and internal maintenance intervals, is in good condition and all external parts are serviceable. Dry chemical and dry powder types are hit on the bottom with a rubber mallet to make sure the powder is free-flowing, which is called "fluffing" the powder. The tech will then attach a new tamper seal around the pin and a yearly service tag.
  • Internal Maintenance: Water-annually, foam-every 3 years, wet chemical and CO2, every 5 years, dry chemical, dry powder, halon and clean agents, 6 years.

The extinguisher is emptied of its chemical and pressure to check for proper operation. All components are disassembled, inspected, cleaned, lubricated, or replaced if defective. Liquid agents are replaced at this time, dry agents may be re-used if in good condition, halon is recovered and re-used, but CO2 is discharged into the atmosphere. The extinguisher is then re-filled and recharged, after a "verification of service" collar is placed around the cylinder neck. It is impossible to properly install or remove a collar without depressurizing the extinguisher. Note: Cartridge-operated extinguishers should be visually examined, but do not require a verification of service collar.

  • Hydrostatic testing: Water, Foam, Wet chemical, and CO2, every 5 years. Dry chemical, dry powder, halon, and clean agents, every 12 years.

Extinguishers installed on vehicles every 5 years regardless of type.

Note: these are the required intervals for normal service conditions, if the extinguisher has been exposed to excessive heat, vibration, or mechanical damage it may need to be tested sooner.

The agent is emptied and depressurized and the valve is removed. After a thorough internal and external visual inspection, the cylinder is filled with water, placed inside a safety cage, and pressurized to the specified test pressure (varies with the type, age, and cylinder material) for the specified time period. If no failure, bulges, or leaks are detected, the cylinder passes. The cylinder is then emptied of water and thoroughly dried. CO2 types have the test date, company's ID, etc. stamped on the cylinder, all other types get a sticker on the back of the cylinder. Once dry, the units are recharged. Unlike the UK, the US does not rebuild extinguishers and replace valves at specific intervals unless parts are found to be defective, with the exception of halon. Halon types are often given new o-rings and valve stems at every internal maintenance to minimize any leakage potential.

OEM equipment must be used for replacement parts for the extinguisher to maintain its UL rating. If parts are unavailable, replacement is recommended, keep in mind extinguishers have a projected service life of about 25–35 years, although many are of such quality that they can outlast this, but realize that science is ever-changing, and something that was the best available 30 years ago may not be acceptable for modern fire protection needs.

Vandalism and extinguisher protection

A fire extinguisher stored inside a cabinet mounted to a wall

Fire extinguishers can be a target of vandalism in schools and other open spaces. Extinguishers can be partially or fully discharged by a vandal, impairing the extinguisher's actual firefighting abilities.

In open public spaces, extinguishers are ideally kept inside cabinets that have glass that must be broken to access the extinguisher, or which emit an alarm siren that cannot be shut off without a key, to alert people the extinguisher has been handled by an unauthorized person when a fire is not present.

Fire extinguisher signs

Heavy-duty CO2-powered fire extinguisher on standby at a temporary helicopter landing site

Fire extinguisher identification signs are small signs designed to be mounted near a fire extinguisher, in order to draw attention to the extinguisher's location (Ex. If the Extinguisher is on a large pole the sign would generally be at the top of the pole so it can be seen from a distance) Such signs may be manufactured from a variety of materials, commonly self-adhesive vinyl, rigid PVC and aluminum.

In addition to words and pictographs indicating the presence of a fire extinguisher , some modern extinguisher ID signs also describe the extinguishing agent in the unit, and summarize the types of fire on which it may safely be used.

Some public and government buildings are often required, by local legal codes, to provide an ID sign for each extinguisher on the site.[8]

Similar signs are available for other fire equipment (including fire blankets and fire hose reels/racks), and for other emergency equipment (such as first aid kits).

Placement of fire extinguisher signs

Fire extinguisher signs are mounted above or to the side of the extinguisher they relate to.

Most licensing authorities have regulations describing the standard appearance of these signs (e.g. text height, pictographs used and so on).[9]

Photo-luminescent fire extinguisher signs

Photo-luminescent fire extinguisher signs are made with a photoluminescent phosphor that absorbs ambient light and releases it slowly in dark conditions - the sign "glows in the dark". Such signs are independent of an external power supply, and so offer a low-cost, reliable means of indicating the position of emergency equipment in dark or smoky conditions.

Photo-luminescent signs are sometimes wrongfully described as being reflective. A reflective material will only return ambient light for as long as the light source is supplied, rather than storing energy and releasing it over a period of time. However, many fire extinguishers and extinguisher mounting posts have strips of retroreflective adhesive tape placed on them to facilitate their location in situations where only emergency lighting or flashlights are available now.

References

  • Automatic Sprinkler Protection - Goram Dana, S.B.

External links


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Dictionary. The American Heritage® Dictionary of the English Language, Fourth Edition Copyright © 2007, 2000 by Houghton Mifflin Company. Updated in 2009. Published by Houghton Mifflin Company. All rights reserved.  Read more
How Products are Made. How Products are Made. Copyright © 2002 by The Gale Group, Inc. All rights reserved.  Read more
Sci-Tech Encyclopedia. McGraw-Hill Encyclopedia of Science and Technology. Copyright © 2005 by The McGraw-Hill Companies, Inc. All rights reserved.  Read more
Insurance Dictionary. Dictionary of Insurance Terms. Copyright © 2000 by Barron's Educational Series, Inc. All rights reserved.  Read more
Architecture. McGraw-Hill Dictionary of Architecture and Construction. Copyright © 2003 by McGraw-Hill Companies, Inc. All rights reserved.  Read more
Wikipedia. This article is licensed under the Creative Commons Attribution/Share-Alike License. It uses material from the Wikipedia article "Fire extinguisher" Read more