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The 3rd carbon atom in hexan-3-ol is asymmetric so arrange four groups around this carbon atom in two ways the one should be mirror image of other now these are two optical isomers, d-hexan-3-ol and l-hexan-3-ol.

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The 3rd carbon atom in hexan-3-ol is asymmetric so arrange four groups around this carbon atom in two ways the one should be mirror image of other now these are two optical isomers, d-hexan-3-ol and l-hexan-3-ol.

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