An atheist is simply someone who does not believe in a god or
gods.
A freethinker is someone with a philosophical viewpoint that
holds that opinions should be formed on the basis of logic, reason
and science and not authority, tradition, or other dogmas.
So, while the term "atheist" only answers the question of belief
in gods, the term "freethinker" describes a person's philosophical
viewpoint. In short, yes, you can be both an atheist and a
freethinker.