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fuller's earth

 
(fʊl'ərz)
n.
A highly adsorbent claylike substance consisting of hydrated aluminum silicates, used predominantly in fulling woolen cloth, in talcum powders, as a filter, and as a catalyst.


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Any natural earthy material that decolorizes mineral and vegetable oils and has high sorbent capacity for water and oil. The term fuller's earth has no genetic or mineralogic significance. However, the most common earthy materials classed as fuller's earth are calcium montmorillonites and palygorskites (attapulgites) and sepiolites. The term originated in England, where in ancient times raw wool was cleaned by kneading it in water with clay materials that adsorbed dirt and lanolin. The process was known as fulling, and the clay or earth became known as fuller's earth. See also Adsorption; Montmorillonite; Sepiolite.

Several clay deposits in the world are mined and processed for their absorbent, adsorbent, and decolorizing or bleaching properties. Some clays have a high natural decolorizing ability; however, in most instances a clay, normally a calcium montmorillonite, is acid-activated to enhance its bleaching or decolorizing properties. Sulfuric acid is commonly used, and in the treatment process sodium, calcium, magnesium, and iron that occupy the cation exchange sites on the clay surface are removed by the acid and replaced by hydrogen. Also, some aluminum, iron, or magnesium is removed from the mineral structure, increasing the negative charge on the clay surface. These highly charged surfaces covered with hydrogen ions selectively absorb the color bodies and other impurities in the oil. See also Clay; Clay minerals.

The largest applications for fuller's earth are as sorbents, and by far the biggest market is pet-litter production. Other large sorbent applications are as carriers for insecticides, pesticides, and fertilizers used in agriculture and as absorbers of oil and water spills on the floors of machine shops, factories, service stations, and other manufacturing plants for safety purposes.


An adsorbent clay, calcium montmorillonite, or bentonite; adsorbs both by physical means and by ion exchange. Used to bleach oils, clarify liquids, and absorb grease.

A naturally occurring earthy substance, somewhat similar to potter’s clay but lacking its plasticity; used as a poultice to remove stains from stonework on a building.


Columbia Encyclopedia:

fuller's earth

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fuller's earth, mineral substance characterized by the property of absorbing basic colors and removing them from oils. It is composed mainly of alumina, silica, iron oxides, lime, magnesia, and water, in extremely variable proportions, and is generally classified as a sedimentary clay. In color it may be whitish, buff, brown, green, olive, or blue. It is semiplastic or nonplastic and may or may not disintegrate easily in water. It was originally used in the fulling of wool to remove oil and grease but is now used chiefly in bleaching and clarifying petroleum and secondarily in refining edible oils. Fuller's earth is mined in many parts of the United States, Georgia and Florida being the leading producers, and in England near Reigate, Nutfield, and Bath. Before it can be used, it has to be crushed and dried.


Science Q&A:

What is fuller's earth?

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It is a naturally occurring white or brown clay containing aluminum magnesium silicate. Fuller's earth acts as a catalyst and was named for a process known as fulling-a process used to clean grease from wool and cloth. It is currently used for lightening the color of oils and fats, as a pigment extender, as a filter, as an absorbent (for example, in litter boxes to absorb animal waste), and in floor sweeping compounds.

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a naturally occurring, porous, absorptive aluminium-magnesium silicate clay. It is useful for decolorizing oils and other liquids and as a filtering medium. It is so-called because it was originally used to full (i.e. cleanse and thicken) wool and woollen cloth.

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Saunders Veterinary Dictionary:

fuller's earth

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An absorbent, commonly used in dusting powders.

Wikipedia on Answers.com:

Fuller's earth

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Fuller's earth is any non-plastic clay or clay-like earthy material used to decolorize, filter, and purify animal, mineral, and vegetable oils and greases.

Contents

Occurrence and composition

Output of fuller's earth in 2005

In 2005, the United States was the largest producer of fuller's earth with an almost 70% world share followed at a distance by Japan and Mexico.

Fuller's earth usually has a high magnesium oxide content. In the United States, two varieties of fuller's earth are mined, mainly in the southeastern states. These comprise the minerals montmorillonite or palygorskite (attapulgite) or a mixture of the two; some of the other minerals that may be present in fuller's earth deposits are calcite, dolomite, and quartz.

In England, fuller's earth occurs mainly in the Lower Greensand. It has also been mined in the Vale of White Horse, Oxfordshire, England. The Combe Hay Mine was a fuller's earth mine operating to the south of Bath, Somerset until 1979.[1] Other sites south of Bath included Frome, Lonsdale, Englishcombe Tucking Mill and Duncorn Hill.[2] Although these sites had been used since Roman times William Smith developed new methods for the identification of deposits of Fuller's earth to the south of Bath.[3] Other English sources include a mine near Redhill, Surrey (worked until 2000), and Woburn, Bedfordshire, where production ceased in 2004.

In some countries calcium bentonite is known as fuller's earth, a term that can also refer to attapulgite, a mineralogically distinct clay mineral that exhibits similar properties.

Hills, cliffs, and slopes that contain fuller's earth can be unstable, since this material can be thixotropic, when saturated by heavy rainfall.

Uses

The name reflects the first use of the material. In past centuries, fullers kneaded fuller's earth and water into woollen cloth to absorb lanolin, oils, and other greasy impurities as part of the cloth finishing process. Similarly, it has been used as an ingredient in powdered, "dry" shampoos. Fuller's earth was also sold in pharmacies until recently for compressing pills and cleaning hats and fabrics.[4]

Important uses are in absorbents and filters. Because of this, it is used (with activated charcoal) in the treatment of paraquat overdose to prevent the progression to pulmonary fibrosis. Fuller's earth is also used by military and civil emergency service personnel to decontaminate the clothing and equipment of soldiers and CBRN (Chemical Biological Radiological Nuclear) responders who have been contaminated with chemical agents.[5]

See also

References

  1. ^ A. B. Hawkins, M. S. Lawrence and K. D. Privett (September 1986). "Clay Mineralogy and Plasticity of the Fuller's Earth Formation Bath, UK". Clay Minerals (The Mineralogical Society) 21 (3): 293–310. doi:10.1180/claymin.1986.021.3.04. http://www.minersoc.org/pages/Archive-CM/Volume_21/21-3-293.pdf. Retrieved 2009-09-05. 
  2. ^ Mineral statistics of the United Kingdom of Great Britain and Ireland, 1855, http://books.google.co.uk/books?id=nr8MAAAAYAAJ&pg=RA2-PA148 
  3. ^ Macmillen, Neil (2009). A history of the Fuller's Earth mining industry around Bath. Lydney: Lightmoor Press. pp. 9. ISBN 9781899889327. 
  4. ^ Gray Cross Prescription Purity Fuller's Earth "Uses: Used for cleaning hats and fabrics" Rabin Company, Los Angeles, USA, circa 1958
  5. ^ Survive to Fight, British Army CBRN Publication, 2008
  • British Geological Survey, Mineral Fact Sheet: Fuller's Earth [1] (accessed 7 August 2009).
  • "fuller's earth". Encyclopædia Britannica. Encyclopædia Britannica Online. 2006. 9035638. http://www.britannica.com/eb/article-9035638. Retrieved 2006-11-02. 
  • Oxford English Dictionary, Second Edition. Oxford: Oxford U P, 1989.


Further reading

  • Brady, G.S., Clauser, H.R., & Vaccari, J.A. (2002). Materials handbook. (15th ed.) New York: McGraw-Hill.
  • Hosterman, J.W. and S.H. Patterson. (1992). Bentonite and Fuller's earth resources of the United States [U.S. Geological Survey Professional Paper 1522]. Washington, D.C.: United States Government Printing Office.

External links


 
 

 

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American Heritage Dictionary. The American Heritage® Dictionary of the English Language, Fourth Edition Copyright © 2007, 2000 by Houghton Mifflin Company. Updated in 2009. Published by Houghton Mifflin Company. All rights reserved.  Read more
McGraw-Hill Science & Technology Encyclopedia. McGraw-Hill Encyclopedia of Science and Technology. Copyright © 2005 by The McGraw-Hill Companies, Inc. All rights reserved.  Read more
Oxford Food & Nutrition Dictionary. A Dictionary of Food and Nutrition. Copyright © 1995, 2003, 2005 by A. E. Bender and D. A. Bender. All rights reserved.  Read more
McGraw-Hill Dictionary of Architecture & Construction. McGraw-Hill Dictionary of Architecture and Construction. Copyright © 2003 by McGraw-Hill Companies, Inc. All rights reserved.  Read more
Columbia Encyclopedia. The Columbia Electronic Encyclopedia, Sixth Edition Copyright © 2012, Columbia University Press. Licensed from Columbia University Press. All rights reserved. www.cc.columbia.edu/cu/cup/ Read more
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 Oxford Dictionary of Biochemistry. Oxford University Press. Oxford Dictionary of Biochemistry and Molecular Biology © 1997, 2000, 2006 All rights reserved.  Read more
Saunders Veterinary Dictionary. Saunders Comprehensive Veterinary Dictionary 3rd Edition. Copyright © 2007 by D.C. Blood, V.P. Studdert and C.C. Gay, Elsevier. All rights reserved.  Read more
Wikipedia on Answers.com. This article is licensed under the Creative Commons Attribution/Share-Alike License. It uses material from the Wikipedia article Fuller's earth Read more

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