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hemimorphite

 
Dictionary: hem·i·mor·phite   (hĕm'ĭ-môr'fīt') pronunciation
n.
A usually white or colorless mineral, essentially Zn4Si2O7(OH)2·H2O, an important ore of zinc. Also called calamine.

[HEMIMORPH(IC) + -ITE1.]


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Sci-Tech Encyclopedia: Hemimorphite
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A mineral sorosilicate having the composition Zn4Si2O7(OH)2.H2O; an ore of zinc. Crystals are usually colorless and the aggregates white, but in some cases there are faint shades of green, yellow, and blue. The mineral has a vitreous luster, a hardness of 4½ to 5 on Mohs scale, and a specific gravity of 3.45.

Hemimorphite has a wide distribution and has been mined in Belgium, Germany, Romania, England, Algeria, and Mexico. In the United States it is found at Sterling Hill, New Jersey; Friedensville, Pennsylvania; and Elkhorn Mountains, Montana. See also Silicate minerals.


Rock & Mineral Guide: hemimorphite
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Zn
Orthorhombic -- Rhombic pyramidal

Environment

The oxidized zone of zinc deposits.

Crystal description

Commonly crystallized in flattened prismatic plates up to an inch (2-3 cm) in length, attached at the base so that the unlike array of the lower end (indicative of its hemimorphism) is not apparent. Also in mammillary rounded groups with convexly crystallized surfaces (Franklin, New Jersey) and in smoother botryoidal knobs, granular, massive, and earthy.

Physical properties

White, sometimes slightly stained with iron or copper (brown and blue or green). Luster glassy; hardness 4Ɖ-5; specific gravity 3.4-3.5; fracture uneven to poor conchoidal; cleavage prismatic. Transparent to translucent. Strongly susceptible to electrical charges with changing temperature (pyroelectric); often fluorescent pale orange in longwave ultraviolet light.

Composition

Alkaline hydrated zinc silicate (67.5% ZnO, 25.0% SiO 2 , 7.5% H 2 O).

Tests

Decrepitates, and readily becomes frosted; develops a coating, yellow when hot, turning white when cold. Following roasting, fluoresces bright orange in longwave ultraviolet, white in shortwave ultraviolet.

Distinguishing characteristics

Distinguished from smithsonite by its lack of bubbling in acid; recognized as a zinc mineral by its colored coating after blowpiping. Heavier than prehnite, not found in basalts, and not associated with the similar zeolites.

Occurrence

No longer a significant American mineral. The best U.S. specimens were found in the Stone Mine, Leadville, Colorado, and at Elkhorn, Montana. Solid masses of white, giant crawling-caterpillar-like crystalline surfaces were obtained in the early days at Franklin, New Jersey. Excellent bladed examples now come from Mapimi, Durango, Mexico, with crystals 1 in. (2.5 cm) and more in length standing up in limonitic gossan pockets. Crusts of upstanding, flat, and well-terminated crystals Ɖ to 4 in. (1-7 cm) long and 蔹-ƈ in. (1-3 mm) broad, have likewise been found at Santa Eulalia, Chihuahua, Mexico, many smaller ones protruding like hedgehog spines from white dolomite rhombohedrons and more delicate than most hemimorphites. Any remaining crystals from the Joplin, Missouri, district are small, on cavernous ocher hemimorphite masses mixed with a brown and earthy smithsonite ("dry-bone ore").

Remarks

The old name, calamine, was once widely used but has been changed by international consent to hemimorphite, which describes the asymmetrical crystal class (no center of symmetry) to which it belongs. The current name eliminates centuries of confusion resulting from the European miner's use of "calamine" for both carbonate and silicate.



WordNet: hemimorphite
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Note: click on a word meaning below to see its connections and related words.

The noun has one meaning:

Meaning #1: a white mineral; a common ore of zinc
  Synonym: calamine


Wikipedia: Hemimorphite
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Hemimorphite

Hemimorphite from Mapimi, Durango, Mexico
General
Category Mineral
Chemical formula Zn4Si2O7(OH)2·H2O
Identification
Color White, blue, greenish
Crystal habit Polar crystals, with different or hemimorphic ends. Also coxcomb masses, mammillary, stalactitic, or massive
Crystal system Orthorhombic
Cleavage Perfect
Fracture Uneven to conchoidal
Mohs scale hardness 4.5-5
Luster Vitreous, silky
Specific gravity 3.516 - 3.525
Refractive index Transparent to translucent
Solubility Soluble in acid

Hemimorphite, is a sorosilicate mineral which has been mined from days of old from the upper parts of zinc and lead ores, chiefly associated with smithsonite. It was often assumed to be the same mineral and both were classed under the same name of calamine. In the second half of the 18th century it was discovered that there were two different minerals under the heading of calamine - a zinc carbonate and a zinc silicate, which often closely resembled each other.

The silicate was the more rare of the two, and was named hemimorphite because of the hemimorph development of its crystals. This unusual form, which is typical of only a few minerals, means that the crystals are terminated by dissimilar faces. Hemimorphite most commonly forms crystalline crusts and layers, also massive, granular, rounded and reniform aggregates, concentrically striated, or finely needle-shaped, fibrous or stalactitic, and rarely fan-shaped clusters of crystals.

Some specimens show strong green fluorescence in shortwave ultraviolet light (253.7 nm) and weak light pink fluorescence in longwave UV.

Occurrence

Hemimorphite most frequently occurs as the product of the oxidation of the upper parts of sphalerite bearing ore bodies, accompanied by other secondary minerals which form the so-called iron cap or gossan. Hemimorphite is an important ore of zinc and contains up to 54.2% of the metal.

Hemimorphite

The regions on the Belgian-German border are well known for their deposits of hemimorphite of metasomatic origin, especially Vieille Montagne in Belgium and Aachen in Germany. Other deposits are near Tarnovice in upper Silesia, Poland; near Phoenixville, Pennsylvania; the Missouri lead-zinc district; Elkhorn, Montana; Leadville, Colorado; and Organ Mountains, New Mexico in the United States; and in several localities in North Africa. Further hemimorphite occurrences are the Padaeng deposit near Mae Sod in western Thailand; Sardinia; Nerchinsk, Siberia; Cave del Predil, Italy; Bleiberg, Carinthia, Austria; Matlock, Derbyshire, England.

Use

Zinc silicate (Zn2SiO4, CAS number [68611-47-2], EINECS number 271-896-0), whether prepared from hemimorphite or from quartz and zinc oxide, can be used as a food additive, as an anti-caking agent for dry foods. As such, its E number is E557. [1] However its use is rare and its status is now unpermitted.

Zinc silicate, doped with manganese, sometimes with addition of arsenic or antimony, is often used as a green phosphor for display tubes, plasma displays, and fluorescent lamps.

Zinc silicate can be also used as a corrosion inhibitor pigment for some primers. [2] In such application it may be called Inorganic Zinc Silicate (IZS). The paint is composed of ethyl silicate and zinc powder. [3]

Zinc silicate can be also a component of some glass ionomer dental cements. [4]

References

  • Hurlbut, Cornelius S.; Klein, Cornelis, 1985, Manual of Mineralogy, 20th ed., ISBN 0-471-80580-7
  • Boni, M., Gilg, H.A., Aversa, G., and Balassone, G., 2003, The "Calamine" of southwest Sardinia: Geology, mineralogy, and stable isotope geochemistry of supergene Zn mineralization: Economic Geology, v. 98, p. 731-748.
  • Reynolds, N.A., Chisnall, T.W., Kaewsang, K., Keesaneyabutr, C., and Taksavasu, T., 2003, The Padaeng supergene nonsulfide zinc deposit, Mae Sod, Thailand: Economic Geology, v. 98, p. 773-785.
  • Mineral galleries
  • Webmineral
  • Mindat.org

 
 
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Calamine
silicate minerals
hydrozincite

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Dictionary. The American Heritage® Dictionary of the English Language, Fourth Edition Copyright © 2007, 2000 by Houghton Mifflin Company. Updated in 2009. Published by Houghton Mifflin Company. All rights reserved.  Read more
Sci-Tech Encyclopedia. McGraw-Hill Encyclopedia of Science and Technology. Copyright © 2005 by The McGraw-Hill Companies, Inc. All rights reserved.  Read more
Rock & Mineral Guide. Peterson Field Guide to Rocks and Minerals, by Frederick H. Pough. Copyright © 1998 by Houghton Mifflin Company. Published by Houghton Mifflin Company. All rights reserved.  Read more
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