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Henri Etienne Sainte-Claire Deville

French chemist (1818–1881)

The son of a wealthy shipowner from the West Indies island of St. Thomas, Deville studied medicine in Paris but became interested in chemistry by attending Louis Thenard's lectures. He isolated toluene and methyl benzoate from tolu balsam and investigated other natural products before turning to inorganic chemistry, following his appointment as professor of chemistry at Besançon (1845).

Deville's first major discovery was that of nitrogen pentoxide (1849). Following this success he became professor of chemistry at the Ecole Normale Supérieure (1851) and also lectured at the Sorbonne from 1853. Deville is best known for his work on the large-scale production of aluminum. This had been obtained by Kaspar Wöhler in 1827 but had been produced only in small quantities. Deville developed a commercially successful process involving reduction of aluminum chloride by sodium; the first ingot was produced in 1855. Deville was an expert on the purification of metals and produced (among others) crystalline silicon (1854) and boron (1856), pure magnesium (1857), and pure titanium (1857; with Wöhler). He did much work on the purification of platinum and in 1872 was commissioned to produce the standard kilogram.

After his work on aluminum, Deville's most important researches were those on dissociation. Working with L. J. Troost, he discovered that many molecules were dissociated at high temperature, giving rise to anomalous vapor-density results. Deville's work explained these results and helped to confirm Amedeo Avogadro's hypothesis. His other work included the production of artificial gemstones and improved furnaces.

 
 
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Henri Sainte-Claire Deville
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Henri Sainte-Claire Deville

Henri Etienne Sainte-Claire Deville (March 9, 1818-July 1, 1881) was a French chemist.

He was born in the island of St Thomas, West Indies, where his father was French consul. Together with his elder brother Charles he was educated in Paris at the College Rollin. In 1844, having graduated as doctor of medicine and doctor of science, he was appointed to organize the new faculty of science at Besançon, where he acted as dean and professor of chemistry from 1845 to 1851. Returning to Paris in the latter year he succeeded A. J. Balard at the École Normale, and in 1859 became professor at the Sorbonne in place of J. B. A. Dumas, for whom he had begun to lecture in 1853. He died at Boulogne-sur-Seine.

He began his experimental work in 1841 with investigations of oil of turpentine and tolu balsam, in the course of which he discovered toluene. But his most important work was in inorganic and thermal chemistry. In 1849 he discovered anhydrous nitric acid (nitrogen pentoxide), a substance interesting as the first obtained of the so-called "anhydrides" of the monobasic acids. In 1855, ignorant of what Friedrich Wöhler had done ten years previously, he succeeded in obtaining metallic aluminium, and ultimately he devised a method by which the metal could be prepared on a large scale by the aid of sodium, the manufacture of which he also developed. With H. J. Debray (1827-1888) he worked at the platinum metals, his object being on the one hand to prepare them pure, and on the other to find a suitable metal for the standard metre for the International Metric Commission then sitting at Paris. With L. J. Troost (b. 1825) he devised a method for determining vapour densities at temperatures up to 1400˚C, and, partly with F. Wohler, he investigated the allotropic forms of silicon and boron. The artificial preparation of minerals, especially of apatite and isorhor-phous minerals and of crystalline oxides, was another subject in which he made many experiments. But his best known contribution to general chemistry is his work on the phenomena of reversible reactions, which he comprehended under a general theory of "dissociation." He first took up the subject about 1857, and it was in the course of his investigations on it that he devised the apparatus known as the "Deville hot and cold tube."


This article incorporates text from the Encyclopædia Britannica Eleventh Edition, a publication now in the public domain.

References

  • Jaime Wisniak (2004). "Henri Étienne Sainte-Claire Deville: A physician turned metallurgist". Journal of Materials Engineering and Performance 13 (2): 117-128. DOI:10.1361/10599490418271. 
  • A.G. Morachevskii (2006). "Henri Étienne Sainte-Claire Deville (to 150th anniversary of the development of the first industrial method for production of aluminum)". Journal Russian Journal of Applied Chemistry 79 (10): 1731-1735. DOI:10.1134/S1070427206100399. 

 
 

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