A rhyming couplet is any pair of lines that end with rhyming words. An example would be:
When help is what you're trying to get
Head on down to the internet!
Iambic pentameter is a bit trickier. A line of iambic has 10 syllables, with the first syllable unstressed, the next stressed, then it alternates between unstressed and stressed for the rest of the line. Sonnets usually utilize iambic pentameter.
But sometimes you must try to bediscreet.
(Italics added to show stress)