Iron poisoning. This can easily lead to death. Be careful.
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Iron overdose
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Iron overload is a genetic disorder that is inherited, but it
can also develop from multiple blood transfusions or chronic iron
poisoning.
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Dangerous in what sense? If you mean toxic, the answer is
generally no, though iron poisoning is possible if you ingest too
much. Fine iron powder can be flammable if dispersed in air. A
solid iron rod can be an effective blunt weapon.
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Yes, it is ok to use iron out in a pool for "cleaning only". If
you intend to swim in the pool iron out can cause skin and eye
irritations and poisoning if swallowed. The makers of Iron Out said
it is not recommended for swimming pools.