on the bad side its the impero curse i think......
on the good side idk
I don't think so,
its probably the patronus charm (Expecto Patronum) because it is really advanced defensive magic,
or The Memory Charm (Obliviate) because it is an excellent cover-up Charm,
then it might be The Cruciatis Curse (Crucio) because it can force out the info you need.
But most of all its your will and desire to cast a spell like when Harry only used a Disarming Charm (Expelliarmus) and reflected The Killing Curse (Avada Kadava) and killed Voldemort.(In the 7th volume)
or it is everyones opinion,
For Voldemort The Killing Curse (Avada Kadava) is his specialty,
For Harry it might be The Disarming Charm (Expelliarmus) or The Patronus Charm (Expecto Patronum)