Lawsonite

Lawsonite is a hydrous calcium aluminium sorosilicate mineral with formula CaAl₂Si₂O₇(OH)₂·H₂O. Lawsonite crystallizes in the orthorhombic system in prismatic, often tabular crystals. Crystal twinning is common. It forms transparent to translucent colorless, white, and bluish to pinkish grey glassy to greasy crystals. Refractive indices are nα=1.665, nβ=1.672 - 1.676, and nγ=1.684 - 1.686. It is typically almost colorless in thin section, but some lawsonite is pleochroic from colorless to pale yellow to pale blue, depending on orientation. The mineral has a Mohs hardness of 8 and a specific gravity of 3.09. It has perfect cleavage in two directions and a brittle fracture.

Lawsonite is a metamorphic mineral typical of the blueschist facies. It also occurs as a secondary mineral in altered gabbro and diorite. Associate minerals include epidote, titanite, glaucophane, garnet and quartz. It is an uncommon constituent of eclogite.

It was first described in 1895 for occurrences in the Tiburon peninsula, Marin County, California. It was named for geologist Andrew Lawson (1861-1952) of the University of California.

Composition

Lawsonite is a metamorphic silicate mineral related chemically and structurally to the epidote group of minerals. It is close to the ideal composition of CaAl₂Si₂O₇(OH)₂ . H₂O giving it a close chemical composition with anorthite CaAl₂Si₂O₈ (its anhydrous equivalent), yet lawsonite has greater density and a different Al coordination (Comodi et al., 1996). The substantial amount of water bound in lawsonite’s crystal structure is released during its breakdown to denser minerals during prograde metamorphism. This means lawsonite is capable of conveying appreciable water to shallow depths in subducting oceanic lithosphere (Clark et al., 2006). Experimentation on lawsonite to vary its responses at different temperatures and different pressures is among its most studied aspects, for it is these qualities that affect its abilities to carry water down to mantle depths, similar to other OH-containing phases like antigorite, talc, phengite, staurolite, and epidote (Comodi et al., 1996)

Geologic Occurrence

Lawsonite is a very widespread mineral and has attracted considerable interest over the last few years because of its importance as a marker of moderate Pressure (6-12 kilobars) and low Temperature (300 - 400°C) conditions in nature (Clark et al., 2006). This mainly occurs along continental margins (subduction zones) such as those found in: Franciscan Formation in California (Fig. 1), Reed Station, Tiburon Peninsula of Marin County, California, Piedmont metamorphics of Italy, and schists in New Zealand, New Caledonia, China, Japan and from various points in the circum-Pacific orogenic belt. Many times it can simply be found on the surface or in outcrops.

Crystal Structure

Though lawsonite and anorthite have similar compositions, their structures are quite different. While anorthite has a tetrahedral coordination with Al (Al substitutes for Si in feldspars), lawsonite has an octahedral coordination with Al, making it an orthorhombic sorosilicate with a space group of Cmcm which consists of Si₂O₇ Groups and O, OH, F, and H₂O with cations in [4] and/or > [4] coordination. This is much similar to the epidote group which lawsonite is often found in conjunction with, which are also sorosilicates because their structure consists of two connected SiO4 tetrahedra plus connecting cation. The water contained in its structure is made possible by cavities formed by rings of two Al octahedral and two Si₂O₇ groups, each containing an isolated water molecule and calcium atom. The hydroxyl units are bound to the edge-sharing Al octahedral (Baur, 1978).

Physical Properties

Lawsonite has crystal habits of orthorhombic prismatic, which are crystals shaped like slender prisms, or tubular figures, which are form dimensions that are thin in one direction, both with two perfect cleavages. This crystal is transparent to translucent and varies in color from white to pale blue to colorless with a white streak and a vitreous or greasy luster. It has a relatively low specific gravity of 3.1g/cm3, and a pretty high hardness of 7.5 on Mohs scale of hardness, slightly higher than quartz. Under the microscope, lawsonite can be seen as blue, yellow, or colorless under plan polarized light while the stage is rotated. Lawsonite has three refractive indices of nα = 1.665 nβ = 1.672 - 1.676 nγ = 1.684 - 1.686, which produces a birefringence of δ = 0.019 - 0.021 and an optically positive biaxial interference figure.

Significance of Lawsonite

Lawsonite is a significant metamorphic mineral as it can be used as an index mineral for high pressure conditions. Index minerals are used in geology to determine the degree of metamorphism a rock has experienced. New metamorphic minerals form through solid-state cation exchanges following changing pressure and temperature conditions imposed upon the protolith (pre-metamorphosed rock). This new mineral that is produced found in the metamorphosed rock is the index mineral, which indicates the minimum pressure and temperature the protolith must have achieved in order for that mineral to form.

Lawsonite is known to form in high pressure, low temperature conditions, most commonly found in subduction zones where cold oceanic crust subducts down oceanic trenches into the mantle (Comodi et al., 1996). The initially-low temperature of the slab, and fluids taken down with it manage to depress isotherms and keep the slab much colder than the surrounding mantle, allowing for these unusual high pressure, low temperature conditions. Glaucophane, kyanite and zoisite are other common minerals in the blueschist facies and are commonly found to coexist (Pawley et al., 1996). It can be said that this assemblage is diagnostic of this facies.

References

• Hurlbut, Cornelius S.; Klein, Cornelis, 1985, Manual of Mineralogy, 20th ed., Wiley, ISBN 0-471-80580-7
• Mindat with location data
• Webmineral data
• Comodi P. and Zanazzi P. F. (1996) Effects of temperature and pressure on the structure of lawsonite, Piazza University, Perugia, Italy. American Mineralogist 81, 833-841.
• Baur W. H. (1978) Crystal structure refinement of lawsonite, University of Illinois, Chicago, Illinois. American Mineralogist 63, 311-315.
• Clarke G. L., Powell R., Fitzherbert J. A. (2006) The lawsonite paradox: a comparison of field evidence and mineral equilibria modeling, Australia. J. metamorphis Geol. 24, 715-725.
• Maekawa H., Shozul M., Ishll T., Fryer P., Pearce J. A. (1993) Blueschist metamorphism in an active subduction zone, Japan. Nature 364, 520-523.
• Pawley A. R., Redfern S. A. T., Holland T. J. B. (1996) Volume behavior of hydrous minerals at high pressure and temperature: I. Thermal expansion of lawsonite, zoisite, clinozoisite, and diaspore, U.K. American Mineralogist 81, 335-340.