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lepidolite

 
Dictionary: le·pid·o·lite   (lĭ-pĭd'l-īt') pronunciation
n.
A lilac or pink to gray mineral of the mica group, K(Li,Al)3(Si,Al)4O10(F,OH)2, used as lithium ore and in ceramic production.

[LEPIDO- + -LITE.]


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Sci-Tech Encyclopedia: Lepidolite
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A mineral of variable composition which is also known as lithium mica and lithionite, K2(Li,Al)5−6(Si6−7, Al2−1)O20−21(F,OH)3−4. Rubidium (Rb) and cesium (Cs) may replace potassium (K); small amounts of Mn, Mg, Fe(II), and Fe(III) normally are present; and the OH/F ratio varies considerably. Polithionite is a silicon- and lithium-rich, and thus aluminum-poor, variety of lepidolite.

Lepidolite usually forms small scales or fine-grained aggregates. Its colors, pink, lilac, and gray, are a function of the Mn/Fe ratio. Hardness is 2.5–4.0 on Mohs scale; specific gravity is 2.8–3.0. See also Mica; Silicate minerals.

Lepidolite is uncommon, occurring almost exclusively in structurally complex granitic pegmatites, commonly in replacement units. Common associates are quartz, cleavelandite, alkali beryl,and alkali tourmaline. It is a commercial source of lithium, commonly used directly in lithium glasses and other ceramic products.


Rock & Mineral Guide: lepidolite
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K
Monoclinic -- domatic

Environment

A mica mineral of the core area of lithium-bearing pegmatites.

Crystal description

Commonly occurs in medium- to fine-grained aggregates; well-developed crystals of sharp hexagonal outline less common. Sometimes in late growths bordering ordinary muscovite mica, but the cleavage flakes show a slight marginal break and are not quite continuous. Crystals 1-2 in. (2.5-5 cm), tapering down to a slender point and more prismatic than tabular, occur at some localities. Elsewhere often in curving convex hemispheres embedded in feldspar.

Physical properties

Lilac, graygreen, pale yellow. Luster pearly and vitreous; hardness directional variable 2Ɖ and 4; specific gravity 2.8-3.3; cleavage perfect basal (micaceous), making elastic plates. Micaceous; translucent to transparent; can be gorgeous amethystine hue through the side, reminiscent of kunzite spodumene.

Composition

Alkaline fluosilicate of lithium, potassium, and aluminum (about 5% Li 2 O, 12% K 2 O, 26% Al 2 O 3 , 51% SiO 2 , 1.5% H 2 O, and 4.5% F).

Tests

Fuses easily to a bubbly fluorescent glass (blue and pinkish fluorescence). Colors the flame red.

Distinguishing characteristics

Since lepidolite colors can be confusing, a melting and flame test is desirable if there is any reason (such as the presence of elbaite tourmalines or of other lithium minerals) to suspect a mica is lepidolite, rather than the more common muscovite. The fluorescence and flame tests will also distinguish it from the more intensely colored chromium chlorites, dumortierite, and similar hydrous silicates.

Occurrence

Once, before alkali lake brines proved better, an important ore of lithium. Relatively rare, since it is only found in the complex pegmatites that have a history of a long series of replacements by successive elements; always an associate with lithium minerals. Only found in regions where dikes of this type are exposed, as in New England, particularly in Maine, and at Portland, Connecticut, and San Diego Co., California.

Well-formed crystals up to an inch (2.5 cm) or more across are found at Auburn, Maine. Fine-grained aggregates are common in many Maine localities, and are associated with microlite at Dixon, New Mexico. The coarsest crystals form bladed aggregates at Ohio City, Colorado. Foreign localities include Afghanistan and Pakistan; Minas Gerais, Brazil; Madagascar; Varutrask, Sweden; Namibia; Western Australia (where there are sheets as much as 6 in. [15 cm] across in the Londonderry pegmatite); Russia; and Germany. The Alto Ligonha pegmatite in Mozambique had abundant notable lepidolite knobs to 12 in. high and 6 in. across (30 × 15 cm).



WordNet: lepidolite
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Note: click on a word meaning below to see its connections and related words.

The noun has one meaning:

Meaning #1: a mineral of the mica group; an important source of lithium


Wikipedia: Lepidolite
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Lepidolite

Crystal of lepidolite, Brazil
General
Category Silicate mineral
Chemical formula KLi2Al(Al,Si)3O10(F,OH)2
Identification
Color Pink, purple, rose-red, violet-gray, yellowish, white, colorless
Crystal habit Tabular to prismatic pseudohexagonal crystals, scaly aggregates and massive
Crystal system Monoclinic
Twinning Rare, composition plane
Cleavage [001] Perfect
Fracture Uneven
Mohs scale hardness 2.5–3
Luster Vitreous to pearly
Diaphaneity Transparent to translucent
Specific gravity 2.8–2.9
Optical properties Biaxial (-)
Refractive index a=1.525–1.548, b=1.551–1.58, g=1.554–1.586
Birefringence 0.0290–0.0380
References [1][2]

Lepidolite (KLi2Al(Al,Si)3O10(F,OH)2 is a lilac-gray or rose-colored phyllosilicate mineral of the mica group that is a secondary source of lithium.[3] It is associated with other lithium-bearing minerals like spodumene in pegmatite bodies. It is one of the major sources of the rare alkali metals rubidium and caesium.[4] In 1861 Robert Bunsen and Gustav Kirchhoff extracted 150 kg of lepidolite and yielded few grams of rubidium salts for analysis, and therefore discovered the new element rubidium.[5]

It occurs in granite pegmatites, in some high-temperature quartz veins, greisens, and granites. Associated minerals include quartz, feldspar, spodumene, amblygonite, tourmaline, columbite, cassiterite, topaz, and beryl.[1]

Notable occurrences: Brazil; Ural Mountains, Russia; California; Tanco Pegmatite, Bernic Lake Manitoba, Canada, Madagascar.

References

  1. ^ a b http://rruff.geo.arizona.edu/doclib/hom/lepidolite.pdf Handbook of Mineralogy
  2. ^ http://webmineral.com/data/Lepidolite.shtml Webmineral
  3. ^ Hurlbut, Cornelius S.; Klein, Cornelis (1985), Manual of Mineralogy, Wiley, (20th ed.) ISBN 0-471-80580-7
  4. ^ H. Nechamkin, The Chemistry of the Elements, McGraw-Hill, New York, 1968.
  5. ^ G. Kirchhoff, R. Bunsen (1861). "Chemische Analyse durch Spectralbeobachtungen". Annalen der Physik und Chemie 189 (7): 337–381. doi:10.1002/andp.18611890702. 

 
 
Learn More
lithian muscovite (mineralogy)
zinnwaldite (mineralogy)
rubidium

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Dictionary. The American Heritage® Dictionary of the English Language, Fourth Edition Copyright © 2007, 2000 by Houghton Mifflin Company. Updated in 2009. Published by Houghton Mifflin Company. All rights reserved.  Read more
Sci-Tech Encyclopedia. McGraw-Hill Encyclopedia of Science and Technology. Copyright © 2005 by The McGraw-Hill Companies, Inc. All rights reserved.  Read more
Rock & Mineral Guide. Peterson Field Guide to Rocks and Minerals, by Frederick H. Pough. Copyright © 1998 by Houghton Mifflin Company. Published by Houghton Mifflin Company. All rights reserved.  Read more
WordNet. WordNet 1.7.1 Copyright © 2001 by Princeton University. All rights reserved.  Read more
Wikipedia. This article is licensed under the Creative Commons Attribution/Share-Alike License. It uses material from the Wikipedia article "Lepidolite" Read more