lox

The blue colour of liquid oxygen in a dewar flask

Liquid oxygen (also LOx, LOX or Lox in the aerospace, submarine and gas industry) is a form of the element oxygen. It has a pale blue color and is strongly paramagnetic and can be suspended between the poles of a powerful horse shoe magnet. Liquid oxygen has a density of 1.141 g/cm³ (1.141 kg/L) and is cryogenic (freezing point: 50.5 K (−222.65 °C), boiling point: 90.19 K (−297.33 °F, −182.96 °C) at 101.325 kPa (760 mmHg). In commerce, liquid oxygen is classified as an industrial gas and is widely used for industrial and medical purposes. Liquid oxygen is obtained from the oxygen found naturally in air by fractional distillation. Liquid oxygen has an expansion ratio of 861:1 at 68 °F (20 °C); and because of this, it is used in some commercial and military aircraft as a source of breathing oxygen.

LOX used in space rockets (and probably in aerospace) is a mixture of liquid oxygen with up to 25% liquid ozone and several additives to stabilize this liquid oxyidator.

Due to its cryogenic nature, LOX can cause the materials it touches to become extremely brittle. Liquid oxygen is also a very powerful oxidising agent: organic materials will burn rapidly and energetically in liquid oxygen. Further, if soaked in LOX some materials such as coal briquets, carbon black, etc., can detonate unpredictably from sources of ignition such as flames, sparks or impact from light blows. Petrochemicals often exhibit this behavior, including asphalt.

LOX is a common liquid oxidizer propellant for spacecraft rocket applications, usually in combination with liquid hydrogen or kerosene. LOX is useful in this role because it creates a high specific impulse. It was used in the very first rocket applications like the V2 missile (under the name A-Stoff and Sauerstoff) and Redstone, R-7 Semyorka or Atlas boosters. LOX was also used in some early ICBMs, although more modern ICBMs do not use LOX because its cryogenic properties and need for regular replenishment to replace boiloff make it harder to maintain and launch quickly. Many modern rockets use LOX, including the main engines on the Space Shuttle.

LOX also had extensive use in making oxyliquit explosives, but is rarely used now due to a high rate of accidents.

The tetraoxygen molecule (O₄) was first predicted in 1924 by Gilbert N. Lewis, who proposed it as an explanation for the failure of liquid oxygen to obey Curie's law.^[1] Today it seems Lewis was off, but not by far: computer simulations indicate that although there are no stable O₄ molecules in liquid oxygen, O₂ molecules do tend to associate in pairs with antiparallel spins, forming transient O₄ units.^[2]

Liquid nitrogen has a lower boiling point at −196 °C (77 K) than oxygen's −183 °C (90 K), and vessels containing liquid nitrogen can condense oxygen from air: when most of the nitrogen has evaporated from such a vessel there is a risk that liquid oxygen remaining can react violently with organic material. Conversely, liquid nitrogen or liquid air can be oxygen-enriched by letting it stand in open air; atmospheric oxygen dissolves in it, while nitrogen evaporates preferentially.

History

• By 1845, Michael Faraday had managed to liquefy most permanent gases then known to exist. Six gases, however, resisted every attempt at liquefaction ^[3] and were known at the time as "permanent gases". They were oxygen, hydrogen, nitrogen, carbon monoxide, methane, and nitric oxide.
• In 1877, Louis Cailletet (1832–1913) in France and Raoul Pictet (1846–1929) in Switzerland succeeded in producing the first droplets of liquid air.
• The first measurable quantity of liquid oxygen was produced by Polish professors Zygmunt Wróblewski and Karol Olszewski (Jagiellonian University in Kraków) on April 5^th 1883.

See also

• Cryogenics
• Karol Olszewski and Zygmunt Florenty Wróblewski
• Liquid hydrogen
• Liquid helium
• Liquid nitrogen
• List of Stoffs
• Natterer compressor
• Rocket fuel
• Solid oxygen
• Tetraoxygen

References

1. ^ Lewis, Gilbert N. (September 1924). "The Magnetism of Oxygen and the Molecule O₂". Journal of the American Chemical Society 46 (9): 2027–2032. doi:10.1021/ja01674a008. 
2. ^ Oda, Tatsuki; Alfredo Pasquarello (October 2004). "Noncollinear magnetism in liquid oxygen: A first-principles molecular dynamics study". Physical Review B 70 (134402): 1–19. doi:10.1103/PhysRevB.70.134402. http://link.aps.org/abstract/PRB/v70/e134402. 
3. ^ http://www.scienceclarified.com/Co-Di/Cryogenics.html