The best known as a LiveCD (as opposed to being the most popular
with a LiveCD available) is Knoppix.
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A LiveCD is a bootable CD that provides a fully functional
operating system with no need for installation.
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Most of the popular Linux distributions these days have a LiveCD
portion, including Ubuntu, PCLinuxOS, and even Gentoo. The most
popular known specifically for LiveCD functionality is probably
Knoppix.
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Yes. All desktop editions of Ubuntu have a LiveCD edition. It is
the default and recommended method of installing Ubuntu.
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The image downloaded from Ubuntu's website is already a LiveCD.
If you want guides on how to customize it, or to create one from an
installed system, refer to the links below.