mercury-vapor lamp

A 175W mercury-vapor yard light approximately 15 seconds after starting

A closeup of a 175W mercury vapor lamp.

The spectrum

A mercury-vapor lamp is a gas discharge lamp which uses mercury in an excited state to produce light. The arc discharge is generally confined to a small fused quartz arc tube mounted within a larger borosilicate glass bulb. The outer bulb may be clear or coated with a phosphor; in either case, the outer bulb provides thermal insulation, protection from ultraviolet radiation, and a convenient mounting for the fused quartz arc tube.

Mercury vapor lamps (and their relatives) are often used because they are relatively efficient. Phosphor coated bulbs offer better color rendition than either high- or low-pressure sodium vapor lamps. Mercury vapor lamps also offer a very long lifetime, as well as intense lighting for several applications.

Theory and relations

The mercury vapor lamp is a negative resistance device and requires auxiliary components (for example, a ballast) to prevent it from taking excessive current. The auxiliary components are substantially similar to the ballasts used with fluorescent lamps. It is used often for outside lighting (signs) and for auditoriums and stages.

Also like fluorescent lamps, mercury vapor lamps usually require a starter which is usually contained within the mercury vapor lamp itself. A third electrode is mounted near one of the main electrodes and connected through a resistor to the other main electrode. When power is applied, there is sufficient voltage to strike an arc between the starting electrode and the adjacent main electrode. This arc discharge eventually provides enough ionized mercury to strike an arc between the main electrodes. Occasionally, a thermal switch will also be installed to short the starting electrode to the adjacent main electrode, completely suppressing the starting arc once the main arc strikes.

Variation: Metal halide

A closely-related lamp design called the metal halide lamp uses various other elements in an amalgam with the mercury. Sodium iodide and Scandium iodide are commonly in use. These lamps can produce much better quality light without resorting to phosphors. If they use a starting electrode, there is always a thermal shorting switch to eliminate any electrical potential between the main electrode and the starting electrode once the lamp is lit. (This electrical potential in the presence of the halides can cause the failure of the glass/metal seal). More modern metal halide systems do not use a separate starting electrode; instead, the lamp is started using high voltage pulses as with high-pressure sodium vapor lamps. "MetalArc" is Osram Sylvania's trademark for their metal halide lamps; "Arcstream" and "MultiVapor" are General Electric's trademark. Besides their use in traditional outdoor lighting, these lamps now appear in most computer and video projectors. However, Philips' UHP lamp, introduced in 1995, contains only mercury. As an example of application and efficiency of mercury lamps, the 61" Samsung DLP rear projection TV (HL-S6187W) uses a 132 watt Philips UHP lamp.

Operation

When a mercury vapor lamp is first turned on, it will produce a dark blue glow because only a small amount of the mercury is ionized and the gas pressure in the arc tube is very low, so much of the light is produced in the ultraviolet mercury bands. As the main arc strikes and the gas heats up and increases in pressure, the light shifts into the visible range and the high gas pressure causes the mercury emission bands to broaden somewhat, producing a light that appears more-white to the human eye, although it is still not a continuous spectrum. Even at full intensity, the light from a mercury vapor lamp with no phosphors is distinctly bluish in color. The pressure in the silica glass tube rises to approximately one atmosphere once the bulb has reached its working temperature. If the discharge should be interrupted (e.g. by interruption of the electric supply), it is not possible for the lamp to restrike until the bulb cools enough for the pressure to fall considerably.

Color considerations

To correct the bluish tinge, many mercury vapor lamps are coated on the inside of the outer bulb with a phosphor that converts some portion of the ultraviolet emissions into red light. This helps to fill in the otherwise very-deficient red end of the electromagnetic spectrum. These lamps are generally called "color corrected" lamps. Most modern mercury vapor lamps have this coating. One of the original complaints against mercury lights was they tended to make people look like "bloodless corpses" because of the lack of light from the red end of the spectrum. A common method of correcting this problem before phosphors were used was to operate the mercury lamp in conjunction with an incandescent lamp. There is also an increase in red color (e.g., due to the continuous radiation) in ultra-high pressure mercury vapor lamps (usually greater than 200 atm.) which has found application in modern compact projection devices. When outside, coated or color corrected lamps can usually be identified by a blue "halo" around the light being given off.

Example of a phosphor coated 125 watt lamp.

Emission Line Spectrum

The peaks of the emission line spectrum are^[1]

Usage of low pressure lamps for surface cleaning

Low-pressure Hg lamps can be rather small, but efficient sources of deep UV light

Low pressure mercury-vapor lamps^[2] have usually a quartz bulb in order to allow the transmission of short wavelength light. If synthetic quartz is used, then the transparency of the quartz is increased further and an emission line at 185nm is observed also. Such a lamp can then be used for the cleaning or modification of surfaces.^[3]

Light pollution considerations

For placements where light pollution is of prime importance (for example, an observatory parking lot), low pressure sodium is preferred. As it emits light on only one wavelength, it is the easiest to filter out. Mercury vapor lamps without any phosphor are second best; they produce only a few distinct mercury lines that need to be filtered out.

Bans

Mercury vapor lamps will be banned in the EU in 2015.^[4] In the USA, ballasts and fixtures were banned in 2008. ^[5]

Ultraviolet hazards

All mercury vapor lamps (including metal halide lamps) must contain a feature (or be installed in a fixture that contains a feature) that prevents ultraviolet radiation from escaping. Usually, the borosilicate glass outer bulb of the lamp performs this function but special care must be taken if the lamp is installed in a situation where this outer envelope can become damaged.^[6] There have been documented cases of lamps being damaged in gymnasiums. Sun burns and eye inflammation have resulted.^[7] When used in locations like gyms, the fixture should contain a strong outer guard or an outer lens to protect the lamp's outer bulb. Also, special "safety" lamps are made which will deliberately burn out if the outer glass is broken. This is usually achieved by using a thin carbon strip, which will burn up in the presence of air, to connect one of the electrodes.

Even with these methods, some UV radiation can still pass through the outer bulb of the lamp. This causes the aging process of some plastics used in the construction of luminaires to be accelerated, leaving them significantly discolored after only a few years' service. Polycarbonate suffers particularly from this problem, and it is not uncommon to see fairly new polycarbonate surfaces positioned near the lamp to have turned a dull, 'ear-wax'-like color after only a short time. Certain polishes, such as Brasso, can be used to remove some of the yellowing, but usually only with limited success.

End of life

Mercury vapor lamps rarely burn out completely but suffer from lumen depreciation. The lamp produces 50% less light every five years, to the point of becoming ineffective while still drawing the same amount of power it drew when it was new. This comes about because the emitter is deposited as a film darkening the arctube wall and reducing light output.

Uses

Photoresist exposure

Ultra high pressure mercury vapor lamps are used in the area of photolithography to expose various photoresists. The unique spectral emission characteristics of mercury vapor lamps are ideal for photoresists, the most common of which are generally photosensitive between 350 and 500 nm wavelengths.

See also

Wikimedia Commons has media related to: Mercury-vapor lamp

• History of street lighting in the United States
• List of light sources

References

1. ^ Persistent Lines of Neutral Mercury ( Hg I )
2. ^ "Low pressure mercury-vapor lamps". http://www.crystec.com/senlampe.htm. 
3. ^ "Surface cleaning by UV-light". http://www.crystec.com/senteche.htm. 
4. ^ http://www.osram.com/osram_com/Consumer/Home_Lighting/Alternatives_to_light_bulbs/EU_directive_-_street%2c_office_and_industry_lighting/index.html
5. ^ http://mercuryvaporlight.com/banned-Mercury-Vapor-Lights/energy-policy-act-of-2005.html
6. ^ 291 KBPDF, Osram Sylvania
7. ^ Thun, MJ; Altman R, Ellingson O, Mills LF, Talansky ML (November 1982). "Ocular complications of malfunctioning mercury vapor lamps". Ann Ophthalmol. 14 (11): 1017–20. PMID 7181332 : 7181332. http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?cmd=Retrieve&db=PubMed&list_uids=7181332&dopt=Abstract. 

• Waymouth, John (1971). Electric Discharge Lamps. Cambridge, MA: The M.I.T. Press. ISBN 0-262-23048-8. 
• Museum of Electric Lamp Technology
• Mercury Vapor Light

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