By itself no, methyl salicylate would increase the absorption into the skin of a medicine that could.

salicylic acid (an acid) is more polar than methyl salicylate (an ester)

Organic acids and alcohols are reacted (in the presence of a dehydrating agent) to produce esters. And these substances are often recognized by their characteristic odors. In the case here, salicylic acid and methyl alcohol yield methyl salicylate, which is winter-green.

Methyl salicylate is a liquid ester that is usually applied externally for the minor joint and muscle pain.

a strong minty smell