Mimetite

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(′mim·ə′tīt)

(mineralogy) Pb5(AsO4)3Cl A yellow to yellowish-brown mineral of the apatite group, commonly containing calcium or phosphate; a minor ore of lead. Also known as mimetene; mimetesite.



Pb
Hexagonal -- Hexagonal bipyramidal

Environment

Secondary (weathered) zone of lead ore deposits.

Crystal description

Slender to thick needles, sometimes in yellowish mammillary crusts. Orange-yellow rounded crystals (melon-shaped) called campylite.

Physical properties

White, yellow, yellow-orange to brown. Luster resinous; hardness 3Ɖ; specific gravity 7.0-7.3; fracture uneven; cleavage pyramidal. Brittle; transparent to translucent.

Composition

Lead chloroarsenate (74.6% PbO, 23.2% As 2 O 2.4% Cl).

Tests

Fuses readily on charcoal; suddenly boils, giving off arsenic fumes (garlic odor), and reduces to a lead bead.

Distinguishing characteristics

Appearance, associations, and occurrence show it to be a member of this group. Distinguished from pyromorphite and vanadinite by arsenic smell.

Occurrence

Like pyromorphite and vanadinite, mimetite is a secondary mineral. It is rather rare, being far less common than the other two, and only occasionally is it of importance as an ore of lead. Best distributed in collections are the old campylite specimens. Campylite occurs in small (to 蕀 in.; 1 cm) crystals at several British localities. Mimetite is rare in the U.S. Most frequent occurrence is across the border in Durango, Mexico, where it formed orange-yellow botryoidal coatings of great charm at San Pedro Corralitos. Brilliant orange blobs illuminate thin yellow wulfenites at Cerro Prieto, Sonora, Mexico, and at the Rowley and 79 Mines in Theba and Hayden, Arizona. It has been found at Eureka, Utah. The best and largest isolated crystals of former times were found in the old mine visited by Goethe at Johanngeorgenstadt, Saxony. Remarkable, gemmy, pale yellow, beautifully terminated 2-in. (4-5 cm) crystals have lately been found at Tsumeb, Namibia, and provide what is probably the all-time great for this mineral.



Mimetite

Mimetite, Bilbao mine, Zacatecas, Mexico. Size: 7.9 x 5.8 x 3.4 cm
General
Category Arsenate minerals
Chemical formula Pb5(AsO4)3Cl
Strunz classification 08.BN.05
Crystal symmetry Hexagonal dipyramidal
H-M symbol: (6/m)
Space group: P63/m
Unit cell a = 10.250(2) Å, c = 7.454(1) Å; Z=2
Identification
Color Pale to bright yellow, yellowish brown, yellow-orange, white, may be colorless
Crystal habit Prismatic to acicular crystals; reniform, botryoidal, globular,
Crystal system Hexagonal
Twinning Rare on {1122}
Cleavage [1011] Imperfect
Fracture Brittle, conchoidal
Tenacity Brittle
Mohs scale hardness 3.5 - 4
Luster Resinous, subadamantine
Streak White
Diaphaneity Transparent to translucent
Specific gravity 7.1 - 7.24
Optical properties Uniaxial (-), anomalously biaxial
Refractive index nω = 2.147 nε = 2.128
Birefringence δ = 0.019
Pleochroism Weak
References [1][2][3]

Mimetite, whose name derives from the Greek Μιμητής mimethes, meaning "imitator", is a lead arsenate chloride mineral (Pb5(AsO4)3Cl) which forms as a secondary mineral in lead deposits, usually by the oxidation of galena and arsenopyrite. The name is a reference to mimetite's resemblance to the mineral pyromorphite. This resemblance is not coincidental, as mimetite forms a mineral series with pyromorphite (Pb5(PO4)3Cl) and with vanadinite (Pb5(VO4)3Cl). Notable occurrences are Mapimi, Durango, Mexico and Tsumeb, Namibia.

Contents

Uses of mimetite

Mimetite from Namibia

Industrially, mimetite is a minor ore of lead. The chief use of mimetite is as a collector's specimen, often creating attractive botryoidal crusts on the surface of the specimen. Though mimetite is also found in prismatic crystal forms, it is not used as a gemstone due to its softness. Quality prismatic forms have been found in Johanngeorgenstadt in Saxony and Wheal Unity in Cornwall, England.

Associated minerals

Mimetite is found in association with lead and arsenic minerals, including those minerals with which it forms a series. Some associated minerals include: calcite, galena, pyromorphite, smithsonite, vanadinite, and wulfenite.

Alternative names

Alternative names of mimetite include arsenopyromorphite, mimetesite, and prixite. Campylite is the name for a variety with barrel shaped crystals of a brownish-red or orange-yellow color and containing a considerable proportion of phosphoric acid.

Notes for identification

Useful information pertaining to the field identification of mimetite include its habit, color, and high density. However, this mineral's similarity to pyromorphite can be problematic, especially since these minerals are known to share colors. Pyromorphite is typically green, and mimetite is typically yellow, but specimens of each are known in the other's colors. As a result, some identification may require lab analysis.

Mimetite specimen gallery

References


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