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Newman projection

 
Sci-Tech Dictionary: Newman projection
(′nü·mən prə′jek·shən)

(organic chemistry) A representation of the conformation of a molecule in which the viewer's eye is considered to be sighting down a carbon-carbon bond; the front carbon is represented by a point and the back carbon by a circle.


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Wikipedia: Newman projection
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Molecule of butane in syn-clinal (-sc) conformation
Sawhorse projection butane -sc.png Newman projection butane -sc.png
Sawhorse
projection
Newman
projection

A Newman projection, useful in alkane stereochemistry, visualizes chemical conformations of a carbon-carbon chemical bond from front to back, with the front carbon represented by a dot and the back carbon as a circle (see below). The front carbon atom is called proximal, while the back atom is called distal. This type of representation is useful for assessing the torsional angle between bonds.

A Sawhorse representation, on the other hand, views a carbon-carbon bond from an oblique angle. This type of representation makes it easy to visualize the molecule as a whole in 3-D.

Other methods for depicting molecules are the Fischer projection, the Haworth projection and the Natta projection.

This projection is named after Melvin Spencer Newman, an American chemist of Ohio State University who introduced it in 1952.

References

  • Newman, M. S. Record. Chem. Progr. (Kresge-Hooker Sci. Lib.) 1952, 13, 111.
  • Newman, M. S. A notation for the study of certain stereochemical problems. J. Chem. Educ. 1955, 32, 344-347.

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