Nuclear isomer

A nuclear isomer is a metastable state of an atomic nucleus caused by the excitation of one or more of its nucleons. A nuclear isomer occupies a higher energy state than the corresponding non-excited nucleus, called the ground state. Most nuclear excited states decay by gamma ray emission or internal conversion, though, far from stability, other decay modes are known. Only one long-lived nuclear isomer is found in nature, 180m73Ta. ^180mTa has the unusual property that the excited state decays with a half life longer than 10¹⁵ years while the lower-energy ground state undergoes beta decay with a half-life of only 8 hours.

Metastable isomers

Metastable isomers can be produced through nuclear fusion or other nuclear reactions. A nucleus thus produced generally starts its existence in an excited state that relaxes through the emission of one or more gamma rays or conversion electrons. However, sometimes it happens that the de-excitation does not proceed rapidly all the way to the nuclear ground state. This usually occurs because of the formation of an intermediate excited state with a spin far different from that of the ground state. Gamma-ray emission is far slower (is "hindered") if the spin of the post-emission state is very different from that of the emitting state, particularly if the excitation energy is low, than if the two states are of similar spin. The excited state in this situation is therefore a good candidate to be metastable if there are no other states of intermediate spin with excitation energies less than that of the metastable state.

Metastable isomers of a particular isotope are usually designated with an "m" (or, in the case of isotopes with more than one isomer, m2, m3, and so on). This designation is placed after the mass number of the atom; for example, Cobalt-58m (abbreviated 58m27Co, where 27 is the atomic number of cobalt). Increasing indices, m, m2, etc. correlate with increasing levels of excitation energy stored in each of the isomeric states (e.g., Hafnium-177m2 or 177m272Hf).

A different kind of metastable nuclear state (isomer) is the fission isomer or shape isomer. Most actinoid nuclei, in their ground states, are not spherical, but rather spheroidal — specifically, prolate, with an axis of symmetry longer than the other axes (similar to an American football or rugby ball, although with a less pronounced departure from spherical symmetry). In some of these, quantum-mechanical states can exist in which the distribution of protons and neutrons is farther yet from spherical (in fact, about as non-spherical as an American football), so much so that de-excitation to the nuclear ground state is strongly hindered. In general, these states either de-excite to the ground state (albeit far more slowly than a "usual" excited state) or undergo spontaneous fission with half lives of the order of nanoseconds or microseconds — a very short time, but many orders of magnitude longer than the half life of a more usual nuclear excited state. Fission isomers are usually denoted with a postscript or superscript "f" rather than "m", so that a fission isomer in, e.g., plutonium 240 is denoted Plutonium-240f or 240f94Pu.

Nearly-stable isomers

Most nuclear excited states are very unstable, and radiate away the extra energy immediately (on the order of 10⁻¹² seconds). As a result, the term is usually restricted to refer to isomers with half-lives of 10⁻⁹ seconds or more. Quantum mechanics predicts that certain atomic species will possess isomers with unusually long lifetimes even by this stricter standard, and so have interesting properties. By definition, there is no such thing as a "stable" isomer; however, some are so long-lived as to be nearly stable, and can be produced and observed in quantity.

The most stable nuclear isomer occurring in nature is 180m73Ta, which is present in all tantalum samples at about 1 part in 8,300. Its half-life is at least 10¹⁵ years, markedly longer than the age of the universe. This remarkable persistence results from the fact that the excitation energy of the isomeric state is low, and gamma de-excitation to the ¹⁸⁰Ta ground state (which is radioactive and has a half-life of only 8 hours), and beta decay to hafnium or tungsten are all suppressed, owing to spin mismatches. The origin of this isomer is mysterious, though it is believed to have been formed in supernovae (as are most other heavy elements). When it relaxes to its ground state, it releases a photon with an energy of 75 keV. It was first reported in 1988 by Collins^[1] that ^180mTa can be forced to release its energy by weaker x-rays. After 11 years of controversy those claims were confirmed in 1999 by Belic and co-workers in the Stuttgart nuclear physics group.^[2]

Another reasonably stable nuclear isomer (with a half-life of 31 years) is 178m272Hf, which has the highest excitation energy of any comparably long-lived isomer. One gram of pure ^178m2Hf contains approximately 1330 megajoules of energy, the equivalent of exploding about 317 kilograms (700 pounds) of TNT. Further, in the natural decay of ^178m2Hf, the energy is released as gamma rays with a total energy of 2.45 MeV. As with ^180mTa, there are disputed reports that ^178m2Hf can be stimulated into releasing its energy, and as a result the substance is being studied as a possible source for gamma ray lasers. These reports also indicate that the energy is released very quickly, so that ^178m2Hf can produce extremely high powers (on the order of exawatts). Other isomers have also been investigated as possible media for gamma-ray stimulated emission.^[3][4]

Holmium has an interesting nuclear isomer, 166m167Ho with a half-life of 1200 years, which is nearly the longest half-life of any holmium radionuclide (only ¹⁶³Ho, with a half life of 4570 years is longer).

22990Th has a remarkably low-lying metastable isomer, only 7.6 ± 0.5 electron volts above the ground state, as calculated from spectroscopic measurements. This direct decay has not been observed, however. If this isomer were to decay it would produce a gamma ray (defined by its origin, not its wavelength) in the ultraviolet range. These "ultraviolet gamma rays" were thought to have been detected at one time,^[5] but this observation has since been found to be from nitrogen gas excited by higher energy emissions.^[6]

Applications

Hafnium and tantalum isomers have been considered in some quarters as weapons that could be used to circumvent the Nuclear Non-Proliferation Treaty, since they can be induced to emit very strong gamma radiation^{[citation needed]}. DARPA has (or had) a program to investigate this use of both nuclear isomers.^[7]

Technetium isomers Tc-99m (with a half-life of 6.01 hours) and Tc-95m (with a half-life of 61 days) are used in medical and industrial applications.

Decay processes

Isomers decay to lower energy states of the nuclide through two isomeric transitions:

1. γ (gamma) emission (emission of a high-energy photon)
2. internal conversion (the energy is used to ionize the atom)

See also

• induced gamma emission
• Isomeric shift

References

1. ^ C.B. Collins et al. (1988). "Depopulation of the isomeric state ¹⁸⁰Ta^m by the reaction ¹⁸⁰Ta^m(γ,γ′)¹⁸⁰Ta". Phys. Rev. C 37: 2267–2269. doi:10.1103/PhysRevC.37.2267. http://www.hafniumisomer.org/isomer/180ta.pdf. 
2. ^ D. Belic et al. (1999). "Photoactivation of ¹⁸⁰Ta^m and Its Implications for the Nucleosynthesis of Nature's Rarest Naturally Occurring Isotope". Phys. Rev. Lett. 83 (25): 5242. doi:10.1103/PhysRevLett.83.5242. 
3. ^ "UNH researchers search for stimulated gamma ray emission". UNH Nuclear Physics Group. 1997. http://einstein.unh.edu/nuclear/NucNews/graser_news.html. Retrieved 1 June 2006. 
4. ^ P.M. Walker, J.J. Carroll (2007). "Nuclear Isomers: Recipes from the Past and Ingredients for the Future". Nuclear Physics News 17 (2): 11. doi:10.1080/10506890701404206. http://epubs.surrey.ac.uk/cgi/viewcontent.cgi?article=1060&context=physicspapers. 
5. ^ R.W. Shaw, J.P. Young, S.P. Cooper, O.F. Webb (1999-02-08). "Spontaneous Ultraviolet Emission from 233Uranium/229Thorium Samples". Physical Review Letters 82 (6): 1109–1111. doi:10.1103/PhysRevLett.82.1109. 
6. ^ S.B. Utter et al. (1999). "Reexamination of the Optical Gamma Ray Decay in ²²⁹Th". Phys. Rev. Lett. 82 (3): 505–508. doi:10.1103/PhysRevLett.82.505. 
7. ^ S. Weinberger (28 March 2004). "Scary things come in small packages". Sunday Supplement Magazine. Washington Post. http://www.washingtonpost.com/ac2/wp-dyn?pagename=article&contentId=A22099-2004Mar24&notFound=true. Retrieved 2009-05-03. 

External links

• Research group which presented initial claims of hafnium nuclear isomer de-excitation control. - The Center for Quantum Electronics, The University of Texas at Dallas.
• JASON Defense Advisory Group report on high energy nuclear materials mentioned in the Washington Post story above
• Bertram Schwarzschild (May 2004). "Conflicting Results on a Long-Lived Nuclear Isomer of Hafnium Have Wider Implications". Physics Today: 21. http://scitation.aip.org/journals/doc/PHTOAD-ft/vol_57/iss_5/21_1.shtml.  login required?
• Confidence for Hafnium Isomer Triggering in 2006. - The Center for Quantum Electronics, The University of Texas at Dallas.
• Reprints of articles about nuclear isomers in peer reviewed journals. - The Center for Quantum Electronics, The University of Texas at Dallas.