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Paul Sabatier

 
Scientist: Paul Sabatier

French chemist (1854–1941)

Sabatier, who was born at Carcassone in southwest France, was a student at the Ecole Normale, Paris, and gained his PhD from the Collège de France in 1880. He became professor of chemistry at the University of Toulouse (1884–1930).

In 1897 Sabatier showed how various organic compounds could undergo hydrogenation, e.g., ethylene will not normally combine with hydrogen but when a mixture of the gases is passed over finely divided nickel, ethane is produced. Benzene can be converted into cyclohexane in the same way. Sabatier discussed the whole problem in his book Le catalyse en chimie organique (1912; Catalysis in Organic Chemistry), published the same year in which he was awarded the Nobel Prize for chemistry for his work on catalytic hydrogenations.

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Food and Nutrition: Paul Sabatier
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(1854-1941) French chemist; jointly with Senderens discovered the process for catalytic hydrogenation of oils to solid fats (1899); Nobel Prize 1912.

Biography: Paul Sabatier
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The French chemist Paul Sabatier (1854-1941) is best known for his work in the field of catalyzed gas phased reactions.

Paul Sabatier was born in Carcassonne on Nov. 5, 1854. After graduating from the École Normale Supérieure in 1874 and teaching a year in the lycée at Nîmes, he became a laboratory assistant at the Colle‧gede France in 1878. Two years later he received his doctoral degree with a thesis on the thermochemistry of sulfur and the metallic sulfides. After serving as maître de conference in physics in the faculty of sciences at Bordeaux for a year, he took charge of the course in physics in the faculty of sciences at Toulouse, the school at which he remained for the rest of his life. He became professor of chemistry in 1884 and went on to become one of the most brilliant representatives of the French chemical school.

After completing his thesis, Sabatier turned his attention to a host of inorganic and physical problems related to the thermochemistry of sulfides, chlorides, and chromates. A detailed study of the rate of transformation of metaphosphoric acid, studies on absorption spectra, and measurement of the partition coefficients of a base between two acids were included in the first 2 decades of his work.

Sabatier's efforts in the field of organic chemistry began about 1897 and led to the enunciation of a theory of catalytic hydrogenation over finely divided metals such as nickel, copper, cobalt, iron, and platinum. With the help of his colleagues he not only carried out a large number of experimental studies on catalytic hydrogenation but also proposed a theory of catalysis that is still useful and sound. He suggested that reactants combine with each other over catalysts as a result of forming unstable complexes or compounds with the catalyst surface. For this hypothesis and for his numerous experimental catalytic studies, science and industry will be eternally grateful.

The chemist received many honors. He was elected a member of the French Academy of Sciences, commander of the Légion d'Honneur, and an honorary member of the Royal Society of London, the Academy of Madrid, and the Royal Netherlands Academy of Sciences. He was awarded many prizes and medals as well, and "for his method of hydrogenating organic compounds in the presence of finely divided nickel" he received the Nobel Prize in chemistry in 1912.

Sabatier is described as being reserved and detached. He was fond of art and gardening. From his marriage to Mademoiselle Herail there were four daughters, one of whom married the Italian chemist Emile Pomilio. Sabatier died on Aug. 14, 1941.

Further Reading

Biographical information on Sabatier is in Eduard Farber, Nobel Prize Winners in Chemistry, 1901-1950 (1953); Eduard Farber, ed., Great Chemists (1961); and Nobel Foundation, Chemistry: Nobel Lectures, Including Presentation Speeches and Laureates' Biographies (3 vols., 1964-1966).

 
Columbia Encyclopedia: Paul Sabatier
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Sabatier, Paul, 1854-1941, French organic chemist, D.Sc. Collège de France, 1880. He joined the faculty at the Univ. of Toulouse in 1882 and taught there until he retired in 1930. Sabatier was a corecipient of the 1912 Nobel Prize in Chemistry with Victor Grignard for his method of hydrogenating organic compounds in the presence of finely disintegrated metals, particularly nickel. His work in catalysis laid the groundwork for a number of laboratory syntheses and also led to the development of margarine, hydrogenated oils, and synthetic methanol.
Wikipedia: Paul Sabatier (chemist)
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Paul Sabatier

Paul Sabatier
Born November 5, 1854
Carcassonne, France
Died August 14, 1941 (aged 86)
Toulouse, France
Nationality France
Fields Inorganic chemistry
Alma mater Collège de France
Doctoral advisor Marcellin Berthelot
Known for Heterogeneous catalysis
Notable awards Nobel Prize for Chemistry (1912)

Paul Sabatier (November 5, 1854 – August 14, 1941) was a French chemist, born at Carcassonne. He taught science classes most of his life before he became Dean of the Faculty of Science in 1905.

Sabatier's earliest research concerned the thermochemistry of sulfur and metallic sulfates, the subject for the thesis leading to his doctorate. In Toulouse, he continued his physical and chemical investigations to sulfides, chlorides, chromates and copper compounds. He also studied the oxides of nitrogen and nitrosodisulfonic acid and its salts and carried out fundamental research on partition coefficients and absorption spectra.

Sabatier greatly facilitated the industrial use of hydrogenation. In 1897, he discovered that the introduction of a trace of nickel as a catalyst facilitated the addition of hydrogen to molecules of carbon compounds.

Sabatier is best known for the Sabatier process and his works such as La Catalyse en Chimie Orgarnique (Catalysis in organic chemistry) which was published in 1913. He won the Nobel Prize in Chemistry jointly with fellow Frenchman Victor Grignard in 1912. He is also known for the Sabatier principle of catalysis.

Sabatier was married with four daughters, one of whom wed the famous Italian chemist Emilio Pomilio.

The Paul Sabatier University in Toulouse is named in honor of Paul Sabatier. Paul Sabatier was a co-founder of the Annales de la Faculté des Sciences de Toulouse, together with the mathematician Thomas Joannes Stieltjes.

See also

References

  • "Paul Sabatier (to 150th anniversary of his birthday)". Russian Journal of Applied Chemistry 77 (11): 1582. 2004. doi:10.1007/s11167-005-0190-6. 
  • E. K. Rideal (1951). "Presidential address. Concepts in catalysis. The contributions of Paul Sabatier and of Max Bodenstein". J. Chem. Soc.: 1640–1647. doi:10.1039/JR9510001640. 
  • Hugh S. Taylor (1944). "Paul Sabatier 1854-1941". J. Chem. Soc. 66 (10): 1615–1617. doi:10.1021/ja01238a600. 

External links

  • Nobel Lecture The Method of Direct Hydrogenation by Catalysis from Nobelprize.org website
  • Biography Biography from Nobelprize.org website

 
 

 

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Scientist. A Dictionary of Scientists. Copyright © Market House Books Ltd 1993, 1999, 2003. All rights reserved.  Read more
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