The simplest member of a class of organic compounds possessing a hydroxyl group attached to a benzene ring or to a more complex aromatic ring system. Phenol itself, C6H5OH, may also be called hydroxybenzene or carbolic acid. Pure phenol is a colorless solid melting at 42°C (108°F), moderately soluble in water, and weakly acidic (pK 9.9).
Phenol has broad biocidal properties, and dilute aqueous solutions have long been used as an antiseptic. At higher concentrations phenol causes severe skin burns; it is a violent systemic poison.
Phenol has the structure shown. Simple substituted phenols, such as the three isomeric chlorophenols, are named as indicated, using the ortho (o), meta (m), and para (p) prefixes. In more highly substituted phenols the positions of substitution are indicated by numbers (as in 2,4-dichlorophenol). Compounds with more than one hydroxyl group per aromatic ring are known as polyhydric phenols, and include catechol, resorcinol, hydroquinone, phloroglucinol, and pyrogallol.

Until World War I phenol was essentially a natural coal tar product. However, synthetic methods have replaced extraction from natural sources. There are many possible syntheses.
Phenol is one of the most versatile and important industrial organic chemicals. It is the starting point for many diverse products used in the home and industry. A partial list includes: nylon, epoxy resins, surface active agents, synthetic detergents, plasticizers, antioxidants, lube oil additives, phenolic resins (with formaldehyde, furfural, and so on), polyurethanes, aspirin, dyes, wood preservatives, herbicides, drugs, fungicides, gasoline additives, inhibitors, explosives, and pesticides. See also Phenolic resin.