rhodonite

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(rōd'n-īt') pronunciation
n.
A pink to rose-red mineral, essentially a glassy crystalline manganese silicate, MnSiO3, used as an ornamental stone.

[From Greek rhodon, rose.]



Rhodonite from Pajsberg, Swed.
(click to enlarge)
Rhodonite from Pajsberg, Swed. (credit: Courtesy of the Field Museum of Natural History, Chicago; photograph, John H. Gerard)
Silicate mineral that occurs in various manganese ores, often with rhodochrosite. A manganese silicate, MnSiO3, with small amounts of iron and calcium, it is found in the Ural Mountains, Sweden, Australia, California, New Jersey, and elsewhere. Rhodonite is the primary source of some important manganese oxide deposits, such as the manganese ores of India. Fine-grained rhodonite of clean, pink colour is a desirable gem and ornamental stone.

For more information on rhodonite, visit Britannica.com.

A mineral inosilicate with composition MnSiO3. Hardness is 5.5–6 on Mohs scale, and specific gravity is 3.4–3.7. The luster is vitreous and the color is rose red, pink, or brown. Rhodonite is similar in color to rhodochrosite, manganese carbonate, but it may be distinguished by its greater hardness and insolubility in hydrochloric acid. It has been found at Langban, Sweden; near Sverdlovsk in the Ural Mountains; and at Broken Hill, Australia. Fine crystals of a zinc-bearing variety, fowlerite, are found at Franklin, New Jersey. See also Silicate minerals.



(Mn,Mg,Fe)SiO
Triclinic -- pinacoidal

Environment

A mineral of metamorphic rocks, related to manganese occurrences; rarely associated with ore veins.

Crystal description

Usually massive, sometimes in fine-grained masses. Good several-cm, equidimensional crystals were found embedded in calcite, in the early days of Franklin, New Jersey. Smaller, flattened, acute-angled crystals of deeper hue are also found there. Similar rich-hued, very cleavable material has been found in Congonhas, Brazil. However, the most significant crystal occurrence of rhodonite is one of large, gemmy, chunky red crystals embedded in galena, at Broken Hill, New South Wales, Australia, with very similar pyroxmangite (MnSiO 3 ) and bustamite ([Mn,Ca] 3 Si 3 O 9 ).

Physical properties

Pink to grayish, blackening rapidly on the surface through weathering. Luster glassy; hardness 5Ɖ-6; specific gravity 3.4-3.7; fracture splintery, very tough in massive state; cleavage prismatic at about 88° and 92°. Crystals brittle; transparent to translucent.

Composition

Manganese silicate (54.1% MnO, 45.9% SiO 2 , with Ca partially replacing Mn).

Tests

Fuses to a brown glass. Gives manganese test in borax bead.

Distinguishing characteristics

The pink material is likely to be mistaken only for rhodochrosite (but it is much harder than the manganese carbonate) and for feldspar, which gives no manganese test or easy fusion. The gemmy red crystals are practically indistinguishable from the similar, closely related iron-bearing pyroxmangite. Bustamite is less intensely red. A black stain quickly develops on exposed internally pinkish boulders and is really diagnostic.

Occurrence

The world's leading specimen locality for large crystal masses is Franklin, New Jersey, a mine from which have come specimens that add luster to museums of the world; the crystals were worked out by careful excavation from a matrix of enclosing calcite. Massive rhodonite is found at Plainfield, Massachusetts, and at numerous western and foreign localities -- California, Brazil (Minas Gerais), Siberia, Australia (Tamworth, New South Wales), and Tanzania, to name a few.

Good and sometimes transparent red crystals are found with other silicates distributed through sulfide ores at Broken Hill, New South Wales (in Japanese manganese mines, pyroxmangite predominates). Masses suitable for carving are found in the Ural Mountains. Small late Franklin-type wedge crystals are found at Pajsberg and Langban, Sweden.



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Rhodonite

Rhodonite crystals in rock
General
Category Silicate mineral
Chemical formula (Mn2+,Fe2+,Mg,Ca)SiO3
Strunz classification 09.DK.05
Dana classification 65.04.01.01
Crystal symmetry Triclinic 1 pinacoidal
Unit cell a = 9.758 Å, b = 10.499 Å, c = 12.205 Å; α = 108.58°, β = 102.92°, γ = 82.52°; Z = 20
Identification
Color Rose-pink to brownish red, gray, or yellow
Crystal habit Tabular crystals, massive, granular
Crystal system Triclinic - Pinacoidal H-M Symbol (1) Space Group: P1
Twinning Lamellar, composition plane {010}
Cleavage Perfect on {110} and {110}, (110) ^ (110) = 92.5°; good on {001}
Fracture Conchoidal to uneven
Mohs scale hardness 5.5 - 6.5
Luster Vitreous to pearly
Streak White
Diaphaneity Transparent to translucent
Specific gravity 3.57 - 3.76
Optical properties Biaxial (+)
Refractive index nα = 1.711 - 1.738 nβ = 1.714 - 1.741 nγ = 1.724 - 1.751
Birefringence δ = 0.013
Pleochroism Weak
2V angle Measured: 58° to 73°, Calculated: 58°
Alters to Exterior commonly black from manganese oxides
References [1][2][3]

Rhodonite is a manganese inosilicate, (Mn, Fe, Mg, Ca)SiO3 and member of the pyroxenoid group of minerals, crystallizing in the triclinic system. It commonly occurs as cleavable to compact masses with a rose-red color (the name comes from the Greek ῥόδος rhodos, rosy), often tending to brown because of surface oxidation.

Rhodonite crystals often have a thick tabular habit, but are rare. It has a perfect, prismatic cleavage, almost at right angles. The hardness is 5.5–6.5, and the specific gravity 3.4–3.7; luster is vitreous, being less frequently pearly on cleavage surfaces. The manganese is often partly replaced by iron, magnesium, calcium, and sometimes zinc which may sometimes be present in considerable amounts; a greyish-brown variety containing as much as 20% of calcium oxide is called bustamite; fowlerite is a zinciferous variety containing 7% of zinc oxide.

Pink rhodonite contrasting with black manganese oxides is sometimes used as a gem material as seen in this specimen from Humboldt Co., Nevada, USA

The inosilicate (chain silicate) structure of rhodonite has a repeat unit of five silica tetrahedra. The rare polymorph pyroxmangite, formed at different conditions of pressure and temperature, has the same chemical composition but a repeat unit of seven tetrahedra.

Rhodonite has also been worked as an ornamental stone. In the iron and manganese mines at Pajsberg near Filipstad and Långban in Värmland, Sweden, small brilliant and translucent crystals (pajsbergite) and cleavage masses occur. Fowlerite occurs as large, rough crystals, somewhat resembling pink feldspar, with franklinite and zinc ores in granular limestone at Franklin Furnace in New Jersey.

Rhodonite is the official gem of Commonwealth of Massachusetts.[4]

See also

References

  1. ^ http://rruff.geo.arizona.edu/doclib/hom/rhodonite.pdf Handbook pf Mineralogy
  2. ^ http://www.mindat.org/min-3407.html Mindat.org
  3. ^ http://webmineral.com/data/Rhodonite.shtml Webmineral data
  4. ^ M.G.L. - Chapter 2, Section 15

 This article incorporates text from a publication now in the public domainChisholm, Hugh, ed. (1911). Encyclopædia Britannica (11th ed.). Cambridge University Press. 



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fowlerite (mineralogy)
manganous silicate (inorganic chemistry)
pyroxenoids (mineralogy)
pyroxene (mineral – in chemistry)