The answer is no. The Sonata for Two Pianos in D major, K. was
composed for two pianos.
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It dates as far back as the 18th century, ex. Mozart's Rondo in A Minor for piano, K 511 (1787).
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At the beginning of the episode, he's playing a part of:
Franz Schubert's Piano Sonata No. 20 in A Major, D. 959, IV.
Rondo. Allegretto.
Later in the episode, he plays a duet with Roz which is:
Mozart's Concerto No. 21.
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The rondo form introduced in classical period is not to be
confused with the renaissance rondo. It is also known as ABACADA
form. The principal theme 'A' restates after each episode (B C and
D as here). A popular example is Mozart's Marcia alla Turka from
his piano sonata, K 331.
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Tchaikovsky orchestrated four piano pieces, three by Mozart and a Liszt piano transcription.
Gigue. Allegro (G major) After the Little Gigue for piano, K. 574.
Menuet. Moderato (D major) After the Minuet for piano, K. 355.
Preghiera. Andante ma non tanto (B flat major) After Franz Liszt's piano transcription of the Ave verum corpus, K. 618.
Thème et variations. Allegro giusto (G major) After the piano Variations on a Theme by Gluck, K. 455.