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Rudolph A. Marcus

 

(born July 21, 1923, Montreal, Que., Can.) Canadian-born U.S. chemist. Educated at McGill University, he worked at the Polytechnic Institute of Brooklyn (from 1951), the University of Illinois (from 1964), and the California Institute of Technology (from 1978). He studied electron transfer in redox reactions in the 1950s and '60s, finding that subtle changes in the molecular structures of the reactants and the solvent molecules around them influence the ability of electrons to move between the molecules. He also discovered the parabolic relationship between the driving force of an electron-transfer reaction and the reaction's rate. His work, which has shed light on fundamental phenomena such as photosynthesis, cell metabolism, and simple corrosion, won him a 1992 Nobel Prize.

For more information on Rudolph A. Marcus, visit Britannica.com.

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Scientist: Rudolph Arthur Marcus
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Canadian-born American chemist (1923–)

Marcus was born in Montreal and educated at McGill University there. After graduating he taught at the Polytechnic Institute, Brooklyn (1951–64) and at the University of Illinois (1968–78). In 1978 he was appointed professor of chemistry at the California Institute of Technology.

In the 1950s Marcus began to work on electron-transfer reactions. The addition, removal, and transfer of electrons is the driving force behind many basic chemical processes including photosynthesis, respiration, and the production of solar energy. Such reactions are, in principle, very simple involving the movement of an electron from one ion to form another ion. The rates of such reactions can, however, vary widely. Marcus was able to explain electron-transfer reaction rates in terms of the way in which the solvent molecules, initially configured to solvate the reactant, reorganize to solvate the products.

Marcus was awarded the 1992 Nobel Prize for chemistry for his work in this field.

 
Columbia Encyclopedia: Rudolph Marcus
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Marcus, Rudolph, 1923-, American chemist, b. Montreal, Canada. A professor at the California Institute of Technology, he was awarded the 1992 Nobel Prize in Chemistry for developing a theory of electron transfer reactions in chemical systems.
Wikipedia: Rudolph A. Marcus
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Rudolph A. Marcus

Rudolph A. Marcus in 2005
Born July 21, 1923
Montreal, Quebec
Citizenship United States
Nationality Canada
Fields Chemistry
Institutions Caltech
Alma mater McGill University
Known for electron transfer
Notable awards Nobel Prize in Chemistry (1992)

Rudolph "Rudy" Arthur Marcus (born July 21, 1923) is a Canadian-born chemist who received the 1992 Nobel Prize in Chemistry[1] for his theory of electron transfer. Marcus theory, named after him, provides a thermodynamic and kinetic framework for describing one electron outer-sphere electron transfer.

He was born in Montreal, Quebec. He earned a B.Sc. in 1943 and a Ph.D. in 1946, both from McGill University. In 1958, he became a naturalized citizen of the United States. He is an active professor at Caltech. He is a member of the International Academy of Quantum Molecular Science.

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Year 1992 (in Science & Technology)
Nobel prizes in chemistry
Nobel Prizes (table)

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