Historically, a common method described in literature was "to
sow salt." In practice this does not actually work, as salt is
soluable and easily carried away by rain.
Soil is partially sterlized through the use of herbicides, such
as Agent Orange or Round Up. Covering patches of soil with black
plastic is another method of sterilization that does not require
adding chemicals. Herbicides are often sprayed along road ways and
side walks to prevent the roots of trees and brush from cracking
the concrete or pavement. Of course, covering land with asphalt is
another effective "sterilization" technique.
Finally, if one can afford the energy, running soil through an
autoclave will sterilize it. This might be done for certain biology
experiments in university laboratories. Soil is not typically
autoclaved for regular agricultural use.