According to SOWPODS (the combination of Scrabble dictionaries used around the world) there are 8 words with the pattern S-P-A----. That is, nine letter words with 1st letter S and 3rd letter P and 5th letter A. In alphabetical order, they are:
sapraemia
sapraemic
septarian
septarium
septation
sopranini
sopranino
sopranist