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There's a great chapter on bryophyte decomposition (including Sphagnum) in Dr. Janice Glime's online Bryophyte Ecology textbook. Sphagnum does decompose, but quite slowly, and one of the reasons is that Sphagnum acidifies its environment. This limits the activity of decomposers.

in other words acid!

Q: Sphagnum does not decompose because the environment is too?

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