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synthetic elements

 
 
Columbia Encyclopedia: synthetic elements
synthetic elements, in chemistry, radioactive elements that were not discovered occurring in nature but as artificially produced isotopes. They are technetium (at. no. 43), which was the first element to be synthesized, promethium (at. no. 61), astatine (at. no. 85), francium (at. no. 87), and the transuranium elements (at. no. 93 and beyond in the periodic table). Some of these elements have since been shown to exist in minute amounts in nature, usually as short-lived members of natural radioactive decay series (see radioactivity).

The synthetic elements through at. no. 100 (fermium) are created by bombarding a heavy element, such as uranium or plutonium, with neutrons or alpha particles. The synthesis of the transfermium elements (elements with at. no. 101 or greater) is accomplished by the fusion of the nuclei of two lighter elements. Elements 101 through 106 were first produced by fusing the nuclei of slightly lighter elements, such as californium, with those of light elements, such as carbon. Elements 107 through 112 were first produced by fusing the nuclei of medium-weight elements, such as bismuth or lead, with those of other medium-weight elements, such as iron, nickel, or zinc. Element 114 was first produced by fusing the nuclei of plutonium and calcium and subsequently by fusing the nuclei of lead and krypton, as was element 116. Element 115 was produced by bombarding americium with calcium, and element 113 resulted from the radioactive decay of element 115. The claim by Lawrence Berkeley National Laboratory to have created element 118 has been retracted.)

The transfermium elements are produced in very small quantities (one atom at a time), and identification is therefore very difficult because of half-lives ranging from minutes to milliseconds and the need to identify the products by methods other than known chemical separations. This has led to controversy over reported discoveries and over the naming of the elements. It has been predicted that one isotope of element 114-containing 114 protons and 184 neutrons-would be very stable because its nucleus would have a full complement of protons and neutrons. Termed an "island of stability," its half-life might be measured in years. However, none of the three isotopes of element 114 synthesized as yet have as many as 184 neutrons, and their half-lives are still in the millisecond range.


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Wikipedia: Synthetic element
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In chemistry, the chemical elements labeled as synthetic are too unstable to be found naturally on Earth. These synthetic elements possess half-lives so short, relative to the age of the Earth, that any atoms of these elements that may have existed when the Earth formed have long since decayed away. Because of this, atoms of synthetic elements are only present on Earth as the product of experiments involving nuclear reactors or particle accelerators via nuclear fusion or neutron absorption. Uranium and thorium have no stable isotopes, but are found naturally in the Earth's crust and atmosphere, so neither of these two elements are called synthetic. Unstable elements such as polonium, radium, and radon—which are formed through the decay of uranium and thorium—can also be found in nature despite having very short half-lives.

The first element discovered through synthesis was technetium. This discovery filled a gap in the periodic table, and the fact that no stable isotopes of technetium exist explains its natural absence on Earth (and the gap). With the longest-lived isotope of technetium, Tc-98, having a 4.2 million year half-life, no technetium remains from the formation of the Earth. Only minute traces of technetium occur naturally in the Earth's crust (as a spontaneous fission product of uranium-238 or by neutron capture in molybdenum ores), but technetium is found naturally in red giant stars.

Atomic mass for natural elements is based on weighted average abundance of natural isotopes occurring in the Earth's crust and atmosphere. For synthetic elements the isotope formed depends on the means of synthesis, so the concept of natural isotope abundance has no meaning. Therefore for synthetic elements the total nucleus (protons plus neutrons) count of the most stable isotope (ie, the isotope with the longest half-life) is listed in brackets as the atomic mass.

Quasi-synthetic[clarification needed] elements include:

(All elements with atomic numbers 1 through 94 are naturally occurring at least in trace quantities)

Provisional names for recently observed synthetic elements:


 
 

 

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Columbia Encyclopedia. The Columbia Electronic Encyclopedia, Sixth Edition Copyright © 2003, Columbia University Press. Licensed from Columbia University Press. All rights reserved. www.cc.columbia.edu/cu/cup/ Read more
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