Polyesters are co-polymers, meaning they have more than one
monomer. Instead of a chain made of repeated identical units,
A-A-A-A-A-A-A-....., they have alternating units,
A-B-A-B-A-B-A-B-.....In theory you start with a dicarboxylic acid
such as terephthalic acid with a diol such as ethylene glycol,
which react by a series of condenstation reactions to form the
polymer. In practice they often start with acid derivatives such as
dimethyl terephthalate, which then reacts by a transesterification
reaction with the glycol. The precise monomers depend on which
polyester you are making, but terephthalic acid and ethylene glycol
make the commonest one, poly(terephthalic ester) or PET.