Thermal expansion: Definition from Answers.com

Concept

Most materials are subject to thermal expansion: a tendency to expand when heated, and to contract when cooled. For this reason, bridges are built with metal expansion joints, so that they can expand and contract without causing faults in the overall structure of the bridge. Other machines and structures likewise have built-in protection against the hazards of thermal expansion. But thermal expansion can also be advantageous, making possible the workings of thermometers and thermostats.

How It Works

Molecular Translational Energy

In scientific terms, heat is internal energy that flows from a system of relatively high temperature to one at a relatively low temperature. The internal energy itself, identified as thermal energy, is what people commonly mean when they say "heat." A form of kinetic energy due to the movement of molecules, thermal energy is sometimes called molecular translational energy.

Temperature is defined as a measure of the average molecular translational energy in a system, and the greater the temperature change for most materials, as we shall see, the greater the amount of thermal expansion. Thus, all these aspects of "heat"—heat itself (in the scientific sense), as well as thermal energy, temperature, and thermal expansion—are ultimately affected by the motion of molecules in relation to one another.

Molecular Motion and Newtonian Physics

In general, the kinetic energy created by molecular motion can be understood within the framework of classical physics—that is, the paradigm associated with Sir Isaac Newton (1642-1727) and his laws of motion. Newton was the first to understand the physical force known as gravity, and he explained the behavior of objects within the context of gravitational force. Among the concepts essential to an understanding of Newtonian physics are the mass of an object, its rate of motion (whether in terms of velocity or acceleration), and the distance between objects. These, in turn, are all components central to an understanding of how molecules in relative motion generate thermal energy.

The greater the momentum of an object—that is, the product of its mass multiplied by its rate of velocity—the greater the impact it has on another object with which it collides. The greater, also, is its kinetic energy, which is equal to one-half its mass multiplied by the square of its velocity. The mass of a molecule, of course, is very small, yet if all the molecules within an object are in relative motion—many of them colliding and, thus, transferring kinetic energy—this is bound to lead to a relatively large amount of thermal energy on the part of the larger object.

Molecular Attraction and Phases of Matter

Yet, precisely because molecular mass is so small, gravitational force alone cannot explain the attraction between molecules. That attraction instead must be understood in terms of a second type of force—electromagnetism—discovered by Scottish physicist James Clerk Maxwell (1831-1879). The details of electromagnetic force are not important here; it is necessary only to know that all molecules possess some component of electrical charge. Since like charges repel and opposite charges attract, there is constant electromagnetic interaction between molecules, and this produces differing degrees of attraction.

The greater the relative motion between molecules, generally speaking, the less their attraction toward one another. Indeed, these two aspects of a material—relative attraction and motion at the molecular level—determine whether that material can be classified as a solid, liquid, or gas. When molecules move slowly in relation to one another, they exert a strong attraction, and the material of which they are a part is usually classified as a solid. Molecules of liquid, on the other hand, move at moderate speeds, and therefore exert a moderate attraction. When molecules move at high speeds, they exert little or no attraction, and the material is known as a gas.

Predicting Thermal Expansion

Coefficient of Linear Expansion

A coefficient is a number that serves as a measure for some characteristic or property. It may also be a factor against which other values are multiplied to provide a desired result. For any type of material, it is possible to calculate the degree to which that material will expand or contract when exposed to changes in temperature. This is known, in general terms, as its coefficient of expansion, though, in fact, there are two varieties of expansion coefficient.

The coefficient of linear expansion is a constant that governs the degree to which the length of a solid will change as a result of an alteration in temperature For any given substance, the coefficient of linear expansion is typically a number expressed in terms of 10⁻⁵/°C. In other words, the value of a particular solid's linear expansion coefficient is multiplied by 0.00001 per °C. (The °C in the denominator, shown in the equation below, simply "drops out" when the coefficient of linear expansion is multiplied by the change in temperature.)

For quartz, the coefficient of linear expansion is 0.05. By contrast, iron, with a coefficient of 1.2, is 24 times more likely to expand or contract as a result of changes in temperature. (Steel has the same value as iron.) The coefficient for aluminum is 2.4, twice that of iron or steel. This means that an equal temperature change will produce twice as much change in the length of a bar of aluminum as for a bar of iron. Lead is among the most expansive solid materials, with a coefficient equal to 3.0.

Calculating Linear Expansion

The linear expansion of a given solid can be calculated according to the formula δL = aL_OΔT. The Greek letter delta (d) means "a change in"; hence, the first figure represents change in length, while the last figure in the equation stands for change in temperature. The letter a is the coefficient of linear expansion, and L_O is the original length.

Suppose a bar of lead 5 meters long experiences a temperature change of 10°C; what will its change in length be? To answer this, a (3.0 · 10⁻⁵/°C) must be multiplied by L_O (5 m) and δT (10°C). The answer should be 150 & 10⁻⁵ m, or 1.5 mm. Note that this is simply a change in length related to a change in temperature: if the temperature is raised, the length will increase, and if the temperature is lowered by 10°C, the length will decrease by 1.5 mm.

Volume Expansion

Obviously, linear equations can only be applied to solids. Liquids and gases, classified together as fluids, conform to the shape of their container; hence, the "length" of any given fluid sample is the same as that of the solid that contains it. Fluids are, however, subject to volume expansion—that is, a change in volume as a result of a change in temperature.

To calculate change in volume, the formula is very much the same as for change in length; only a few particulars are different. In the formula δV = bV_OδT, the last term, again, means change in temperature, while δV means change in volume and V_O is the original volume. The letter b refers to the coefficient of volume expansion. The latter is expressed in terms of 10⁻⁴/°C, or 0.0001 per °C.

Glass has a very low coefficient of volume expansion, 0.2, and that of Pyrex glass is extremely low—only 0.09. For this reason, items made of Pyrex are ideally suited for cooking. Significantly higher is the coefficient of volume expansion for glycerin, an oily substance associated with soap, which expands proportionally to a factor of 5.1. Even higher is ethyl alcohol, with a volume expansion coefficient of 7.5.

Real-Life Applications

Liquids

Most liquids follow a fairly predictable pattern of gradual volume increase, as a response to an increase in temperature, and volume decrease, in response to a decrease in temperature. Indeed, the coefficient of volume expansion for a liquid generally tends to be higher than for a solid, and—with one notable exception discussed below—a liquid will contract when frozen.

The behavior of gasoline pumped on a hot day provides an example of liquid thermal expansion in response to an increase in temperature. When it comes from its underground tank at the gas station, the gasoline is relatively cool, but it will warm when sitting in the tank of an already warm car. If the car's tank is filled and the vehicle left to sit in the sun—in other words, if the car is not driven after the tank is filled—the gasoline might very well expand in volume faster than the fuel tank, overflowing onto the pavement.

Engine Coolant

Another example of thermal expansion on the part of a liquid can be found inside the car's radiator. If the radiator is "topped off" with coolant on a cold day, an increase in temperature could very well cause the coolant to expand until it overflows. In the past, this produced a problem for car owners, because car engines released the excess volume of coolant onto the ground, requiring periodic replacement of the fluid.

Later-model cars, however, have an overflow container to collect fluid released as a result of volume expansion. As the engine cools down again, the container returns the excess fluid to the radiator, thus, "recycling" it. This means that newer cars are much less prone to overheating as older cars. Combined with improvements in radiator fluid mixtures, which act as antifreeze in cold weather and coolant in hot, the "recycling" process has led to a significant decrease in breakdowns related to thermal expansion.

Water

One good reason not to use pure water in one's radiator is that water has a far higher coefficient of volume expansion than a typical engine coolant. This can be particularly hazardous in cold weather, because frozen water in a radiator could expand enough to crack the engine block.

In general, water—whose volume expansion coefficient in the liquid state is 2.1, and 0.5 in the solid state—exhibits a number of interesting characteristics where thermal expansion is concerned. If water is reduced from its boiling point—212°F (100°C) to 39.2°F (4°C) it will steadily contract, like any other substance responding to a drop in temperature. Normally, however, a substance continues to become denser as it turns from liquid to solid; but this does not occur with water.

At 32.9°F, water reaches it maximum density, meaning that its volume, for a given unit of mass, is at a minimum. Below that temperature, it "should" (if it were like most types of matter) continue to decrease in volume per unit of mass, but, in fact, it steadily begins to expand. Thus, it is less dense, with a greater volume per unit of mass, when it reaches the freezing point. It is for this reason that when pipes freeze in winter, they often burst—explaining why a radiator filled with water could be a serious problem in very cold weather.

In addition, this unusual behavior with regard to thermal expansion and contraction explains why ice floats: solid water is less dense than the liquid water below it. As a result, frozen water stays at the top of a lake in winter; since ice is a poor conductor of heat, energy cannot escape from the water below it in sufficient amounts to freeze the rest of the lake water. Thus, the water below the ice stays liquid, preserving plant and animal life.

Gases

The Gas Laws

As discussed, liquids expand by larger factors than solids do. Given the increasing amount of molecular kinetic energy for a liquid as compared to a solid, and for a gas as compared to a liquid, it should not be surprising, then, to learn that gases respond to changes in temperature with a volume change even greater than that of liquids. Of course, where a gas is concerned, "volume" is more difficult to measure, because a gas simply expands to fill its container. In order for the term to have any meaning, pressure and temperature must be specified as well.

A number of the gas laws describe the three parameters for gases: volume, temperature, and pressure. Boyle's law, for example, holds that in conditions of constant temperature, an inverse relationship exists between the volume and pressure of a gas: the greater the pressure, the less the volume, and vice versa. Even more relevant to the subject of thermal expansion is Charles's law.

Charles's law states that when pressure is kept constant, there is a direct relationship between volume and temperature. As a gas heats up, its volume increases, and when it cools down, its volume reduces accordingly. Thus, if an air mattress is filled in an air-conditioned room, and the mattress is then taken to the beach on a hot day, the air inside will expand. Depending on how much its volume increases, the expansion of the hot air could cause the mattress to "pop."

Volume Gas Thermometers

Whereas liquids and solids vary significantly with regard to their expansion coefficients, most gases follow more or less the same pattern of expansion in response to increases in temperature. The predictable behavior of gases in these situations led to the development of the constant gas thermometer, a highly reliable instrument against which other thermometers—including those containing mercury (see below)—are often gauged.

In a volume gas thermometer, an empty container is attached to a glass tube containing mercury. As gas is released into the empty container, this causes the column of mercury to move upward. The difference between the former position of the mercury and its position after the introduction of the gas shows the difference between normal atmospheric pressure and the pressure of the gas in the container. It is, then, possible to use the changes in volume on the part of the gas as a measure of temperature. The response of most gases, under conditions of low pressure, to changes in temperature is so uniform that volume gas thermometers are often used to calibrate other types of thermometers.

Solids

Many solids are made up of crystals, regular shapes composed of molecules joined to one another as though on springs. A spring that is pulled back, just before it is released, is an example of potential energy, or the energy that an object possesses by virtue of its position. For a crystalline solid at room temperature, potential energy and spacing between molecules are relatively low. But as temperature increases and the solid expands, the space between molecules increases—as does the potential energy in the solid.

In fact, the responses of solids to changes in temperature tend to be more dramatic, at least when they are seen in daily life, than are the behaviors of liquids or gases under conditions of thermal expansion. Of course, solids actually respond less to changes in temperature than fluids do; but since they are solids, people expect their contours to be immovable. Thus, when the volume of a solid changes as a result of an increase in thermal energy, the outcome is more noteworthy.

Jar Lids and Power Lines

An everyday example of thermal expansion can be seen in the kitchen. Almost everyone has had the experience of trying unsuccessfully to budge a tight metal lid on a glass container, and after running hot water over the lid, finding that it gives way and opens at last. The reason for this is that the high-temperature water causes the metal lid to expand. On the other hand, glass—as noted earlier—has a low coefficient of expansion. Otherwise, it would expand with the lid, which would defeat the purpose of running hot water over it. If glass jars had a high coefficient of expansion, they would deform when exposed to relatively low levels of heat.

Another example of thermal expansion in a solid is the sagging of electrical power lines on a hot day. This happens because heat causes them to expand, and, thus, there is a greater length of power line extending from pole to pole than under lower temperature conditions. It is highly unlikely, of course, that the heat of summer could be so great as to pose a danger of power lines breaking; on the other hand, heat can create a serious threat with regard to larger structures.

Expansion Joints

Most large bridges include expansion joints, which look rather like two metal combs facing one another, their teeth interlocking. When heat causes the bridge to expand during the sunlight hours of a hot day, the two sides of the expansion joint move toward one another; then, as the bridge cools down after dark, they begin gradually to retract. Thus the bridge has a built-in safety zone; otherwise, it would have no room for expansion or contraction in response to temperature changes. As for the use of the comb shape, this staggers the gap between the two sides of the expansion joint, thus minimizing the bump motorists experience as they drive over it.

Expansion joints of a different design can also be found in highways, and on "highways" of rail. Thermal expansion is a particularly serious problem where railroad tracks are concerned, since the tracks on which the trains run are made of steel. Steel, as noted earlier, expands by a factor of 12 parts in 1 million for every Celsius degree change in temperature, and while this may not seem like much, it can create a serious problem under conditions of high temperature.

Most tracks are built from pieces of steel supported by wooden ties, and laid with a gap between the ends. This gap provides a buffer for thermal expansion, but there is another matter to consider: the tracks are bolted to the wooden ties, and if the steel expands too much, it could pull out these bolts. Hence, instead of being placed in a hole the same size as the bolt, the bolts are fitted in slots, so that there is room for the track to slide in place slowly when the temperature rises.

Such an arrangement works agreeably for trains that run at ordinary speeds: their wheels merely make a noise as they pass over the gaps, which are rarely wider than 0.5 in (0.013 m). A high-speed train, however, cannot travel over irregular track; therefore, tracks for high-speed trains are laid under conditions of relatively high tension. Hydraulic equipment is used to pull sections of the track taut; then, once the track is secured in place along the cross ties, the tension is distributed down the length of the track.

Thermometers and Thermostats

Mercury in Thermometers

A thermometer gauges temperature by measuring a temperature-dependent property. A thermostat, by contrast, is a device for adjusting the temperature of a heating or cooling system. Both use the principle of thermal expansion in their operation. As noted in the example of the metal lid and glass jar above, glass expands little with changes in temperature; therefore, it makes an ideal container for the mercury in a thermometer. As for mercury, it is an ideal thermometric medium—that is, a material used to gauge temperature—for several reasons. Among these is a high boiling point, and a highly predictable, uniform response to changes in temperature.

In a typical mercury thermometer, mercury is placed in a long, narrow sealed tube called a capillary. Because it expands at a much faster rate than the glass capillary, mercury rises and falls with the temperature. A thermometer is calibrated by measuring the difference in height between mercury at the freezing point of water, and mercury at the boiling point of water. The interval between these two points is then divided into equal increments in accordance with one of the well-known temperature scales.

The Bimetallic Strip in Thermostats

In a thermostat, the central component is a bimetallic strip, consisting of thin strips of two different metals placed back to back. One of these metals is of a kind that possesses a high coefficient of linear expansion, while the other metal has a low coefficient. A temperature increase will cause the side with a higher coefficient to expand more than the side that is less responsive to temperature changes. As a result, the bimetallic strip will bend to one side.

When the strip bends far enough, it will close an electrical circuit, and, thus, direct the air conditioner to go into action. By adjusting the thermostat, one varies the distance that the bimetallic strip must be bent in order to close the circuit. Once the air in the room reaches the desired temperature, the high-coefficient metal will begin to contract, and the bimetallic strip will straighten. This will cause an opening of the electrical circuit, disengaging the air conditioner.

In cold weather, when the temperature-control system is geared toward heating rather than cooling, the bimetallic strip acts in much the same way—only this time, the high-coefficient metal contracts with cold, engaging the heater. Another type of thermostat uses the expansion of a vapor rather than a solid. In this case, heating of the vapor causes it to expand, pushing on a set of brass bellows and closing the circuit, thus, engaging the air conditioner.

Where to Learn More

Beiser, Arthur. Physics, 5th ed. Reading, MA: Addison-Wesley, 1991.

"Comparison of Materials: Coefficient of Thermal Expansion" (Web site). <http://www.handyharmancanada.com/TheBrazingBook/comparis.html> (April 21, 2001).

Encyclopedia of Thermodynamics (Web site). <http://therion.minpet.unibas.ch/minpet/groups/thermodict/> (April 12, 2001).

Fleisher, Paul. Matter and Energy: Principles of Matter and Thermodynamics. Minneapolis, MN: Lerner Publications, 2002.

NPL: National Physics Laboratory: Thermal Stuff: Begin ners' Guides (Web site). <http://www.npl.co.uk/npl/cbtm/thermal/stuff/guides.html> (April 18, 2001).

Royston, Angela. Hot and Cold. Chicago: Heinemann Library, 2001.

Suplee, Curt. Everyday Science Explained. Washington, D.C.: National Geographic Society, 1996.

"Thermal Expansion Measurement" (Web site). <http://www.measurementsgroup.com/guide/tn/tn513/513intro.html> (April 21, 2001).

"Thermal Expansion of Solids and Liquids" (Web site). <http://www.physics.mun.ca/~gquirion/P2053/html19b/> (April 21, 2001).

Walpole, Brenda. Temperature. Illustrated by Chris Fair-clough and Dennis Tinkler. Milwaukee, WI: Gareth Stevens Publishing, 1995.

This article does not cite any references or sources. Please help improve this article by adding citations to reliable sources. Unverifiable material may be challenged and removed. (January 2009)

Material Properties
Specific heat	$c=\frac{T}{N}\left(\frac{\partial S}{\partial T}\right)$
Compressibility	$\beta=-\frac{1}{V}\left(\frac{\partial V}{\partial p}\right)$
Thermal expansion	$\alpha=\frac{1}{V}\left(\frac{\partial V}{\partial T}\right)$

Thermal expansion is the tendency of a matter to change in volume in response to a change in temperature. When a substance is heated, its constituent particles begin moving and become active thus maintaining a greater average separation. Materials which interact with increasing temperature are rare ; this effect is limited in size, and only occurs within limited temperature ranges. The degree of expansion divided by the change in temperature is called the material's coefficient of thermal expansion and generally varies with temperature.

Common engineering solids usually have thermal expansion coefficients that do not vary significantly over the range of temperatures where they are designed to be used, so where extremely high accuracy is not required, calculations can be based on a constant, average, value of the coefficient of expansion.

Materials with anisotropic structures, such as crystals and composites, will generally have different expansion coefficients in different orientations.

To more accurately calculate thermal expansion of a substance a more advanced equation of state must be used, which will then predict the values of the thermal expansion at all the required temperatures and pressures, along with many other state functions.

For solid materials with a significant length, like rods or cables, an estimate of the amount of thermal expansion can be described by the $\frac{}{}\epsilon_{thermal}$ ratio of strain:

$\epsilon_{thermal} = \frac{(L_{final} - L_{initial})} {L_{initial}}$

$\frac{}{}L_{initial}$ is the initial length before the change of temperature and

$\frac{}{}L_{final}$ the final length recorded after the change of temperature.

For most solids, thermal expansion relates directly with temperature:

$\epsilon_{thermal} \propto {\Delta T }$

Thus, the change in either the strain or temperature can be estimated by:

$\frac{}{} \epsilon_{thermal} = \alpha \Delta T$

where

$\frac{}{}\Delta T = (T_{final} - T_{initial})$

and

$\frac{}{}\alpha$ is the coefficient of thermal expansion in inverse kelvins.

$\frac{}{}\Delta T$ is the difference of the temperature between the two recorded strains, measured in Celsius or kelvin.

A number of materials contract on heating within certain temperature ranges; we usually speak of negative thermal expansion, rather than thermal contraction, in such cases. For example, the coefficient of thermal expansion of water drops to zero as it is cooled to roughly 4 °C and then becomes negative below this temperature, this means that water has a maximum density at this temperature, and this leads to bodies of water maintaining this temperature at their lower depths during extended periods of sub-zero weather.

Thermal expansion generally decreases with increasing bond energy, which also has an effect on the hardness of solids, so, harder materials are more likely to have lower thermal expansion. In general, liquids expand slightly more than solids.

In many common materials, changes in size can also be due to water (or other solvents) being absorbed/desorbed, and many organic materials change size much more due to this effect than they do to thermal expansion. Common plastics exposed to water can, in the long term, expand many percent.

Heat-induced expansion has to be taken into account in most areas of engineering. A few examples are:

Metal framed windows need rubber spacers
Metal hot water heating pipes should not be used in long straight lengths
Large structures such as railways and bridges need expansion joints in the structures to avoid sun kink
One of the reasons for the poor performance of cold car engines is that parts have inefficiently large spacings until the normal operating temperature is achieved.
A gridiron pendulum uses an arrangement of different metals to maintain a more temperature stable pendulum length.

This phenomenon can also be put to good use, for example in the process of thermal shrink-fitting parts are assembled with each at a different temperature, and sized such that when they reach the same temperature, the thermal expansion of the parts forces them together to form a stable joint.

Thermometers are another example of an application of thermal expansion—most contain a liquid which is constrained to flow in only one direction (along the tube) due to changes in volume brought about by changes in temperature. A bi-metal mechanical thermometer uses a bi-metal strip and registers changes based on the differing coefficient of thermal expansion between the two materials.

Anisotropy

Many solid materials will expand evenly in all three directions, but this is not true for all. Graphite for example has a pronounced layer structure and the expansion in the direction perpendicular to the layers is quite different from that in the layers. In general the proper description of the thermal expansion of a solid must therefore include its symmetry. For cubic materials a single expansion coefficient suffices, but for a material with triclinic symmetry six parameters must be distinguished, three for each of the three axes (a,b,c) and three for the change in the angles (α,β,γ) between them. An excellent way of measuring the entire expansion tensor is to perform powder diffraction on the material during a heating or cooling run and monitor the position of its diffraction peaks.

External links

Glass Thermal Expansion Thermal expansion measurement, definitions, thermal expansion calculation from the glass composition

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	Coefficient
	Coefficient of Linear Expansion
	Coefficient of Volume Expansion

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