Alpha-tocopherol is a version of vitamin E that contains no
double bonds. When alpha-tocopherol is delivered to the liver via
chylomicron reminants it binds to a binding protein to become
rrr-alpha-tocopherol. RRR-alpha-tocopherol is incorporated into
VLDL (very low density lipoproteins) membranes and is delivered to
perpherial tissues and to LDL. RRR-alpha-tocopherol acts as an
antioxidant to prevent polyunsaturated fatty acids from oxidation
within VLDL and LDL. Without rrr-alpha-tocopherol oxidation of this
fatty acids can occur and cause atherosclerosis.