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Ultimate Iron Man happened on 2005-03-01.
Yes he is
Ultimate Spider-Man - 2012 The Iron Octopus 1-22 is rated/received certificates of:
USA:TV-Y7
You unlock it on the battle at the bottom of the third room on the Helicarrier on protect the engine room mission.
Ultimate Spider-Man - 2012 Flight of the Iron Spider 1-5 is rated/received certificates of: