It could be used, yes and would be understandable. Here are some more synonys: assumptive, arrogant, cavalier, chesty, haughty, highfalutin (also hifalutin), high-and-mighty, high-handed, high-hat, huffish, huffy, imperious, important, lofty, lordly, masterful, overweening, peremptory, pompous, presuming, presumptuous, pretentious, self-asserting, self-assertive, sniffy, stiff-necked, supercilious, superior, toplofty (alsotoploftical), uppish, uppity.