To print your current Windows screen, you have to copy it to the clipboard, then paste the clipboard into a graphics or desktop publishing program and print it from there.
To copy the current window into the clipboard, press Alt-PrintScreen (Alt-PrtSc) on the keyboard. To copy the entire screen with all the windows showing, press PrintScreen. Sometimes, it is necessary to press the PrintScreen key twice.
Then, launch any application you can paste an image into, such as a paint, drawing or desktop publishing program, and paste the clipboard image into a new document by selecting PASTE from the Edit menu. Print the screen capture from this application.
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