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producer gas

 
Dictionary: producer gas
 

n.

A combustible mixture of nitrogen, carbon monoxide, and hydrogen, generated by passing air with steam over burning coke or coal in a furnace and used as fuel. Also called air gas.


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Chemistry Dictionary: producer gas
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Variant: air gas

A mixture of carbon monoxide and nitrogen made by passing air over very hot carbon. Usually some steam is added to the air and the mixture contains hydrogen. The gas is used as a fuel in some industrial processes.



 
Columbia Encyclopedia: producer gas
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producer gas, fuel gas consisting chiefly of carbon monoxide and nitrogen. It is prepared in a furnace or generator in which air is forced upward through a burning fuel of coal or coke. Although the fuel is introduced through the top, no air is admitted there. The carbon of the fuel is oxidized by the oxygen of the air from below to form the carbon monoxide. The nitrogen of the air, being inert, passes through the fire without change. When steam is introduced with the air, the final gaseous product contains hydrogen also. Producer gas has a low heating value because it is about 60% inert nitrogen. It is widely used in industry because it can be made with cheap fuel. When producer gas contains hydrogen, it is also a source material for the manufacture of synthetic ammonia.


 
WordNet: air gas
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Note: click on a word meaning below to see its connections and related words.

The noun has one meaning:

Meaning #1: a gas made of carbon monoxide and hydrogen and nitrogen; made by passing air over hot coke
  Synonym: producer gas


 
Wikipedia: Wood gas
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Wood gasifier on a Ford truck converted into a tractor

Wood gas is a syngas also known as producer gas which is produced by thermal gasification of biomass or other carbon containing materials such as coal in a gasifier or wood gas generator or producer gas. It is the result of two high-temperature reactions (above 700 °C (1,292 °F)): an exothermic reaction where carbon burns to CO2 but is then reduced partially back to CO (endothermic); and an endothermic reaction where carbon reacts with steam, producing carbon monoxide (CO), molecular hydrogen (H2), and carbon dioxide (CO2).

In several gasifiers, the actual gasification process is preceded by pyrolysis, where the biomass or coal turns into char, releasing methane (CH4) and tar rich in polycyclic aromatic hydrocarbons (PAH). Other gasifiers are fed with previously pyrolysed char. Wood gas is flammable because of the carbon monoxide, hydrogen, and methane content.

Contents

Production

Fluidized bed gasifier in Güssing, Austria, operated on wood chips

A wood gasifier takes wood chips, sawdust, charcoal, coal, rubber or similar materials as fuel and burns these incompletely in a fire box, producing solid ashes and soot (which have to be removed periodically from the gasifier) and wood gas. The wood gas can then be filtered for tars and soot/ash particles, cooled and directed to an engine or fuel cell to produce electricity. Most of these engines have severe purity requirements of the wood gas, so the gas often has to pass through extensive gas cleaning in order to remove or convert (i.e. to "crack") tars and particles. The removal of tar is often accomplished by using a water scrubber. Running wood gas in an unmodified gasoline-burning internal combustion engine may lead to problematic build-up of unburned compounds.

The quality of the gas from different gasifier varies a great deal. Staged gasifiers, where pyrolysis and gasification occur separately (instead of in the same reaction zone as was the case in e.g. the WWII gasifiers) can be engineered to produce essentially tar-free gas ( less than 1 mg/m³), while single reactor fluid-bed gasifiers may exceed 50,000 mg/m³ tar. The fluid bed reactors have the advantage of being much more compact (more capacity per volume and price). Depending on the intended use of the gas, tar can be beneficial as well by increasing the heating value of the gas.

The heat of combustion of producer gas is rather low compared to other fuels. Taylor [1] reports that "producer gas" has a lower heating value of 5.7 MJ/kg versus 55.9 MJ/kg for natural gas and 44.1 MJ/kg for gasoline. The heating value of wood is typically 15-18 MJ/kg. Presumably, these values can vary somewhat from sample to sample. The same source reports the following chemical composition by volume which most likely is also variable:

A charcoal gas producer at the Nambassa alternative festival in New Zealand in 1981

Usage in reciprocating engines

Wood gasifiers can power either spark ignition engines where 100% of the normal petrol can be replaced with little change to the carburation, or in a diesel engine by simply feeding the gas into the air inlet when the diesel governor automatically cuts back the diesel to fuel to between 15% - 40%. In the latter case the diesel fuel is still needed to ignite the gas. Wood can be used to power cars with ordinary internal combustion engines if a wood gasifier is attached. This was quite popular during World War II in several European and Asian countries because the war prevented easy and cost-effective access to oil. In more recent times, wood gas has been suggested as a clean and efficient method to heat and cook in developing countries, or even to produce electricity when combined with a gas turbine or internal combustion engine. Compared to the WWII technology, gasifiers have become less dependent on constant attention due to the use of sophisticated electronic control systems, but it remains difficult to get clean gas from them. Purification of the gas and feeding it into the natural gas pipelines is one variant to link it to existing refueling infrastructure. Liquification by the Fischer-Tropsch process is another possibility.

Efficiency rate of the gasifier system is relatively high. The gasification stage converts about 75% of fuel energy content into a combustible gas that can be used as fuel for internal combustion engines. Based on long term practical experiments and over 100 000 km driven with wood gas powered car, the energy consumption has been 1.54 times more compared to the energy demand of the same car on petrol (not including the energy needed to extract, transport and refine the oil from which petrol is derived). This means that 1000 kg of wood combustible matter has been found to substitute 365 litres of petrol during real transportation in similar driving conditions and with the same otherwise unmodified vehicle [2]. This can be considered to be a good result, because no other refining of the fuel is required. This study also considers all possible losses of the wood gas system like preheating of the system and carrying of the extra weight of the gas generating system.

Gasifiers have been built for remote Asian communities using rice husk, which in many cases has no other use. One installation in Burma uses an 80kW modified diesel for about 500 people who are otherwise without power.[3] The ash can be used as fertilizer so this can be considered a renewable fuel. It has been suggested that the rice husk ash, which is particularly pure and high in silica can be used at high economic value in e.g. semiconductor manufacture.

Against general belief, exhaust gas emission level of internal combustion engine is significantly lower on wood gas than on petrol. Especially low are HC emissions. A normal catalytic converter works well with wood gas but even without it, emission level less than 20 ppm HC and 0,2 % CO can be easily achieved by most automobile engines. Combustion of wood gas generates no particulates and the gas thus renders very little carbon black amongst motor oil.

Use in stoves, cooking and furnaces

Certain designs of stove, are in effect a gasifier working on the updraft principle - the air passes up through the fuel, which can be a column of rice husks, and is combusted, then reduced to carbon monoxide by the residual char on the surface. The resulting gas is then burnt by heated secondary coming up a concentric tube. Such a device behaves very much like a gas stove. This arrangement is also known as a Chinese burner.

However, one must take into account that the carbon monoxide, which is part of the wood gas, is very toxic, while being difficult to notice due to its odorless and colorless nature.

History

The first wood gasifier was apparently built by Bischof in 1839. The first vehicle powered by wood gas was built by Thomas Hugh Parker in 1901.[4]

Blue gas was used as a secondary fuel source for some zeppelin designs of the early 20th century, stored in gas cells within the envelope, just below the hydrogen gas cells. The engines could use either the blue gas or liquid petroleum-based fuel for power, but the former, having a density similar to air, required little change in ballast as it was consumed.

Around 1900, many cities delivered wood gas (centrally produced typically from coal) to residences. At this time also, Rudolf Diesel and Georges Imbert were also developing their various engines. It has been theorized that all of these internal combustion engines had been inspired by observing the operation of the fire piston fire making device which had been discovered in New Guinea and Sumatra early in the 1800s.[5] Natural gas began to be used only in 1930.

Wood gasifiers are still manufactured in Singapore, China and Russia for automobiles and as power generators for industrial applications.

See also


References

  1. ^ Taylor, Charles Fayette (1985). Internal-Combustion Engine in Theory and Practice - Vol.1. Cambridge: The MIT Press. pp. 46–47. ISBN 0-262-70027-1. 
  2. ^ Mikkonen, Vesa (2008). Wood Gas for Mobile Applications. Published by the author, available at www.ekomobiili.fi. pp. 29. 
  3. ^ Burmese village rice husk gasifier
  4. ^ "Thomas Hugh Parker". http://www.localhistory.scit.wlv.ac.uk/genealogy/Parker/ThomasHughParker.htm. 
  5. ^ Diesel Story. [Film]. Prelinger Archives: Shell Oil. 1952. http://www.archive.org/details/diesel_story. Retrieved on 2007-02-16. 

External links


 
 

 

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Dictionary. The American Heritage® Dictionary of the English Language, Fourth Edition Copyright © 2007, 2000 by Houghton Mifflin Company. Updated in 2007. Published by Houghton Mifflin Company. All rights reserved.  Read more
Chemistry Dictionary. A Dictionary of Chemistry. Sixth Edition. Copyright © Market House Books Ltd, 2008. All rights reserved.  Read more
Columbia Encyclopedia. The Columbia Electronic Encyclopedia, Sixth Edition Copyright © 2003, Columbia University Press. Licensed from Columbia University Press. All rights reserved. www.cc.columbia.edu/cu/cup/  Read more
WordNet. WordNet 1.7.1 Copyright © 2001 by Princeton University. All rights reserved.  Read more
Wikipedia. This article is licensed under the GNU Free Documentation License. It uses material from the Wikipedia article "Wood gas" Read more