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Actually it's a chemical change. The baking soda reacts with the vinegar to produce carbon dioxide gas, which is why it fizzes when you mix the two together. The reaction between the two is listed below:

NaHCO3(s) {baking soda} + CH3COOH(aq) {vinegar} ---> NaCH3COO(aq) + CO2(g) + H2O(l)

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Q: Baking powder mixed with vinegar is physical change?
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