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Pikachu cannot naturally learn Volt Tackle.

One way for a Pikachu to know Volt Tackle is if it was a Mystery Gift Pikachu from PKMN Battle Revolution.

The only other way for a Pikachu to know Volt Tackle is by breeding (using a Ditto with a Pikachu or Raichu will work) a Pikachu or Raichu that is holding a Light Ball. The hatched Pichu will know moves passed from its father and Volt Tackle.

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Q: Can Pikachu use volt tackle by using charge then quick attack?
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When does Pikachu learn discharge?

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What are Pikachu's moves and what do they do in Pokemon Yellow?

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