Yes.
The pope is a priest and bishop and. as such, can administer all 7 sacraments.
Roman Catholic AnswerA bishop may administer all of the sacraments and is the ordinary minister for all of them. A priest is incapable of ordaining and may only confirm with the permission of his bishop. A deacon may baptise, and witness marriage.
Because a Bishop has the fullness of the priesthood of Christ, he, alone, can administer all the sacraments, and is empowered by the Holy Spirit to complete baptism with confirmation.
Roman Catholic AnswerSix: Baptism, Confirmation, Eucharist, Penance, Matrimony, Anointing. Any priest may administer these sacraments if he is properly licensed by a Bishop. A priest (parish or otherwise) is incapable of ordination. This is reserved to the Bishop. Confirmation is normally reserved to a Bishop except under particular circumstances.
Holy Orders is the sacrament through which a man is ordained as a deacon, priest, or bishop by the laying on of hands and prayer. This sacrament conveys a special grace and power to serve the Church and administer the other sacraments. It is one of the seven sacraments recognized by the Roman Catholic Church.
.Catholic AnswerThe imposition of the Bishop's hands on the Ordinand (the man being ordained) and saying the accompanying prayer.
The bishop
A bishop is head of the diocese in which he practices. He is the chief minister or pastor within the region or diocese. Often a bishop is the one to administer certain religious sacraments such as Confirmation.
As clerics, deacons are required to say the Liturgy of the Hours daily; Deacons, like bishops and priests, are ordinary ministers of the Sacrament of Baptism and can serve as the church's witness at the sacrament of Holy Matrimony, which the bride and groom administer to each other.
Holy Orders.
Quite a few, actually, but the two best known are: A Bishop can confirm and ordain. A priest cannot administer ordination and can only administer confirmation under certain circumstances with a Bishop's permission. Also, a Bishop is considered the primary exorcist, priests can only exorcise if they have been appointed by the Bishop.
The sacrament of Holy Orders can be administered to a priest by a bishop who has the authority to ordain priests within the Catholic Church.