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By definition, a conductor conducts electrical current. That say, the goodness of conduction varies among conductors-- the best being silver, whose electrical conductivity is 6.3E-7 [S/m]. Then copper, gold, ..., and so on. The least conductive metal or metal alloy is NiCr. Carbon, silicon, and Germanium (also certain III-V and II-VI compounds) belong to the semiconductor group. Outside conductors and semiconductors would be insulators. All elements/compounds have varying degrees of 'goodness.' Check Wikipedia for the whole picture (for example, http://en.wikipedia.org/wiki/Electrical_conductivity).

To answer your question, all materials conduct electrical current somehow. But practically, it is safe to insulate yourself with an insulator -- consult an expert for safety reasons. Semiconductors become a poor conductor at a high-enough temperature. It is definitely unsafe to touch metallic materials within turning the power off first.

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