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All of the allotrpes of phosphorus are covalent and can all be crystallised. The white form consiste of P4 molecules- growing crystals is not easy but can be done as X-Ray structures have been published.

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Q: Can phosphorus exist as covalent crystals?
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Can phosphorus exists as covalent crystals in the solid state?

Phosphorus can, in fact, exist as covalent crystals in the solid state. Phosphorus usually exists in the solid state as non-covalent crystals. Under intense pressure, however, the bonds can become covalent.


Is carbon the only covalent solid?

No, sulfur and phosphorus are another two examples for elements which exist as covalent solids.


Does sulfur and phosphorus ionic bond?

No. Carbon does not form ionic bonds, and in this case they are double-covalent bonds.


Are phosphorus and argon molecular covalent or network covalent?

Phosphorus forms molecular covalent bonds because it exists as discrete P4 molecules, while argon does not form covalent bonds at all since it is a noble gas and exists as individual atoms.


Is phosphorus trifluoride covalent or ionic?

Phosphorus trifluoride is a covalent compound. It consists of nonmetals bonding together by sharing electrons, rather than transferring them as in ionic compounds.


Is Phosphorus Sulfur Ionic or Covalent?

Covalent


Is phosphorus pentoxide ionic or covalent bond?

Phosphorus pentoxide is a covalent bond, not a ionic. -Emiko Bunny


Would nitrogen and phosphorus form a covalent bond?

Yes. Nitrogen and phosphorus would form a covalent bond.


Is phosphorus Ionic or convalent bond?

Phosphorus typically forms covalent bonds due to its preference to share electrons to complete its valence shell. However, in some cases, phosphorus can also form ionic bonds with metals to achieve a more stable electron configuration.


Is phosphorus trisulfide ionic or covalent?

Phosphorous trisulfide (PS3) is a covalent compound.


Is phosphorus a ionic or covalent compound?

Phosphorus is a chemical element, not a compound.


Why covalent crystals r opaque?

Covalent crystals are not necessarily opaque. Think of diamond, pure quartz crystals, pure aluminium oxide crystals these all are colorless and transparent.